FR2372187A1 - - Google Patents

Info

Publication number
FR2372187A1
FR2372187A1 FR7735005A FR7735005A FR2372187A1 FR 2372187 A1 FR2372187 A1 FR 2372187A1 FR 7735005 A FR7735005 A FR 7735005A FR 7735005 A FR7735005 A FR 7735005A FR 2372187 A1 FR2372187 A1 FR 2372187A1
Authority
FR
France
Prior art keywords
piperidine
substituted
radicals
arylalkyl
polyamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7735005A
Other languages
French (fr)
Other versions
FR2372187B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ciba Geigy SpA
Original Assignee
Chimosa Chimica Organica SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chimosa Chimica Organica SpA filed Critical Chimosa Chimica Organica SpA
Publication of FR2372187A1 publication Critical patent/FR2372187A1/fr
Application granted granted Critical
Publication of FR2372187B1 publication Critical patent/FR2372187B1/fr
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
    • C08G73/0638—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with at least three nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
    • C08G73/0627—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only one nitrogen atom in the ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

Ce sont des dérivés pipéridiniques de la 1,3,5-triazine de la formule I ci-après, avec R1 et R2 : H, alkyle, cycloalkyle, aryle, arylalkyle, pipéridine, substituée; X et Y : -O-, -S-, -NR8 ; R8 : H, alkyle, cycloalkyle, aryle, arylalkyle, pipéridine substituée; R1 X- et R2 Y- peuvent aussi être des radicaux hétérocycliques azotés fixés au noyau triazinique par un N de ces radicaux; n : nombre entier de 7 à 2 000; Z : radical à n valences issu d'une polyamine à au moins 7 groupes amine; les radicaux R1 X -ou R2 'Y- doivent contenir au moins un radical pipéridine substituée. La préparation consiste à faire réagir une 2-halotriazine bisubstituée en positions 4, 6 avec une polyamine telle que susindiquée. Ces composés améliorent la résistance des polymères synthétiques à la lumière, à la chaleur et à l'oxydation.They are piperidine derivatives of 1,3,5-triazine of formula I below, with R1 and R2: H, alkyl, cycloalkyl, aryl, arylalkyl, piperidine, substituted; X and Y: -O-, -S-, -NR8; R8: H, alkyl, cycloalkyl, aryl, arylalkyl, substituted piperidine; R1 X- and R2 Y- can also be nitrogenous heterocyclic radicals attached to the triazine ring by an N of these radicals; n: integer from 7 to 2000; Z: radical with n valences derived from a polyamine with at least 7 amine groups; the radicals R1 X —or R2 'Y— must contain at least one substituted piperidine radical. The preparation consists in reacting a 2-halotriazine bisubstituted in positions 4, 6 with a polyamine as indicated above. These compounds improve the resistance of synthetic polymers to light, heat and oxidation.

FR7735005A 1976-11-26 1977-11-22 Expired FR2372187B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT2981276A IT1123083B (en) 1976-11-26 1976-11-26 PIPERIDINE DERIVATIVES OF 1,3,5 TRIAZINE AS STABILIZERS FOR SYNTHETIC POLYMERS THAT INCLUDE THEM AND PROCEDURE FOR THEIR PREPARATION

Publications (2)

Publication Number Publication Date
FR2372187A1 true FR2372187A1 (en) 1978-06-23
FR2372187B1 FR2372187B1 (en) 1984-03-30

Family

ID=11228478

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7735005A Expired FR2372187B1 (en) 1976-11-26 1977-11-22

Country Status (10)

Country Link
JP (1) JPS5367749A (en)
BE (1) BE860655A (en)
CA (1) CA1089461A (en)
CH (1) CH626104A5 (en)
DE (1) DE2752740A1 (en)
ES (1) ES464469A1 (en)
FR (1) FR2372187B1 (en)
GB (1) GB1580940A (en)
IT (1) IT1123083B (en)
NL (1) NL7712962A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0003542A1 (en) * 1978-02-08 1979-08-22 Ciba-Geigy Ag Polyalkylpiperidine derivatives of s-triazines, their use as stabilizers for polymers and polymers thus stabilized
EP0013682A1 (en) * 1979-01-29 1980-08-06 Ciba-Geigy Ag Piperidyl-triazine derivatives, process for their production, their use as stabilizers for polymers and the polymers stabilized therewith
EP0042554A1 (en) * 1980-06-19 1981-12-30 Hoechst Aktiengesellschaft Polytriazinyl amines, process for their preparation, their use as stabilizing agents for synthetic polymers and polymers stabilized with these compounds
EP0068083A1 (en) * 1981-04-03 1983-01-05 Hoechst Aktiengesellschaft Poly-bis-triazinyl imide, its preparation and its use as a light-stabiliser for polymers, as well as the polymers stabilised therewith
FR2527215A1 (en) * 1982-05-19 1983-11-25 Apital Prod Ind NOVEL POLYPIPERIDINE COMPOUNDS AND THEIR USE AS STABILIZING AGENTS OF POLYMERS

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4234707A (en) * 1977-11-10 1980-11-18 Ciba-Geigy Corporation Polymeric light stabilizers for plastics
DE2933078A1 (en) * 1979-08-16 1981-03-26 Hoechst Ag, 65929 Frankfurt NEW TRIAZINE DERIVATIVES, THEIR PRODUCTION AND THEIR USE AS STABILIZERS FOR SYNTHETIC POLYMERS
DE2944729A1 (en) * 1979-11-06 1981-05-14 Hoechst Ag, 6000 Frankfurt NEW TRIAZINE STABILIZERS
IT1151035B (en) * 1980-07-31 1986-12-17 Chimosa Chimica Organica Spa PIPERIDYL-DERIVATIVES OF TRIAZINIC COPOLYMERS, PROCESSES FOR THEIR PREPARATION AND STABILIZED COMPOSITIONS THAT INCLUDE THEM
IT1195277B (en) * 1981-10-02 1988-10-12 Chimosa Chimica Organica Spa PIPERIDIL DERIVATIVES OF MACROCYCLIC TRIAZIN COMPOUNDS, HAVING STABILIZING ACTIVITY FOR POLYMERS AND PROCESSES FOR THEIR PREPARATION
IT1254689B (en) * 1992-04-14 1995-09-28 PIPERIDIN-TRIAZINIC COOLIGOMERS SUITABLE FOR USE AS STABILIZERS FOR ORGANIC MATERIALS.
GB2377709B (en) * 1998-12-14 2003-06-18 Ciba Sc Holding Ag Sterically hindered amine compounds
WO2003046068A1 (en) * 2001-11-30 2003-06-05 Ciba Specialty Chemicals Holding Inc. 2-hydroxyphenyl-s-triazine crosslinkers for polymer networks

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2181059A1 (en) * 1972-04-21 1973-11-30 Ciba Geigy Ag
FR2335509A1 (en) * 1975-12-18 1977-07-15 Chimosa Chimica Organica Spa PIPERIDYL-TRIAZINE DERIVATIVES INTENDED FOR POLYMER STABILIZATION

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL179392C (en) * 1975-03-21 1986-09-01 Montefibre Spa A METHOD FOR PREPARING STABILIZED POLYMERIC COMPOSITIONS AND A METHOD FOR PREPARING POLYAMINS SUITABLE AS A STABILIZER, AND MANUFACTURED THEREFOR.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2181059A1 (en) * 1972-04-21 1973-11-30 Ciba Geigy Ag
FR2335509A1 (en) * 1975-12-18 1977-07-15 Chimosa Chimica Organica Spa PIPERIDYL-TRIAZINE DERIVATIVES INTENDED FOR POLYMER STABILIZATION

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0003542A1 (en) * 1978-02-08 1979-08-22 Ciba-Geigy Ag Polyalkylpiperidine derivatives of s-triazines, their use as stabilizers for polymers and polymers thus stabilized
EP0013682A1 (en) * 1979-01-29 1980-08-06 Ciba-Geigy Ag Piperidyl-triazine derivatives, process for their production, their use as stabilizers for polymers and the polymers stabilized therewith
EP0042554A1 (en) * 1980-06-19 1981-12-30 Hoechst Aktiengesellschaft Polytriazinyl amines, process for their preparation, their use as stabilizing agents for synthetic polymers and polymers stabilized with these compounds
EP0068083A1 (en) * 1981-04-03 1983-01-05 Hoechst Aktiengesellschaft Poly-bis-triazinyl imide, its preparation and its use as a light-stabiliser for polymers, as well as the polymers stabilised therewith
US4471417A (en) * 1981-04-03 1984-09-11 Hoechst Aktiengesellschaft Poly-bis-triazinylimides, their preparation
FR2527215A1 (en) * 1982-05-19 1983-11-25 Apital Prod Ind NOVEL POLYPIPERIDINE COMPOUNDS AND THEIR USE AS STABILIZING AGENTS OF POLYMERS

Also Published As

Publication number Publication date
GB1580940A (en) 1980-12-10
CH626104A5 (en) 1981-10-30
NL7712962A (en) 1978-05-30
IT1123083B (en) 1986-04-30
JPS5367749A (en) 1978-06-16
DE2752740A1 (en) 1978-06-01
CA1089461A (en) 1980-11-11
JPS62934B2 (en) 1987-01-10
ES464469A1 (en) 1978-09-01
FR2372187B1 (en) 1984-03-30
BE860655A (en) 1978-03-01

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Legal Events

Date Code Title Description
TP Transmission of property
TP Transmission of property
ST Notification of lapse