FR2356618A1 - PROCESS FOR THE PREPARATION OF ALCANOLS - Google Patents

PROCESS FOR THE PREPARATION OF ALCANOLS

Info

Publication number
FR2356618A1
FR2356618A1 FR7719491A FR7719491A FR2356618A1 FR 2356618 A1 FR2356618 A1 FR 2356618A1 FR 7719491 A FR7719491 A FR 7719491A FR 7719491 A FR7719491 A FR 7719491A FR 2356618 A1 FR2356618 A1 FR 2356618A1
Authority
FR
France
Prior art keywords
weight
alcanols
preparation
nickel
alkanals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7719491A
Other languages
French (fr)
Other versions
FR2356618B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of FR2356618A1 publication Critical patent/FR2356618A1/en
Application granted granted Critical
Publication of FR2356618B1 publication Critical patent/FR2356618B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J177/00—Adhesives based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Adhesives based on derivatives of such polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof

Abstract

L'invention concerne un procédé amélioré pour l'hydrogénation d'alcanals en C3 -C5 en les alcanols correspondants, à 130-190 degrés C, et sous 30 à 300 bars de pression d'hydrogène, en phase liquide, en présence d'eau, au moyen de catalyseurs à support renfermant du nickel. Selon l'invention on utilise à cet effet un catalyseur dont la masse active renferme 40 à 80 % en poids de nickel, 10 à 50 % en poids de cuivre et 2 à 10 % en poids de manganèse.The invention relates to an improved process for the hydrogenation of C3 -C5 alkanals to the corresponding alkanols, at 130-190 degrees C, and under 30 to 300 bar of hydrogen pressure, in the liquid phase, in the presence of. water, using supported catalysts containing nickel. According to the invention, a catalyst is used for this purpose, the active mass of which contains 40 to 80% by weight of nickel, 10 to 50% by weight of copper and 2 to 10% by weight of manganese.

FR7719491A 1976-06-28 1977-06-24 PROCESS FOR THE PREPARATION OF ALCANOLS Granted FR2356618A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2628987A DE2628987C3 (en) 1976-06-28 1976-06-28 Process for the preparation of C? 3? -C? 5? Alkanols

Publications (2)

Publication Number Publication Date
FR2356618A1 true FR2356618A1 (en) 1978-01-27
FR2356618B1 FR2356618B1 (en) 1981-07-17

Family

ID=5981652

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7719491A Granted FR2356618A1 (en) 1976-06-28 1977-06-24 PROCESS FOR THE PREPARATION OF ALCANOLS

Country Status (7)

Country Link
JP (1) JPS532408A (en)
AT (1) AT351005B (en)
CA (1) CA1072123A (en)
DE (1) DE2628987C3 (en)
ES (1) ES460134A1 (en)
FR (1) FR2356618A1 (en)
GB (1) GB1579159A (en)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3228881C2 (en) * 1982-08-03 1985-06-13 Basf Ag, 6700 Ludwigshafen Process for the preparation of C? 3? -C? 5? Alcohols
CA1303412C (en) 1985-05-31 1992-06-16 Shigeharu Koboshi Method for forming direct positive color image
US5866725A (en) * 1997-12-11 1999-02-02 Celanese International Corporation Process for the production of n-propanol
DE10024542A1 (en) 2000-05-18 2001-11-22 Basf Ag Production of saturated 3-20C alcohols uses a hydrogenation catalyst bed in the presence of a salt-like base in the reactant feed containing an anion of an acid having a pKa of greater than 2
DE10357718A1 (en) 2003-12-09 2005-07-21 Basf Ag Process for the preparation of tricyclodecanedialdehyde
CA2642592A1 (en) 2006-03-03 2007-09-07 Basf Se Process for the preparation of 1,2-propanediol
EP2200960B1 (en) 2007-08-31 2015-11-04 Basf Se Method for producing 1,2-propandiol by low-pressure hydrogenation of glycerine
EP2200958B1 (en) 2007-08-31 2015-11-04 Basf Se Method for producing 1,2-propandiol by hydrogenating glycerine in a two-step reactor cascade
BRPI0815783A2 (en) 2007-08-31 2015-02-24 Basf Se PROCESS FOR PREPARING 1,2-PROPANODIOL.
WO2011009936A2 (en) 2009-07-24 2011-01-27 Basf Se Process for the preparation of 1,2-propanediol from glycerol
US8871985B2 (en) 2010-03-15 2014-10-28 Exxonmobil Chemical Patents Inc. Processes for the production of alcohols
US9365715B2 (en) 2010-12-23 2016-06-14 Styrolution Europe Gmbh Thermoplastic elastomer composition and method for the production thereof
US9035110B2 (en) 2012-03-07 2015-05-19 Basf Se Process for heat integration in the hydrogenation and distillation of C3—C20-aldehydes
JP2015513553A (en) 2012-03-07 2015-05-14 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Process for heat integration in hydrogenation and distillation of C3-C20 aldehydes
TWI654177B (en) 2013-10-31 2019-03-21 德商巴斯夫歐洲公司 Process for preparing carboxylic acid esters and use thereof as plasticizer
CA2932240A1 (en) 2013-12-06 2015-06-11 Basf Se Softener composition which contains tetrahydrofuran derivatives and 1,2-cyclohexane dicarboxylic acid esters
WO2015104309A1 (en) 2014-01-09 2015-07-16 Basf Se Plasticizer composition containing furan derivatives and 1,2-cyclohexanedicarboxylic ester
JP2017517496A (en) 2014-04-22 2017-06-29 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Process for the preparation of carboxylic esters in the presence of ionic liquids and acidic esterification catalysts and their use as plasticizers
DE102015207291A1 (en) 2014-04-24 2016-03-10 Basf Se Plasticizer composition containing furan derivatives and 1,2-cyclohexanedicarboxylic acid ester
TW201609628A (en) 2014-07-08 2016-03-16 巴斯夫歐洲公司 Plasticizer composition which comprises diesters of aliphatic dicarboxylic acids and dialkylesters of terephthalic acid
TW201605945A (en) 2014-07-08 2016-02-16 巴斯夫歐洲公司 Molding compounds containing esters of dicarboxylic acids and esters of 1,2-cyclohexanedicarboxylic acid
TWI706979B (en) 2014-08-19 2020-10-11 德商巴斯夫歐洲公司 Plasticizer composition comprising polymeric dicarboxylic esters
TWI686444B (en) 2014-09-04 2020-03-01 德商巴斯夫歐洲公司 Plasticizer composition comprising polymeric dicarboxylic esters
TW201619119A (en) 2014-10-09 2016-06-01 巴斯夫歐洲公司 Plasticizer composition which comprises cycloalkyl esters of saturated dicarboxylic acids and 1,2-cyclohexane dicarboxylic esters
TW201619120A (en) 2014-10-09 2016-06-01 巴斯夫歐洲公司 Plasticizer composition which comprises cycloalkyl esters of saturated dicarboxylic acids and terephthalic esters
PL3037400T3 (en) 2014-12-23 2019-02-28 Evonik Degussa Gmbh Chromium-free hydrogenation of hydroformylation mixtures
ES2707345T3 (en) 2015-01-30 2019-04-03 Basf Se Plasticizing composition containing polymeric esters of dicarboxylic acids and dialkyl esters of terephthalic acid
WO2017055431A1 (en) 2015-09-30 2017-04-06 Basf Se Plasticizer composition containing polymeric dicarboxylic acid esters and dicarboxylic acid diesters
CN108137853B (en) 2015-09-30 2020-11-20 巴斯夫欧洲公司 Plasticizer composition comprising polymeric dicarboxylate and dialkyl terephthalate
US20180291180A1 (en) 2015-09-30 2018-10-11 Basf Se Plasticizer composition containing polymeric dicarboxylic acid esters and dicarboxylic acid diesters
EP3405518B1 (en) 2016-01-20 2019-11-06 Basf Se Plasticiser composition containing aliphatic dicarboxylic acid esters and diesters selected from 1,2-cyclohexane dicarboxylic acid esters and terephthalic acid esters
US10787565B2 (en) 2016-03-23 2020-09-29 Basf Se Polymer composition containing a cycloalkyl alkyl dicarboxylic acid diester as a plasticizer
WO2018024597A1 (en) 2016-08-01 2018-02-08 Basf Se Plasticizer composition
WO2018024591A1 (en) 2016-08-01 2018-02-08 Basf Se Plasticizer composition
US20190161597A1 (en) 2016-08-01 2019-05-30 Basf Se Plasticizer composition
KR102641656B1 (en) 2017-05-16 2024-02-29 바스프 에스이 Method for producing monohydroxy compounds
EP3466938A1 (en) 2017-10-05 2019-04-10 Basf Se 3,5-diethyl-2-propyl-tetrahydropyran and stereoisomers thereof for use as aroma chemicals
WO2019185409A1 (en) 2018-03-29 2019-10-03 Basf Se Pvc composition containing at least one plasticizer having at least one carboxylic acid ester group, and containing at least one carbodiimide compound
EP3747860B1 (en) 2019-06-04 2023-07-26 Basf Se Novel cyclohexanone based plasticisers
EP3878831A1 (en) 2020-03-10 2021-09-15 Basf Se Improved nickel-copper-manganese-catalyst for the preparation of alcohols by hydrogenation of the corresponding aldehydes and ketones
EP4249114A1 (en) 2022-03-21 2023-09-27 Basf Se Nickel-copper-manganese hydrogenation catalyst comprising a silica support

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1199194A (en) * 1957-07-16 1959-12-11 Basf Ag Process for the catalytic hydrogenation of carbocyclic compounds with olefinic double bonds
FR1528522A (en) * 1966-06-25 1968-06-07 Basf Ag Process for the preparation of saturated alcohols by hydrogenation of aldehydes or ketones
FR1556790A (en) * 1967-03-18 1969-02-07
FR2062354A5 (en) * 1969-09-30 1971-06-25 Basf Ag
US3950441A (en) * 1970-09-16 1976-04-13 Gaf Corporation Process and catalyst for preparing 1,4-butanediol

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1276620B (en) * 1965-11-26 1968-09-05 Huels Chemische Werke Ag Process for the preparation of saturated aliphatic alcohols
DE1269605B (en) * 1966-06-25 1968-06-06 Basf Ag Process for the production of saturated alcohols by hydrogenating aldehydes or ketones

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1199194A (en) * 1957-07-16 1959-12-11 Basf Ag Process for the catalytic hydrogenation of carbocyclic compounds with olefinic double bonds
FR1528522A (en) * 1966-06-25 1968-06-07 Basf Ag Process for the preparation of saturated alcohols by hydrogenation of aldehydes or ketones
FR1556790A (en) * 1967-03-18 1969-02-07
FR2062354A5 (en) * 1969-09-30 1971-06-25 Basf Ag
US3950441A (en) * 1970-09-16 1976-04-13 Gaf Corporation Process and catalyst for preparing 1,4-butanediol

Also Published As

Publication number Publication date
AT351005B (en) 1979-07-10
ATA452777A (en) 1978-12-15
DE2628987C3 (en) 1981-10-22
FR2356618B1 (en) 1981-07-17
JPS532408A (en) 1978-01-11
ES460134A1 (en) 1978-10-01
GB1579159A (en) 1980-11-12
CA1072123A (en) 1980-02-19
DE2628987B2 (en) 1981-01-08
DE2628987A1 (en) 1978-01-12

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