FR2361154A1 - HYDROGEN RESIDUE TREATMENT CATALYST AND PROCESS USING SUCH A CATALYST - Google Patents

HYDROGEN RESIDUE TREATMENT CATALYST AND PROCESS USING SUCH A CATALYST

Info

Publication number
FR2361154A1
FR2361154A1 FR7723410A FR7723410A FR2361154A1 FR 2361154 A1 FR2361154 A1 FR 2361154A1 FR 7723410 A FR7723410 A FR 7723410A FR 7723410 A FR7723410 A FR 7723410A FR 2361154 A1 FR2361154 A1 FR 2361154A1
Authority
FR
France
Prior art keywords
catalyst
pores
residue treatment
hydrogen residue
angstroms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7723410A
Other languages
French (fr)
Inventor
Howard Samuel Sherry
Stephen Bruce Jaffe
Stephen Michael Oleck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of FR2361154A1 publication Critical patent/FR2361154A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La présente invention a pour objet un catalyseur comprenant les oxydes et/ou sulfures de métaux des Groupes VIB et VIII associes à un support d'alumine et initiés par une quantité atteignant 2,5 % en poids d'un oxyde de métal alcalin Il est caractérisé en ce qu'au moins 25 % du volume des pores de ce catalyseur sont représentés par des pores ayant un diamètre compris entre 30 et 100 Angstrom , moins de 15 % du volume de ses pores sont représentés par des pores ayant un diamètre supérieur à 300 Angstrom les pores ayant des diamètres supérieurs à 300 Angstrom représentent 0,450 à 0,550 cm**3/g de catalyseur. Elle se rapporte à un catalyseur permettant l'elimination des métaux et de soufre d'huiles de pétrole.The present invention relates to a catalyst comprising the oxides and / or sulphides of metals from Groups VIB and VIII combined with an alumina support and initiated with an amount reaching 2.5% by weight of an alkali metal oxide. characterized in that at least 25% of the volume of the pores of this catalyst are represented by pores having a diameter between 30 and 100 Angstrom, less than 15% of the volume of its pores are represented by pores having a diameter greater than 300 Angstroms the pores having diameters greater than 300 Angstroms represent 0.450 to 0.550 cm ** 3 / g of catalyst. It relates to a catalyst for the removal of metals and sulfur from petroleum oils.

FR7723410A 1976-08-12 1977-07-29 HYDROGEN RESIDUE TREATMENT CATALYST AND PROCESS USING SUCH A CATALYST Withdrawn FR2361154A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US71395576A 1976-08-12 1976-08-12

Publications (1)

Publication Number Publication Date
FR2361154A1 true FR2361154A1 (en) 1978-03-10

Family

ID=24868227

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7723410A Withdrawn FR2361154A1 (en) 1976-08-12 1977-07-29 HYDROGEN RESIDUE TREATMENT CATALYST AND PROCESS USING SUCH A CATALYST

Country Status (9)

Country Link
JP (1) JPS5322181A (en)
BE (1) BE857333A (en)
DE (1) DE2733050A1 (en)
FR (1) FR2361154A1 (en)
GB (1) GB1538036A (en)
IT (1) IT1086160B (en)
NL (1) NL7708891A (en)
NZ (1) NZ184201A (en)
ZA (1) ZA773855B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2570385A1 (en) * 1984-09-14 1986-03-21 Raffinage Cie Francaise PROCESS FOR HYDROPROCESSING HYDROCARBON LOADS AND CATALYST FOR IMPLEMENTING SAID METHOD
EP0243894A2 (en) * 1986-05-02 1987-11-04 W.R. Grace & Co.-Conn. Hydroprocessing catalyst and support having bidisperse pore structure
FR2605900A1 (en) * 1986-10-29 1988-05-06 Elf Aquitaine IMPROVEMENT TO THE PROCESS OF DESULFURING TERPENIC ESSENCES

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3416224C2 (en) * 1983-05-06 1994-05-05 Mitsubishi Chem Ind Process for the production of a liquefied coal oil
JPS62206041A (en) * 1986-03-03 1987-09-10 帝人株式会社 Blended fiber yarn for carpet and its production
US4908344A (en) * 1986-05-02 1990-03-13 W. R. Grace & Co.-Conn. Hydroprocessing catalyst and support having bidisperse pore structure
JP3378402B2 (en) * 1995-04-05 2003-02-17 新日本石油株式会社 Desulfurization method of catalytic cracking gasoline

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3383301A (en) * 1966-01-20 1968-05-14 Gulf Research Development Co Residue desulfurization with catalyst whose pore volume is distributed over wide range of pore sizes
US3730879A (en) * 1970-11-19 1973-05-01 Gulf Research Development Co Two-bed catalyst arrangement for hydrodesulrurization of crude oil

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3383301A (en) * 1966-01-20 1968-05-14 Gulf Research Development Co Residue desulfurization with catalyst whose pore volume is distributed over wide range of pore sizes
US3730879A (en) * 1970-11-19 1973-05-01 Gulf Research Development Co Two-bed catalyst arrangement for hydrodesulrurization of crude oil

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2570385A1 (en) * 1984-09-14 1986-03-21 Raffinage Cie Francaise PROCESS FOR HYDROPROCESSING HYDROCARBON LOADS AND CATALYST FOR IMPLEMENTING SAID METHOD
EP0175605A1 (en) * 1984-09-14 1986-03-26 Compagnie De Raffinage Et De Distribution Total France Process for hydrotreating hydrocarbon feeds and catalyst used in such a process
EP0243894A2 (en) * 1986-05-02 1987-11-04 W.R. Grace & Co.-Conn. Hydroprocessing catalyst and support having bidisperse pore structure
EP0243894A3 (en) * 1986-05-02 1988-10-05 W.R. Grace & Co. Hydroprocessing catalyst and support having bidisperse pore structure
FR2605900A1 (en) * 1986-10-29 1988-05-06 Elf Aquitaine IMPROVEMENT TO THE PROCESS OF DESULFURING TERPENIC ESSENCES
EP0267833A1 (en) * 1986-10-29 1988-05-18 Societe Nationale Elf Aquitaine (Production) Process for the desulfurization of ternic oils

Also Published As

Publication number Publication date
DE2733050A1 (en) 1978-02-16
ZA773855B (en) 1979-02-28
BE857333A (en) 1978-01-30
NL7708891A (en) 1978-02-14
GB1538036A (en) 1979-01-10
NZ184201A (en) 1979-10-25
IT1086160B (en) 1985-05-28
JPS5322181A (en) 1978-03-01

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Legal Events

Date Code Title Description
ST Notification of lapse