FR2354306A1 - PROCESS FOR PREPARING 2-PHENYL-ETHANOL DERIVATIVES - Google Patents

PROCESS FOR PREPARING 2-PHENYL-ETHANOL DERIVATIVES

Info

Publication number
FR2354306A1
FR2354306A1 FR7717716A FR7717716A FR2354306A1 FR 2354306 A1 FR2354306 A1 FR 2354306A1 FR 7717716 A FR7717716 A FR 7717716A FR 7717716 A FR7717716 A FR 7717716A FR 2354306 A1 FR2354306 A1 FR 2354306A1
Authority
FR
France
Prior art keywords
bonded
phenyl
optionally
carbon atom
converted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7717716A
Other languages
French (fr)
Other versions
FR2354306B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of FR2354306A1 publication Critical patent/FR2354306A1/en
Application granted granted Critical
Publication of FR2354306B1 publication Critical patent/FR2354306B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/095—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C07C1/30—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms by splitting-off the elements of hydrogen halide from a single molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/10—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with ester groups or with a carbon-halogen bond
    • C07C67/11—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with ester groups or with a carbon-halogen bond being mineral ester groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Procédé pour la préparation de dérivés de bêta-phényl éthanol. Un dérivé de l'éthane dans lequel un atome d'halogène est lié à un atome de carbone et un groupe phényle qui peut être substitué par 1 ou 2 atomes d'halogènes ou groupes alcoyle et/ou alcoxy de 1 à 6 atomes de carbone et éventuellement aussi un ou deux groupes alcoyle de 1 à 6 atomes de carbone sont liés à l'autre atome de carbone, est transformé en un dérivé d'éthylène dans lequel le groupe phényle est lié au premier atome de carbone et le ou les groupes alcoyle éventuels mentionnés en dernier lieu sont liés à l'autre atome de carbone, par réaction avec un acide carboxylique de formule RCOOH où R est un atome d'hydrogène ou un groupe alcoyle de 1 à 6 atomes de carbone éventuellement halogéné à une température d'au moins 50 degrés C, on transforme ce dérivé d'éthylène en l'ester bêtaphényl éthylcarboxylique correspondant avec un acide carboxylique de formule RCOOH, éventuellement en présence d'un catalyseur acide fort à une température inférieure à 100 degrés C et éventuellement on hydrolyse cet ester dans des conditions basiques. Ainsi, du chlorure de néophyle peut être transformé en diméthylbenzylcarbinol.Process for the preparation of beta-phenyl ethanol derivatives. An ethane derivative in which a halogen atom is bonded to a carbon atom and a phenyl group which may be substituted with 1 or 2 halogen atoms or alkyl and / or alkoxy groups of 1 to 6 carbon atoms and optionally also one or two alkyl groups of 1 to 6 carbon atoms are bonded to the other carbon atom, is converted into an ethylene derivative in which the phenyl group is bonded to the first carbon atom and the group (s) optional alkyls mentioned last are bonded to the other carbon atom, by reaction with a carboxylic acid of formula RCOOH where R is a hydrogen atom or an alkyl group of 1 to 6 carbon atoms optionally halogenated at a temperature d 'at least 50 degrees C, this ethylene derivative is converted into the corresponding beta-phenyl ethylcarboxylic ester with a carboxylic acid of formula RCOOH, optionally in the presence of a strong acid catalyst at a temperature below 100 degrees C and optionally hydrochloric acid rolyse this ester under basic conditions. Thus, neophyll chloride can be converted into dimethylbenzylcarbinol.

FR7717716A 1976-06-11 1977-06-09 PROCESS FOR PREPARING 2-PHENYL-ETHANOL DERIVATIVES Granted FR2354306A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB7624337A GB1542112A (en) 1976-06-11 1976-06-11 Process for the preparation of 2-phenylethanol or derivatives thereof

Publications (2)

Publication Number Publication Date
FR2354306A1 true FR2354306A1 (en) 1978-01-06
FR2354306B1 FR2354306B1 (en) 1980-02-29

Family

ID=10210135

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7717716A Granted FR2354306A1 (en) 1976-06-11 1977-06-09 PROCESS FOR PREPARING 2-PHENYL-ETHANOL DERIVATIVES

Country Status (6)

Country Link
JP (1) JPS52151137A (en)
CH (1) CH629736A5 (en)
DE (1) DE2726064C2 (en)
FR (1) FR2354306A1 (en)
GB (1) GB1542112A (en)
NL (1) NL7706332A (en)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3027478A1 (en) * 1980-07-19 1982-03-04 Ruhrchemie Ag, 4200 Oberhausen METHOD FOR PRODUCING DIMETHYLBENZYLCARBINOL AND DIMETHYLBENZYLCARBINYLFORMIAT
DE19654072A1 (en) * 1996-12-23 1998-07-09 Buna Sow Leuna Olefinverb Gmbh New plasticisers with low volatility and low fogging
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
CA2532367C (en) 2003-07-15 2013-04-23 Grt, Inc. Hydrocarbon synthesis
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
KR101335397B1 (en) 2006-02-03 2013-12-02 지알티, 인코포레이티드 Separation of light gases from halogens
AP2673A (en) 2006-02-03 2013-05-23 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
NZ581216A (en) 2007-05-24 2011-06-30 Grt Inc Zone reactor incorporating reversible hydrogen halide capture and release
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
US8415517B2 (en) 2008-07-18 2013-04-09 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems

Also Published As

Publication number Publication date
NL7706332A (en) 1977-12-13
GB1542112A (en) 1979-03-14
DE2726064A1 (en) 1977-12-22
CH629736A5 (en) 1982-05-14
JPS52151137A (en) 1977-12-15
DE2726064C2 (en) 1985-09-19
FR2354306B1 (en) 1980-02-29
JPS6113449B2 (en) 1986-04-14

Similar Documents

Publication Publication Date Title
FR2354306A1 (en) PROCESS FOR PREPARING 2-PHENYL-ETHANOL DERIVATIVES
KR890014486A (en) Use of N-cyclopropylaniline in the preparation of N-cyclopropylaniyl and 1-cyclopropyl-quinolonecarboxylic acid and derivatives thereof
FR2419300A1 (en) PROCESS FOR THE PREPARATION OF COPOLYMERS BASED ON ETHYLENE, AT LEAST ONE OTHER A-MONO-OLEFIN AND POSSIBLY A NON-CONJUGATE DIENE
ES8609195A1 (en) Process for preparing anti-inflammatory cycloalkylidenemethylphenylacetic acid derivatives.
FR2376104A1 (en) PROCESS FOR THE DIRECTED CHLORINATION OF ALCOYLBENZENES
KR850005838A (en) Method for preparing 1,3,2-dioxaborinane
KR870004148A (en) Separation method of 2-aminobutanol optical isomer by enzyme
FR2387953A1 (en) PROCESS FOR PREPARING 2-PYRROLIDONS SUBSTITUTES IN THE N POSITION
US2575694A (en) 3, 5, 5-trimethyloxazolidine-2, 4-dione
KR920008054A (en) Method for preparing 4-ethoxyphenyl-3-arylpropyl (dimethyl) silane
ATE1008T1 (en) ISOMERIZATION OF 3-AZABI CYCLO(3.1.0)HEXANE DERIVATIVES.
KR920702673A (en) Method for preparing N-alkylhalogenoaniline
FR2368467A1 (en) CONTINUOUS PROCESS FOR THE PREPARATION OF ACETOACETAMIDES
EP0153203A1 (en) C10-C20-Branched-chain fatty acids useful as medicaments and the preparation thereof
KR930004195B1 (en) Process for preparing substituld diamine
FR2383928A1 (en) NEW PYRIDINE-3-OLS
FR2372844A1 (en) PROCESS FOR PREPARING 17A-HYDROXY-21-ACETOXY-PROGESTERONE
KR890011830A (en) Method for preparing 2-oxyimino-3-oxobutyric acid
BE900739A (en) PROCESS FOR THE PREPARATION OF NEW CARBOXILIC ACID DERIVATIVES.
KR860009006A (en) Method for preparing 2-thiochromenilideneacetoacetic acid ester
KR930004244A (en) Diastereomerically pure intermediates and their use for the preparation of (R)-or (S) -ketoprofen
BE899007A (en) NOVEL ISOXAZOLES AND PROCESS FOR THEIR PREPARATION
FR2442225A1 (en) PROCESS FOR THE PREPARATION OF BASIC ESTERS OF SUBSTITUTED HYDROXYCYCLOHEXANE-CARBOXYLIC ACIDS
FR2378797A1 (en) PROCESS FOR PREPARING ACID DERIVATIVES HYDROXY-17B ALCOXY-20 PREGNANOIQUES-21
FR2387972A1 (en) (1-CHLORETHENYL) -OXIRANNE PREPARATION PROCESS

Legal Events

Date Code Title Description
ST Notification of lapse