FR2362882A1 - Procede de moderation de la vitesse de polymerisation des monomeres phenoliques utilisant un catalyseur complexe cuivre-diamine - Google Patents

Procede de moderation de la vitesse de polymerisation des monomeres phenoliques utilisant un catalyseur complexe cuivre-diamine

Info

Publication number
FR2362882A1
FR2362882A1 FR7726326A FR7726326A FR2362882A1 FR 2362882 A1 FR2362882 A1 FR 2362882A1 FR 7726326 A FR7726326 A FR 7726326A FR 7726326 A FR7726326 A FR 7726326A FR 2362882 A1 FR2362882 A1 FR 2362882A1
Authority
FR
France
Prior art keywords
copper
moderation
diamine complex
polymerization rate
complex catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7726326A
Other languages
English (en)
Other versions
FR2362882B1 (fr
Inventor
Glenn Dale Cooper
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Publication of FR2362882A1 publication Critical patent/FR2362882A1/fr
Application granted granted Critical
Publication of FR2362882B1 publication Critical patent/FR2362882B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
    • C08G65/44—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols by oxidation of phenols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyethers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un procédé de couplage oxydant de monomère phénolique 2,6-disubstitué utilisant un complexe cuivre-diamine comme catalyseur. La vitesse de réaction est contrôlée par adjonction d'une quantité efficace d'eau dans le mélange réactionnel initial. On peut ainsi maîtriser l'élévation de la masse molaire du polymère attendu, élévation qui, d'ailleurs, cesse d'elle-même. Obtention de résines à mouler.
FR7726326A 1976-08-30 1977-08-30 Procede de moderation de la vitesse de polymerisation des monomeres phenoliques utilisant un catalyseur complexe cuivre-diamine Granted FR2362882A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/718,836 US4059568A (en) 1976-08-30 1976-08-30 Method for the control of diamine catalyzed polyphenylene ether polymerization

Publications (2)

Publication Number Publication Date
FR2362882A1 true FR2362882A1 (fr) 1978-03-24
FR2362882B1 FR2362882B1 (fr) 1981-01-02

Family

ID=24887752

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7726326A Granted FR2362882A1 (fr) 1976-08-30 1977-08-30 Procede de moderation de la vitesse de polymerisation des monomeres phenoliques utilisant un catalyseur complexe cuivre-diamine

Country Status (9)

Country Link
US (1) US4059568A (fr)
JP (1) JPS5329400A (fr)
AU (1) AU2820277A (fr)
BR (1) BR7705736A (fr)
CA (1) CA1106539A (fr)
DE (1) DE2738714A1 (fr)
FR (1) FR2362882A1 (fr)
GB (1) GB1538362A (fr)
NL (1) NL7709387A (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4263426A (en) * 1978-11-06 1981-04-21 General Electric Company Process for isolation of polyphenylene ether resin by crumbing in hot water
DE3113096A1 (de) * 1981-04-01 1982-10-21 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von polyphenylenethern
US4477650A (en) * 1983-03-25 1984-10-16 General Electric Company Process for polyphenylene oxide preparation including catalyst pre-mixing
DE3313864A1 (de) * 1983-04-16 1984-10-18 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von polyphenylenoxiden
US4587327A (en) * 1984-09-20 1986-05-06 General Electric Company Method for preparing polyphenylene oxide with copper (I) complex catalysts
US4598140A (en) * 1984-09-20 1986-07-01 General Electric Company Copper (I)-phenoxides useful in polyphenylene oxide preparation
DE3529093A1 (de) * 1985-08-14 1987-02-19 Bayer Ag Verfahren zur herstellung von mono- und bifunktionellen oligophenylenoxiden
US5621066A (en) * 1994-08-10 1997-04-15 General Electric Company Environmentally friendly method for poly(phenylene ether) polymerization and catalyst recycle
JP3504587B2 (ja) * 2000-06-19 2004-03-08 旭化成ケミカルズ株式会社 ポリフェニレンエーテルの製造法
US6472499B1 (en) 2000-08-04 2002-10-29 General Electric Company Preparation of high intrinsic viscosity poly(arylene ether) resins
US7413791B2 (en) * 2003-01-28 2008-08-19 Matsushita Electric Works, Ltd. Poly (phenylene ether) resin composition, prepreg, and laminated sheet
TWI802787B (zh) 2019-03-28 2023-05-21 日商四國化成工業股份有限公司 樹脂組成物及其用途

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1504932A (fr) * 1965-12-15 1967-12-08 Alusuisse Procédé de préparation d'éthers de polyphénylène
FR2260594A1 (fr) * 1974-02-11 1975-09-05 Gen Electric

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2061116B2 (de) * 1969-12-16 1973-02-01 Sumitomo Chemical Co Ltd , Osaka (Japan) Verfahren zur herstellung von polyphenylenoxiden
US3733299A (en) * 1971-06-10 1973-05-15 Gen Electric Process for the preparation of polyphenylene ethers with activated copper-amine catalysts
US3900445A (en) * 1973-12-26 1975-08-19 Gen Electric Process for the preparation of polyphenylene ethers with cuprous and cupric amine catalyst
US3914266A (en) * 1974-02-11 1975-10-21 Gen Electric Copper complex
US3988297A (en) * 1974-07-03 1976-10-26 General Electric Process for the preparation of polyphenylene ethers with activated copper-amine catalysts

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1504932A (fr) * 1965-12-15 1967-12-08 Alusuisse Procédé de préparation d'éthers de polyphénylène
FR2260594A1 (fr) * 1974-02-11 1975-09-05 Gen Electric

Also Published As

Publication number Publication date
DE2738714A1 (de) 1978-03-02
JPS5329400A (en) 1978-03-18
FR2362882B1 (fr) 1981-01-02
NL7709387A (nl) 1978-03-02
CA1106539A (fr) 1981-08-04
BR7705736A (pt) 1978-06-27
US4059568A (en) 1977-11-22
AU2820277A (en) 1979-03-08
GB1538362A (en) 1979-01-17

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