FR2361408A1 - Procede catalytique de preparation des chlorures d'esters d'acides phosphoreux et phosphoneux, et produits obtenus par ce procede - Google Patents
Procede catalytique de preparation des chlorures d'esters d'acides phosphoreux et phosphoneux, et produits obtenus par ce procedeInfo
- Publication number
- FR2361408A1 FR2361408A1 FR7724955A FR7724955A FR2361408A1 FR 2361408 A1 FR2361408 A1 FR 2361408A1 FR 7724955 A FR7724955 A FR 7724955A FR 7724955 A FR7724955 A FR 7724955A FR 2361408 A1 FR2361408 A1 FR 2361408A1
- Authority
- FR
- France
- Prior art keywords
- equal
- phosphorous
- preparation
- phosphoneous
- chlorides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title 1
- 239000002253 acid Substances 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 title 1
- -1 diaryl chlorophosphite Chemical compound 0.000 abstract 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 2
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 abstract 2
- CCBOSLKTSBVYRI-UHFFFAOYSA-N OP(O)(Cl)Cl Chemical compound OP(O)(Cl)Cl CCBOSLKTSBVYRI-UHFFFAOYSA-N 0.000 abstract 1
- DQTRYXANLKJLPK-UHFFFAOYSA-N chlorophosphonous acid Chemical compound OP(O)Cl DQTRYXANLKJLPK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
- C07F9/146—Esters of phosphorous acids containing P-halide groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/42—Halides thereof
- C07F9/425—Acid or estermonohalides thereof, e.g. RP(=X)(YR)(Hal) (X, Y = O, S; R = H, or hydrocarbon group)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
On prépare les composés de l'invention, qui ont pour formule : Rm (R'0)n PCl3 -m-n où R et R' représentent divers radicaux organiques, m est égal à 0 ou 1, n est égal à 1 ou 2 et m + n est égal à 1 ou 2, en faisant réagir un phosphite de trialkyle, un phosphite de triaryle, un chlorophosphite de dialkyle ou un chlorophosphite de diaryle avec le trichlorure de phosphore, un dichlorure d'ester alkyle d'acide phosphoreux ou un dichlorure d'ester arylique d'acide phosphoreux, ou en faisant réagir un phosphonite de dialkyle avec un dichlorophosphonite en présence d'une quantité catalytique d'un composé de phosphore tri- et/ou pentavalent L'invention permet en particulier une préparation industrielle simple avec des rendements élevés.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2636270A DE2636270C2 (de) | 1976-08-12 | 1976-08-12 | Verfahren zur Herstellung von Phosphorigsäureesterchloriden und Phosphonigsäureesterchloriden |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2361408A1 true FR2361408A1 (fr) | 1978-03-10 |
FR2361408B1 FR2361408B1 (fr) | 1983-11-25 |
Family
ID=5985288
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7724955A Granted FR2361408A1 (fr) | 1976-08-12 | 1977-08-12 | Procede catalytique de preparation des chlorures d'esters d'acides phosphoreux et phosphoneux, et produits obtenus par ce procede |
Country Status (13)
Country | Link |
---|---|
US (1) | US4118435A (fr) |
JP (1) | JPS5323930A (fr) |
AT (1) | AT348547B (fr) |
BE (1) | BE857725A (fr) |
BR (1) | BR7705324A (fr) |
CH (1) | CH629214A5 (fr) |
DE (1) | DE2636270C2 (fr) |
DK (1) | DK144887C (fr) |
FR (1) | FR2361408A1 (fr) |
GB (1) | GB1584697A (fr) |
IL (1) | IL52680A (fr) |
IT (1) | IT1079425B (fr) |
NL (1) | NL7708883A (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55139394A (en) * | 1979-04-19 | 1980-10-31 | Nippon Tokushu Noyaku Seizo Kk | Novel synthetic method of thiol phosphate ester chloride |
US4476064A (en) * | 1982-12-28 | 1984-10-09 | Mobil Oil Corporation | Phosphorus acid catalyst for preparation of 3,9-dichloro-2,4,8,10-tetraoxa-3,9-diphospha spiro (5,5) undecane |
DE3541627A1 (de) * | 1985-11-26 | 1987-05-27 | Hoechst Ag | Verfahren zur herstellung von phosphonsaeuredichloriden |
DE3911230A1 (de) * | 1989-04-07 | 1990-10-11 | Hoechst Ag | Verfahren zur herstellung von alkylphosphonigsaeurediestern und/oder dialkylphosphinigsaeureestern |
DE3937610A1 (de) * | 1989-11-11 | 1991-05-16 | Hoechst Ag | Verfahren zur gewinnung von phosphorigsaeure-bis-(2,4-di-tert.-butyl-phenyl)ester-halogeniden |
CN101918415B (zh) * | 2007-12-06 | 2013-05-15 | 日本化学工业株式会社 | 高纯度氯化亚磷酸酯的制造方法 |
CN102276643B (zh) * | 2011-06-24 | 2014-04-09 | 永农生物科学有限公司 | 草铵膦中间体二烷氧基亚磷酰氯的合成方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2325656A1 (fr) * | 1975-09-29 | 1977-04-22 | Ciba Geigy Ag | Procede de preparation de chlorophosphites |
FR2325657A1 (fr) * | 1975-09-29 | 1977-04-22 | Ciba Geigy Ag | Procede de fabrication de chlorophosphites |
-
1976
- 1976-08-12 DE DE2636270A patent/DE2636270C2/de not_active Expired
-
1977
- 1977-07-27 US US05/819,535 patent/US4118435A/en not_active Expired - Lifetime
- 1977-08-08 IL IL52680A patent/IL52680A/xx unknown
- 1977-08-09 CH CH976577A patent/CH629214A5/de not_active IP Right Cessation
- 1977-08-10 IT IT50623/77A patent/IT1079425B/it active
- 1977-08-10 AT AT583277A patent/AT348547B/de not_active IP Right Cessation
- 1977-08-10 JP JP9519477A patent/JPS5323930A/ja active Pending
- 1977-08-10 GB GB33498/77A patent/GB1584697A/en not_active Expired
- 1977-08-11 BR BR7705324A patent/BR7705324A/pt unknown
- 1977-08-11 NL NL7708883A patent/NL7708883A/xx not_active Application Discontinuation
- 1977-08-11 DK DK357977A patent/DK144887C/da active
- 1977-08-12 BE BE2056154A patent/BE857725A/fr not_active IP Right Cessation
- 1977-08-12 FR FR7724955A patent/FR2361408A1/fr active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2325656A1 (fr) * | 1975-09-29 | 1977-04-22 | Ciba Geigy Ag | Procede de preparation de chlorophosphites |
FR2325657A1 (fr) * | 1975-09-29 | 1977-04-22 | Ciba Geigy Ag | Procede de fabrication de chlorophosphites |
Non-Patent Citations (3)
Title |
---|
CA1975 * |
EXBK/49 * |
EXBK/65 * |
Also Published As
Publication number | Publication date |
---|---|
DK357977A (da) | 1978-02-13 |
DE2636270A1 (de) | 1978-02-16 |
GB1584697A (en) | 1981-02-18 |
BR7705324A (pt) | 1978-06-06 |
IL52680A (en) | 1981-02-27 |
AT348547B (de) | 1979-02-26 |
CH629214A5 (de) | 1982-04-15 |
DK144887B (da) | 1982-06-28 |
DK144887C (da) | 1982-11-22 |
ATA583277A (de) | 1978-07-15 |
NL7708883A (nl) | 1978-02-14 |
JPS5323930A (en) | 1978-03-06 |
IT1079425B (it) | 1985-05-13 |
FR2361408B1 (fr) | 1983-11-25 |
IL52680A0 (en) | 1977-10-31 |
BE857725A (fr) | 1978-02-13 |
DE2636270C2 (de) | 1983-06-09 |
US4118435A (en) | 1978-10-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |