GB1138262A - Improvements in or relating to electrolytic nickel plating - Google Patents

Improvements in or relating to electrolytic nickel plating

Info

Publication number
GB1138262A
GB1138262A GB52173/65A GB5217365A GB1138262A GB 1138262 A GB1138262 A GB 1138262A GB 52173/65 A GB52173/65 A GB 52173/65A GB 5217365 A GB5217365 A GB 5217365A GB 1138262 A GB1138262 A GB 1138262A
Authority
GB
United Kingdom
Prior art keywords
derivatives
compounds
ethyl
hydroxymethyl
prepared
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB52173/65A
Inventor
Frank Passal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
M&T Chemicals Inc
Original Assignee
M&T Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by M&T Chemicals Inc filed Critical M&T Chemicals Inc
Publication of GB1138262A publication Critical patent/GB1138262A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C07D213/16—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing only one pyridine ring
    • C07D213/20—Quaternary compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
    • C07D213/30—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
    • C25D3/14—Electroplating: Baths therefor from solutions of nickel or cobalt from baths containing acetylenic or heterocyclic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
  • Pyridine Compounds (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

1,138,262. Quaternary pyridine derivatives. M & T CHEMICALS Inc. 8 Dec., 1965, No. 52173/65. Heading C2C. [Also in Division C7] Compounds of the general formula where R is an alkyl group; R<SP>1</SP> is a hydroxyalkyl group; a is 0, 2, 3, 4 or 5, b is 0, 1, 2, 3 or 4, and when a is 0 b is 1, 2, 3 or 4; and X is a watersolubilizing anion are prepared by quaternizing preferably in the presence of a solvent such as dimethylformamide at room temperature with slight warming at the start of the reaction, the correspondingly substituted pyridine with a propargyl compound HC#C-CH 2 X, preferably where X is halogen, e.g. the bromide. Specified compounds are N-propargyl-pyridinium bromides, viz. the five dimethyl derivatives, the 3-ethyl-4-methyl derivative, the hydroxymethyl, -ethyl and -propyl derivatives and the symmetrical trimethyl and tri-hydroxymethyl derivatives. Corresponding compounds with anions such as acetate, sulphate, perchlorate or methosulphate may be prepared from the bromides by double decomposition with an appropriate silver salt, such as silver acetate.
GB52173/65A 1964-12-21 1965-12-08 Improvements in or relating to electrolytic nickel plating Expired GB1138262A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US420132A US3352766A (en) 1964-12-21 1964-12-21 Bright nickel plating process

Publications (1)

Publication Number Publication Date
GB1138262A true GB1138262A (en) 1968-12-27

Family

ID=23665212

Family Applications (2)

Application Number Title Priority Date Filing Date
GB52173/65A Expired GB1138262A (en) 1964-12-21 1965-12-08 Improvements in or relating to electrolytic nickel plating
GB39118/68A Expired GB1138263A (en) 1964-12-21 1965-12-08 Improvements in or relating to electrolytic nickel plating

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB39118/68A Expired GB1138263A (en) 1964-12-21 1965-12-08 Improvements in or relating to electrolytic nickel plating

Country Status (7)

Country Link
US (1) US3352766A (en)
CH (1) CH477560A (en)
DE (1) DE1496919C3 (en)
ES (1) ES320951A1 (en)
FR (1) FR1460489A (en)
GB (2) GB1138262A (en)
NL (1) NL6516627A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4471044A (en) * 1983-06-13 1984-09-11 Eastman Kodak Company Silver halide emulsions and photographic elements containing adsorbable alkynyl substituted heterocyclic quaternary ammonium salts
RU2583569C1 (en) * 2014-12-10 2016-05-10 Федеральное государственное бюджетное учреждение науки Иркутский институт химии им. А.Е. Фаворского Сибирского отделения Российской академии наук Method of producing shiny nickel coatings

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2644789A (en) * 1951-08-02 1953-07-07 Harshaw Chem Corp Electrodeposition of nickel
US3006822A (en) * 1957-05-08 1961-10-31 Langbein Pfanhauser Werke Ag Electro-deposition of nickel coatings
DE1066068B (en) * 1957-06-05 1959-09-24 Langbein-Pfanhauser Werke Aktiengesellschaft, Neuß Electrolyte for galvanic deposition of mirror-shining, leveled, ductile nickel deposits
US3218244A (en) * 1963-02-01 1965-11-16 M & T Chemicals Inc Nickel electroplating bath containing a 1, 2-dichloropropene pyridinium or quinolinium brightener
US3261840A (en) * 1963-03-18 1966-07-19 Sarki Res And Dev Corp Bright nickel plating baths
US3170853A (en) * 1963-03-18 1965-02-23 Sarki Res And Dev Corp Bright nickel plating baths containing a vinyl pyridinium compound brightener
US3255096A (en) * 1963-11-01 1966-06-07 Harshaw Chem Corp Electrodeposition of nickel

Also Published As

Publication number Publication date
FR1460489A (en) 1966-06-17
DE1496919B2 (en) 1980-09-04
US3352766A (en) 1967-11-14
DE1496919C3 (en) 1981-06-19
DE1496919A1 (en) 1969-04-10
ES320951A1 (en) 1966-11-01
NL6516627A (en) 1966-06-22
GB1138263A (en) 1968-12-27
CH477560A (en) 1969-08-31

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