FR2342356A1 - Anodising aluminium for bonding with polymer adhesives - is carried out in phosphoric acid bath at 10-30 degrees C - Google Patents

Anodising aluminium for bonding with polymer adhesives - is carried out in phosphoric acid bath at 10-30 degrees C

Info

Publication number
FR2342356A1
FR2342356A1 FR7705142A FR7705142A FR2342356A1 FR 2342356 A1 FR2342356 A1 FR 2342356A1 FR 7705142 A FR7705142 A FR 7705142A FR 7705142 A FR7705142 A FR 7705142A FR 2342356 A1 FR2342356 A1 FR 2342356A1
Authority
FR
France
Prior art keywords
anodising
degrees
carried out
bonding
phosphoric acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7705142A
Other languages
French (fr)
Other versions
FR2342356B1 (en
Inventor
J Arthur Marceau
Ralph H Firminhac
Yukimori Nmi Moji
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boeing Co
Original Assignee
Boeing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/661,717 external-priority patent/US4085012A/en
Application filed by Boeing Co filed Critical Boeing Co
Publication of FR2342356A1 publication Critical patent/FR2342356A1/en
Application granted granted Critical
Publication of FR2342356B1 publication Critical patent/FR2342356B1/fr
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/06Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
    • C25D11/08Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing inorganic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

Porous aluminium oxide layers are formed by anodising the article in a bath contg. 1.5-50 wt.% (10-12) wt.% H3PO4 at 10-30 (21-24) degrees C, and using an anodising voltage of 1.50-50 (10-15) volts. Pref. the anodising process is carried out for 10-30 (20-25) mins., and the article is rinsed within 0.3-2.3 mins. after anodising is completed. The process is useful for pretreating aluminium articles which are to be bonded with polymeric adhesives such as epoxy adhesives, e.g. in aircraft manufacture. The porous aluminium oxide layer formed is compatible with polymeric adhesives and gives high bond strengths. The resulting adhesive bonds have high resistance to hydrolysis and failure of the bond is generally by cohesive failure in the glue line rather than adhesive failure in the oxide layer or at the glue/oxide interface.
FR7705142A 1976-02-26 1977-02-22 Anodising aluminium for bonding with polymer adhesives - is carried out in phosphoric acid bath at 10-30 degrees C Granted FR2342356A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/661,717 US4085012A (en) 1974-02-07 1976-02-26 Method for providing environmentally stable aluminum surfaces for adhesive bonding and product produced
US73672676A 1976-10-29 1976-10-29

Publications (2)

Publication Number Publication Date
FR2342356A1 true FR2342356A1 (en) 1977-09-23
FR2342356B1 FR2342356B1 (en) 1982-05-28

Family

ID=27098370

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7705142A Granted FR2342356A1 (en) 1976-02-26 1977-02-22 Anodising aluminium for bonding with polymer adhesives - is carried out in phosphoric acid bath at 10-30 degrees C

Country Status (3)

Country Link
AU (1) AU511699B2 (en)
FR (1) FR2342356A1 (en)
NL (1) NL183956C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2382330A1 (en) * 1975-03-24 1978-09-29 Boeing Co ASSEMBLY OF ALUMINUM PARTS BY ADHERENCE

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8602582D0 (en) * 1986-02-03 1986-03-12 Alcan Int Ltd Porous anodic aluminium oxide films

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1591933A (en) * 1967-11-15 1970-05-04
US3714001A (en) * 1970-03-23 1973-01-30 Kaiser Aluminium Chem Corp Method for forming anodic oxide coatings having improved adhesive properties

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1591933A (en) * 1967-11-15 1970-05-04
US3714001A (en) * 1970-03-23 1973-01-30 Kaiser Aluminium Chem Corp Method for forming anodic oxide coatings having improved adhesive properties

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EXBK/75 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2382330A1 (en) * 1975-03-24 1978-09-29 Boeing Co ASSEMBLY OF ALUMINUM PARTS BY ADHERENCE

Also Published As

Publication number Publication date
NL7701977A (en) 1977-08-30
NL183956B (en) 1988-10-03
AU2262577A (en) 1978-08-31
NL183956C (en) 1989-03-01
FR2342356B1 (en) 1982-05-28
AU511699B2 (en) 1980-09-04

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