FR2361154A1 - HYDROGEN RESIDUE TREATMENT CATALYST AND PROCESS USING SUCH A CATALYST - Google Patents
HYDROGEN RESIDUE TREATMENT CATALYST AND PROCESS USING SUCH A CATALYSTInfo
- Publication number
- FR2361154A1 FR2361154A1 FR7723410A FR7723410A FR2361154A1 FR 2361154 A1 FR2361154 A1 FR 2361154A1 FR 7723410 A FR7723410 A FR 7723410A FR 7723410 A FR7723410 A FR 7723410A FR 2361154 A1 FR2361154 A1 FR 2361154A1
- Authority
- FR
- France
- Prior art keywords
- catalyst
- pores
- residue treatment
- hydrogen residue
- angstroms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003054 catalyst Substances 0.000 title abstract 6
- -1 HYDROGEN RESIDUE Chemical group 0.000 title 1
- 239000011148 porous material Substances 0.000 abstract 5
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8872—Alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
La présente invention a pour objet un catalyseur comprenant les oxydes et/ou sulfures de métaux des Groupes VIB et VIII associes à un support d'alumine et initiés par une quantité atteignant 2,5 % en poids d'un oxyde de métal alcalin Il est caractérisé en ce qu'au moins 25 % du volume des pores de ce catalyseur sont représentés par des pores ayant un diamètre compris entre 30 et 100 Angstrom , moins de 15 % du volume de ses pores sont représentés par des pores ayant un diamètre supérieur à 300 Angstrom les pores ayant des diamètres supérieurs à 300 Angstrom représentent 0,450 à 0,550 cm**3/g de catalyseur. Elle se rapporte à un catalyseur permettant l'elimination des métaux et de soufre d'huiles de pétrole.The present invention relates to a catalyst comprising the oxides and / or sulphides of metals from Groups VIB and VIII combined with an alumina support and initiated with an amount reaching 2.5% by weight of an alkali metal oxide. characterized in that at least 25% of the volume of the pores of this catalyst are represented by pores having a diameter between 30 and 100 Angstrom, less than 15% of the volume of its pores are represented by pores having a diameter greater than 300 Angstroms the pores having diameters greater than 300 Angstroms represent 0.450 to 0.550 cm ** 3 / g of catalyst. It relates to a catalyst for the removal of metals and sulfur from petroleum oils.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US71395576A | 1976-08-12 | 1976-08-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2361154A1 true FR2361154A1 (en) | 1978-03-10 |
Family
ID=24868227
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7723410A Withdrawn FR2361154A1 (en) | 1976-08-12 | 1977-07-29 | HYDROGEN RESIDUE TREATMENT CATALYST AND PROCESS USING SUCH A CATALYST |
Country Status (9)
Country | Link |
---|---|
JP (1) | JPS5322181A (en) |
BE (1) | BE857333A (en) |
DE (1) | DE2733050A1 (en) |
FR (1) | FR2361154A1 (en) |
GB (1) | GB1538036A (en) |
IT (1) | IT1086160B (en) |
NL (1) | NL7708891A (en) |
NZ (1) | NZ184201A (en) |
ZA (1) | ZA773855B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2570385A1 (en) * | 1984-09-14 | 1986-03-21 | Raffinage Cie Francaise | PROCESS FOR HYDROPROCESSING HYDROCARBON LOADS AND CATALYST FOR IMPLEMENTING SAID METHOD |
EP0243894A2 (en) * | 1986-05-02 | 1987-11-04 | W.R. Grace & Co.-Conn. | Hydroprocessing catalyst and support having bidisperse pore structure |
FR2605900A1 (en) * | 1986-10-29 | 1988-05-06 | Elf Aquitaine | IMPROVEMENT TO THE PROCESS OF DESULFURING TERPENIC ESSENCES |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3416224C2 (en) * | 1983-05-06 | 1994-05-05 | Mitsubishi Chem Ind | Process for the production of a liquefied coal oil |
JPS62206041A (en) * | 1986-03-03 | 1987-09-10 | 帝人株式会社 | Blended fiber yarn for carpet and its production |
US4908344A (en) * | 1986-05-02 | 1990-03-13 | W. R. Grace & Co.-Conn. | Hydroprocessing catalyst and support having bidisperse pore structure |
JP3378402B2 (en) * | 1995-04-05 | 2003-02-17 | 新日本石油株式会社 | Desulfurization method of catalytic cracking gasoline |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3383301A (en) * | 1966-01-20 | 1968-05-14 | Gulf Research Development Co | Residue desulfurization with catalyst whose pore volume is distributed over wide range of pore sizes |
US3730879A (en) * | 1970-11-19 | 1973-05-01 | Gulf Research Development Co | Two-bed catalyst arrangement for hydrodesulrurization of crude oil |
-
1977
- 1977-05-25 NZ NZ184201A patent/NZ184201A/en unknown
- 1977-06-27 ZA ZA00773855A patent/ZA773855B/en unknown
- 1977-07-01 IT IT25334/77A patent/IT1086160B/en active
- 1977-07-04 GB GB27884/77A patent/GB1538036A/en not_active Expired
- 1977-07-21 DE DE19772733050 patent/DE2733050A1/en not_active Withdrawn
- 1977-07-29 FR FR7723410A patent/FR2361154A1/en not_active Withdrawn
- 1977-07-29 BE BE179793A patent/BE857333A/en unknown
- 1977-08-11 NL NL7708891A patent/NL7708891A/en not_active Application Discontinuation
- 1977-08-11 JP JP9565677A patent/JPS5322181A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3383301A (en) * | 1966-01-20 | 1968-05-14 | Gulf Research Development Co | Residue desulfurization with catalyst whose pore volume is distributed over wide range of pore sizes |
US3730879A (en) * | 1970-11-19 | 1973-05-01 | Gulf Research Development Co | Two-bed catalyst arrangement for hydrodesulrurization of crude oil |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2570385A1 (en) * | 1984-09-14 | 1986-03-21 | Raffinage Cie Francaise | PROCESS FOR HYDROPROCESSING HYDROCARBON LOADS AND CATALYST FOR IMPLEMENTING SAID METHOD |
EP0175605A1 (en) * | 1984-09-14 | 1986-03-26 | Compagnie De Raffinage Et De Distribution Total France | Process for hydrotreating hydrocarbon feeds and catalyst used in such a process |
EP0243894A2 (en) * | 1986-05-02 | 1987-11-04 | W.R. Grace & Co.-Conn. | Hydroprocessing catalyst and support having bidisperse pore structure |
EP0243894A3 (en) * | 1986-05-02 | 1988-10-05 | W.R. Grace & Co. | Hydroprocessing catalyst and support having bidisperse pore structure |
FR2605900A1 (en) * | 1986-10-29 | 1988-05-06 | Elf Aquitaine | IMPROVEMENT TO THE PROCESS OF DESULFURING TERPENIC ESSENCES |
EP0267833A1 (en) * | 1986-10-29 | 1988-05-18 | Societe Nationale Elf Aquitaine (Production) | Process for the desulfurization of ternic oils |
Also Published As
Publication number | Publication date |
---|---|
DE2733050A1 (en) | 1978-02-16 |
ZA773855B (en) | 1979-02-28 |
BE857333A (en) | 1978-01-30 |
NL7708891A (en) | 1978-02-14 |
GB1538036A (en) | 1979-01-10 |
NZ184201A (en) | 1979-10-25 |
IT1086160B (en) | 1985-05-28 |
JPS5322181A (en) | 1978-03-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |