FR2359199A1 - Additives improving combustion of diesel fuel - comprising oil-soluble rare earth metal derivs. - Google Patents

Additives improving combustion of diesel fuel - comprising oil-soluble rare earth metal derivs.

Info

Publication number
FR2359199A1
FR2359199A1 FR7622425A FR7622425A FR2359199A1 FR 2359199 A1 FR2359199 A1 FR 2359199A1 FR 7622425 A FR7622425 A FR 7622425A FR 7622425 A FR7622425 A FR 7622425A FR 2359199 A1 FR2359199 A1 FR 2359199A1
Authority
FR
France
Prior art keywords
additives
derivs
diesel fuel
salts
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7622425A
Other languages
French (fr)
Other versions
FR2359199B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAMLEN NAINTRE SA
Original Assignee
GAMLEN NAINTRE SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GAMLEN NAINTRE SA filed Critical GAMLEN NAINTRE SA
Priority to FR7622425A priority Critical patent/FR2359199A1/en
Publication of FR2359199A1 publication Critical patent/FR2359199A1/en
Application granted granted Critical
Publication of FR2359199B1 publication Critical patent/FR2359199B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/04Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L11/00Manufacture of firelighters
    • C10L11/04Manufacture of firelighters consisting of combustible material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/1814Chelates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/24Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/26Organic compounds containing phosphorus
    • C10L1/2633Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

Diesel fuel additives comprise oil-soluble organic derivs. of rare-earth metals, esp. Ce or Pr. Pref. additives are salts of >=6C organic carboxylic acids (esp. naphthenic acids), salts of >=6C phosphates, phosphines, sulphates or sulphonates, acetylacetate salts, or chelates of pentadiene-dicarboxylic acid. The additives are pref. used in an amt. corresp. to a metal concn. of 10-250 (10-100) ppm for distillate fuels or 25-250 ppm for heavy fuels. They can be added in solid form or in the form of solns. The additives reduce smoke emission, decrease fuel consumption, inhibit corrosion of valves, etc., and reduce deposit formation in the exhaust system. A typical additive is Ce acetylacetate.
FR7622425A 1976-07-22 1976-07-22 Additives improving combustion of diesel fuel - comprising oil-soluble rare earth metal derivs. Granted FR2359199A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7622425A FR2359199A1 (en) 1976-07-22 1976-07-22 Additives improving combustion of diesel fuel - comprising oil-soluble rare earth metal derivs.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7622425A FR2359199A1 (en) 1976-07-22 1976-07-22 Additives improving combustion of diesel fuel - comprising oil-soluble rare earth metal derivs.

Publications (2)

Publication Number Publication Date
FR2359199A1 true FR2359199A1 (en) 1978-02-17
FR2359199B1 FR2359199B1 (en) 1978-12-22

Family

ID=9176025

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7622425A Granted FR2359199A1 (en) 1976-07-22 1976-07-22 Additives improving combustion of diesel fuel - comprising oil-soluble rare earth metal derivs.

Country Status (1)

Country Link
FR (1) FR2359199A1 (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0087073A2 (en) * 1982-02-18 1983-08-31 Ruhrchemie Aktiengesellschaft Process for improving fuels for diesel engines
DE3245882A1 (en) * 1982-12-11 1984-06-14 Ruhrchemie Ag, 4200 Oberhausen Process for improving the combustion of liquid fuels
EP0134146A2 (en) * 1983-08-17 1985-03-13 Exxon Research And Engineering Company Residual fuel oil composition
EP0194369A1 (en) * 1983-11-18 1986-09-17 Texaco Development Corporation Diesel fuel containing rare earth metal and oxygenated compounds
FR2585360A1 (en) * 1985-07-29 1987-01-30 Rosenbluth Germain Process for reducing unburnt materials from combustion and agent for its use
EP0661377A1 (en) * 1993-12-31 1995-07-05 Rhone-Poulenc Chimie Method preventing the deposition of the carbon soot in the exhaust gas circuit of a turbocompressed internal combustion engine
WO1995018198A1 (en) * 1993-12-31 1995-07-06 Rhone-Poulenc Chimie Filtration and combustion process for carbon particulate matter from an internal combustion engine
FR2719081A1 (en) * 1994-04-20 1995-10-27 Rhone Poulenc Chimie Reduction of carbonaceous particulate emissions in vehicle exhausts
WO1996026255A1 (en) * 1995-02-24 1996-08-29 Rhone-Poulenc Chimie Use of a cerium compound for protecting internal combustion engines
WO1997044414A1 (en) * 1996-05-20 1997-11-27 Bp Chemicals (Additives) Limited Marine diesel process and fuel therefor

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR823791A (en) * 1936-07-13 1938-01-26 Leo Corp Method for operating an internal combustion engine
US2913319A (en) * 1956-08-13 1959-11-17 Gulf Research Development Co Fuel oils
US3003859A (en) * 1956-05-31 1961-10-10 Ethyl Corp Liquified chelate gasoline additives
US3057151A (en) * 1960-06-14 1962-10-09 Gulf Research Development Co Vanadium-containing petroleum fuels modified with rare earth and alkali metal additives
US3157682A (en) * 1960-11-04 1964-11-17 Exxon Research Engineering Co Oil-soluble liquid chelate compounds and their preparation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR823791A (en) * 1936-07-13 1938-01-26 Leo Corp Method for operating an internal combustion engine
US3003859A (en) * 1956-05-31 1961-10-10 Ethyl Corp Liquified chelate gasoline additives
US2913319A (en) * 1956-08-13 1959-11-17 Gulf Research Development Co Fuel oils
US3057151A (en) * 1960-06-14 1962-10-09 Gulf Research Development Co Vanadium-containing petroleum fuels modified with rare earth and alkali metal additives
US3157682A (en) * 1960-11-04 1964-11-17 Exxon Research Engineering Co Oil-soluble liquid chelate compounds and their preparation

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0087073A2 (en) * 1982-02-18 1983-08-31 Ruhrchemie Aktiengesellschaft Process for improving fuels for diesel engines
EP0087073A3 (en) * 1982-02-18 1984-04-25 Ruhrchemie Aktiengesellschaft Process for improving fuels for diesel engines
DE3245882A1 (en) * 1982-12-11 1984-06-14 Ruhrchemie Ag, 4200 Oberhausen Process for improving the combustion of liquid fuels
EP0134146A2 (en) * 1983-08-17 1985-03-13 Exxon Research And Engineering Company Residual fuel oil composition
EP0134146A3 (en) * 1983-08-17 1985-04-24 Exxon Research And Engineering Company Residual fuel oil composition
EP0194369A1 (en) * 1983-11-18 1986-09-17 Texaco Development Corporation Diesel fuel containing rare earth metal and oxygenated compounds
FR2585360A1 (en) * 1985-07-29 1987-01-30 Rosenbluth Germain Process for reducing unburnt materials from combustion and agent for its use
EP0270719A1 (en) * 1986-12-12 1988-06-15 TECHNIQUE FRANCAISE DE DETARTRAGE dite T.F.D., Société Anonyme Process for reducing unburned combustion particles, and agent for carrying out the process
EP0661377A1 (en) * 1993-12-31 1995-07-05 Rhone-Poulenc Chimie Method preventing the deposition of the carbon soot in the exhaust gas circuit of a turbocompressed internal combustion engine
WO1995018198A1 (en) * 1993-12-31 1995-07-06 Rhone-Poulenc Chimie Filtration and combustion process for carbon particulate matter from an internal combustion engine
FR2714695A1 (en) * 1993-12-31 1995-07-07 Rhone Poulenc Chimie A method for keeping the circuits of a turbocharged engine clean and for reducing the carbon emissions of such an engine.
FR2719081A1 (en) * 1994-04-20 1995-10-27 Rhone Poulenc Chimie Reduction of carbonaceous particulate emissions in vehicle exhausts
WO1996026255A1 (en) * 1995-02-24 1996-08-29 Rhone-Poulenc Chimie Use of a cerium compound for protecting internal combustion engines
FR2731009A1 (en) * 1995-02-24 1996-08-30 Rhone Poulenc Chimie METHOD OF PROTECTING INTERNAL COMBUSTION ENGINES AND APPLICATION OF CERIUM-BASED COMPOUND TO THE PROTECTION OF ENGINES AGAINST WEAR AND OXIDATION
WO1997044414A1 (en) * 1996-05-20 1997-11-27 Bp Chemicals (Additives) Limited Marine diesel process and fuel therefor

Also Published As

Publication number Publication date
FR2359199B1 (en) 1978-12-22

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