FR2242407A1 - Novel silicon-contg. polymer prodn. - by reacting a cyclic monomer and a rubber with an unsatd. silane in the presence of a catalyst - Google Patents

Novel silicon-contg. polymer prodn. - by reacting a cyclic monomer and a rubber with an unsatd. silane in the presence of a catalyst

Info

Publication number
FR2242407A1
FR2242407A1 FR7430204A FR7430204A FR2242407A1 FR 2242407 A1 FR2242407 A1 FR 2242407A1 FR 7430204 A FR7430204 A FR 7430204A FR 7430204 A FR7430204 A FR 7430204A FR 2242407 A1 FR2242407 A1 FR 2242407A1
Authority
FR
France
Prior art keywords
silane
contg
catalyst
reacting
unsatd
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7430204A
Other languages
French (fr)
Other versions
FR2242407B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of FR2242407A1 publication Critical patent/FR2242407A1/en
Application granted granted Critical
Publication of FR2242407B1 publication Critical patent/FR2242407B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/25—Incorporating silicon atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/28—Reaction with compounds containing carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Polymers contg. silane gps. in its main chain and/or its side-chains and/or as end-gps. are made by reacting a cyclic monoolefin and/or a polybutadiene, a polypiperylene and/or a butadiene-styrene copolymer in the presence of a reactive olefinically unsatd. silane and a catalyst. The catalyst contains (a) a cpd. of Re, Ta, Mo or W, (b) a Gp. I-IV organometallic cpd. and (c) opt. a cocatalyst opt. in the presence of an inert organic solvent at -60 degrees C to +60 degrees C. The products are rubbers contg. in addn. to C=C unsatn., reactive functionality due to the Si atoms which improves chemical bonding of fillers and improves their adhesion to glass fibres and to metals.
FR7430204A 1973-09-05 1974-09-05 Novel silicon-contg. polymer prodn. - by reacting a cyclic monomer and a rubber with an unsatd. silane in the presence of a catalyst Granted FR2242407A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19732344734 DE2344734A1 (en) 1973-09-05 1973-09-05 METHOD FOR PRODUCING SILICON MODIFIED POLYMERS

Publications (2)

Publication Number Publication Date
FR2242407A1 true FR2242407A1 (en) 1975-03-28
FR2242407B1 FR2242407B1 (en) 1978-04-28

Family

ID=5891695

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7430204A Granted FR2242407A1 (en) 1973-09-05 1974-09-05 Novel silicon-contg. polymer prodn. - by reacting a cyclic monomer and a rubber with an unsatd. silane in the presence of a catalyst

Country Status (6)

Country Link
JP (1) JPS5051592A (en)
BE (1) BE819548A (en)
DE (1) DE2344734A1 (en)
ES (1) ES429753A1 (en)
FR (1) FR2242407A1 (en)
NL (1) NL7411811A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0033774A2 (en) * 1980-02-02 1981-08-19 Chemische Werke Hüls Ag 1,3 diene homo and copolymers containing reactive silyl groups, process for their preparation and their use
EP0042481A1 (en) * 1980-06-19 1981-12-30 Hüls Aktiengesellschaft 1,3-Diene-homo and copolymers containing reactive silyl groups, process for their preparation and their use
EP0134678A2 (en) * 1983-07-20 1985-03-20 Loctite Corporation Polymers with graft alpha-alkylarylate functionality
FR2818651A1 (en) * 2000-12-26 2002-06-28 Hoechst Marion Roussel Inc SYNTHESIS OF NEW OXYGENATED HETEROCYCLIC MOLECULES BY METATHESIS REACTION ON SOLID SUPPORT USING NEW SILYLATED LINKERS
FR2915202A1 (en) * 2007-04-18 2008-10-24 Michelin Soc Tech MONOMODAL COUPLED DIENIC ELASTOMER HAVING CHAIN SILANOL FUNCTION, PROCESS FOR OBTAINING THE SAME, AND RUBBER COMPOSITION CONTAINING SAME.

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4783504A (en) * 1986-02-28 1988-11-08 Shell Oil Company Hot melt adhesive containing a silane grafted hydrogenated block polymer
US6100339A (en) * 1994-11-21 2000-08-08 Asahi Kasei Kogyo Kabushiki Kaisha Curable resin and resin composition comprising the same
US6017985A (en) * 1997-04-21 2000-01-25 Bridgestone Corporation Hydrosilated crystalline high trans polybutadine with silica filler, tires having a base of said composition and method of preparing same
FR3008980B1 (en) * 2013-07-23 2016-09-30 Bostik Sa HYDROCARBON POLYMERS WITH TWO ALCOXYSILANE TERMINAL GROUPS
FR3008982B1 (en) 2013-07-23 2015-09-04 Bostik Sa HYDROCARBON POLYMERS WITH ALCOXYSILANE TERMINAL GROUP

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0033774A2 (en) * 1980-02-02 1981-08-19 Chemische Werke Hüls Ag 1,3 diene homo and copolymers containing reactive silyl groups, process for their preparation and their use
EP0033774A3 (en) * 1980-02-02 1982-02-03 Chemische Werke Hüls Ag 1,3 diene homo and copolymers containing reactive silyl groups, process for their preparation and their use
EP0042481A1 (en) * 1980-06-19 1981-12-30 Hüls Aktiengesellschaft 1,3-Diene-homo and copolymers containing reactive silyl groups, process for their preparation and their use
EP0134678A2 (en) * 1983-07-20 1985-03-20 Loctite Corporation Polymers with graft alpha-alkylarylate functionality
EP0134678A3 (en) * 1983-07-20 1986-08-13 Loctite Corporation Polymers with graft alpha-alkylarylate functionality
FR2818651A1 (en) * 2000-12-26 2002-06-28 Hoechst Marion Roussel Inc SYNTHESIS OF NEW OXYGENATED HETEROCYCLIC MOLECULES BY METATHESIS REACTION ON SOLID SUPPORT USING NEW SILYLATED LINKERS
WO2002051883A1 (en) * 2000-12-26 2002-07-04 Aventis Pharma S.A. Synthesis of novel heterocyclic molecules oxygenated by metathesis reaction on solid support using novel silylated linkers
FR2915202A1 (en) * 2007-04-18 2008-10-24 Michelin Soc Tech MONOMODAL COUPLED DIENIC ELASTOMER HAVING CHAIN SILANOL FUNCTION, PROCESS FOR OBTAINING THE SAME, AND RUBBER COMPOSITION CONTAINING SAME.
WO2008141702A1 (en) * 2007-04-18 2008-11-27 Societe De Technologie Michelin Coupled monomodal dienic elastomer having a silanol in chain medium function, the method of obtaining same and composition of rubber containing it
CN101674946B (en) * 2007-04-18 2011-12-14 米其林技术公司 Coupled monomodal dienic elastomer having a silanol in chain medium function, the method of obtaining same and composition of rubber containing it
EA017106B1 (en) * 2007-04-18 2012-09-28 Компани Женераль Дез Этаблиссман Мишлен Coupled monomodal dienic elastomer having a silanol in chain medium function, method of obtaining same and composition of rubber containing it
US8344063B2 (en) 2007-04-18 2013-01-01 Michelin Recherche Et Technique S.A. Monomodal coupled diene elastomer having a silanol functional group in the middle of the chain, its process of preparation and rubber composition comprising it

Also Published As

Publication number Publication date
ES429753A1 (en) 1976-09-01
FR2242407B1 (en) 1978-04-28
JPS5051592A (en) 1975-05-08
DE2344734A1 (en) 1975-03-13
NL7411811A (en) 1975-03-07
BE819548A (en) 1975-03-04
AU7291674A (en) 1976-03-11

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