FR2301545A1 - Elastomeric block copolyesters - from terephthalic acid-based polyester, and aliphatic polyester based on trimethylene or tetramethylene glycol - Google Patents
Elastomeric block copolyesters - from terephthalic acid-based polyester, and aliphatic polyester based on trimethylene or tetramethylene glycolInfo
- Publication number
- FR2301545A1 FR2301545A1 FR7529906A FR7529906A FR2301545A1 FR 2301545 A1 FR2301545 A1 FR 2301545A1 FR 7529906 A FR7529906 A FR 7529906A FR 7529906 A FR7529906 A FR 7529906A FR 2301545 A1 FR2301545 A1 FR 2301545A1
- Authority
- FR
- France
- Prior art keywords
- polyester
- trimethylene
- terephthalic acid
- elastomeric block
- tetramethylene glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 title abstract 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 title abstract 4
- 229920000728 polyester Polymers 0.000 title abstract 3
- 229920001634 Copolyester Polymers 0.000 title abstract 2
- 229920003232 aliphatic polyester Polymers 0.000 title abstract 2
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 title 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 abstract 1
- 150000002009 diols Chemical class 0.000 abstract 1
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 230000002040 relaxant effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Elastomeric block copolyesters having a softening point of >=120 degrees C, for prodn. of tubes, belts, sheets and injection moulded articles, are prepd. by reacting, in the molten state, an aromatic polyester (I) having a reduced viscosity of >=0.4 g and derived from an aromatic dicarboxylic acid, with a aliphatic polyester (II) having a reduced viscosity of >=0.4, and derived from an aliphatic dicarboxylic acid or hydroxycarboxylic acid, the wt. ratio (I)/(II) being 0.25-9/1. In (I) >70 mole % of the acid component consists of terephthalic acid, and >70 mole % of the diol component consists of tetramethylene glycol or trimethylene glycol. (I) and (II) are reacted until the resulting polyester has an elastic recovery of at least 50%, after drawing by 20% and then relaxing for 5 mins.
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11164474A JPS5138390A (en) | 1974-09-30 | 1974-09-30 | HORIESUTERU DANSEITAINOSEIZOHO |
JP49113284A JPS5921886B2 (en) | 1974-10-03 | 1974-10-03 | Method for producing polyester block copolymer |
JP11616374A JPS5142796A (en) | 1974-10-11 | 1974-10-11 | HORIESUTERUBUROTSUKU KYOJUGOTAINO SEIZOHO |
JP11616474A JPS5835210B2 (en) | 1974-10-11 | 1974-10-11 | Polyester block material |
JP50030196A JPS6037134B2 (en) | 1975-03-14 | 1975-03-14 | Manufacturing method of polyester elastic body |
JP50030926A JPS5851869B2 (en) | 1975-03-14 | 1975-03-14 | elevator elevator |
JP3612175A JPS5913527B2 (en) | 1975-03-27 | 1975-03-27 | Method for manufacturing polyester elastic body |
JP10493775A JPS5913529B2 (en) | 1975-09-01 | 1975-09-01 | Method for manufacturing polyester elastic body |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2301545A1 true FR2301545A1 (en) | 1976-09-17 |
FR2301545B1 FR2301545B1 (en) | 1979-04-06 |
Family
ID=27572102
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7529906A Granted FR2301545A1 (en) | 1974-09-30 | 1975-09-30 | Elastomeric block copolyesters - from terephthalic acid-based polyester, and aliphatic polyester based on trimethylene or tetramethylene glycol |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2301545A1 (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1452249A (en) * | 1964-08-04 | 1966-02-25 | Goodyear Tire & Rubber | Condensation polymers |
-
1975
- 1975-09-30 FR FR7529906A patent/FR2301545A1/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1452249A (en) * | 1964-08-04 | 1966-02-25 | Goodyear Tire & Rubber | Condensation polymers |
Also Published As
Publication number | Publication date |
---|---|
FR2301545B1 (en) | 1979-04-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |