FR2277062A1 - Unsatd. acids/aldehydes by olefins oxidn. - made with high selectivity using a catalyst contg. Co, Mo, Bi and Fe - Google Patents

Unsatd. acids/aldehydes by olefins oxidn. - made with high selectivity using a catalyst contg. Co, Mo, Bi and Fe

Info

Publication number
FR2277062A1
FR2277062A1 FR7423247A FR7423247A FR2277062A1 FR 2277062 A1 FR2277062 A1 FR 2277062A1 FR 7423247 A FR7423247 A FR 7423247A FR 7423247 A FR7423247 A FR 7423247A FR 2277062 A1 FR2277062 A1 FR 2277062A1
Authority
FR
France
Prior art keywords
olefins
unsatd
aldehydes
acids
oxidn
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7423247A
Other languages
French (fr)
Other versions
FR2277062B1 (en
Inventor
Lia Yakovlevna Margolis
Oleg Vladimirovich Isaev
Lilia Samuilovna Luixaar
Igor Vasilievich Luixaar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INST KHIM FIZ AN SSSR
Original Assignee
INST KHIM FIZ AN SSSR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE2431511A priority Critical patent/DE2431511C3/en
Application filed by INST KHIM FIZ AN SSSR filed Critical INST KHIM FIZ AN SSSR
Priority to FR7423247A priority patent/FR2277062A1/en
Publication of FR2277062A1 publication Critical patent/FR2277062A1/en
Application granted granted Critical
Publication of FR2277062B1 publication Critical patent/FR2277062B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Abstract

alpha.BETA-Unsatd. acids/aldehydes are made by the gas phase oxidn. of olefins withoxygen or air at 300-450 degrees C in the presence of a catalyst which contains oxides of Co, Mo, Bi and Fe wherein the atomic ratios of the metals are, in that order, 2-12:12:0.05-5:0.05-6. The catalyst provides a higher degree of conversion, operates with a higher concn. of olefins in the starting reaction mixt. and has improved selectivity and stability during operation.
FR7423247A 1974-07-01 1974-07-04 Unsatd. acids/aldehydes by olefins oxidn. - made with high selectivity using a catalyst contg. Co, Mo, Bi and Fe Granted FR2277062A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE2431511A DE2431511C3 (en) 1974-07-01 1974-07-01 Process for the production of α, β-unsaturated acids and aldehydes
FR7423247A FR2277062A1 (en) 1974-07-01 1974-07-04 Unsatd. acids/aldehydes by olefins oxidn. - made with high selectivity using a catalyst contg. Co, Mo, Bi and Fe

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2431511A DE2431511C3 (en) 1974-07-01 1974-07-01 Process for the production of α, β-unsaturated acids and aldehydes
FR7423247A FR2277062A1 (en) 1974-07-01 1974-07-04 Unsatd. acids/aldehydes by olefins oxidn. - made with high selectivity using a catalyst contg. Co, Mo, Bi and Fe

Publications (2)

Publication Number Publication Date
FR2277062A1 true FR2277062A1 (en) 1976-01-30
FR2277062B1 FR2277062B1 (en) 1978-03-03

Family

ID=25767344

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7423247A Granted FR2277062A1 (en) 1974-07-01 1974-07-04 Unsatd. acids/aldehydes by olefins oxidn. - made with high selectivity using a catalyst contg. Co, Mo, Bi and Fe

Country Status (2)

Country Link
DE (1) DE2431511C3 (en)
FR (1) FR2277062A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0204333A1 (en) * 1985-06-05 1986-12-10 Mitsubishi Rayon Co., Ltd. Method for regenerating an oxidation catalyst

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19855913A1 (en) * 1998-12-03 2000-06-08 Basf Ag Multimetal oxide mass for the gas-phase catalytic oxidation of organic compounds
US7229945B2 (en) * 2003-12-19 2007-06-12 Saudi Basic Industrics Corporation Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0204333A1 (en) * 1985-06-05 1986-12-10 Mitsubishi Rayon Co., Ltd. Method for regenerating an oxidation catalyst
US4707460A (en) * 1985-06-05 1987-11-17 Mitsubishi Rayon Co., Ltd. Method for regenerating phosphorus-molybdenum-alkali containing oxidation catalyst

Also Published As

Publication number Publication date
FR2277062B1 (en) 1978-03-03
DE2431511C3 (en) 1980-10-02
DE2431511A1 (en) 1976-01-29
DE2431511B2 (en) 1980-02-07

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Legal Events

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