GB1461531A - Process for the manufacture of unsaturated optionally haloge nated hydrocarbon polymers with reactive silyl sidegroups - Google Patents

Process for the manufacture of unsaturated optionally haloge nated hydrocarbon polymers with reactive silyl sidegroups

Info

Publication number
GB1461531A
GB1461531A GB1277674A GB1277674A GB1461531A GB 1461531 A GB1461531 A GB 1461531A GB 1277674 A GB1277674 A GB 1277674A GB 1277674 A GB1277674 A GB 1277674A GB 1461531 A GB1461531 A GB 1461531A
Authority
GB
United Kingdom
Prior art keywords
silyl
groups
silylalkenamer
alkenamer
cyclopentene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1277674A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huels AG
Original Assignee
Chemische Werke Huels AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Werke Huels AG filed Critical Chemische Werke Huels AG
Publication of GB1461531A publication Critical patent/GB1461531A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/28—Reaction with compounds containing carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C08L101/10—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing hydrolysable silane groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1461531 Poly(silylalkenamer) preparation CHEMISCHE WERKE HULS AG 22 March 1974 [23 March 1973] 12776/74 Heading C3P A polymer containing silylalkenamer groups is obtained by subjecting to ring-opening, with a catalyst containing a niobium, tantalum, molybdenum, tungsten and/or rhenium compound, a polymerizable material comprising a hydrolysable silyl substituted, optionally halogenated, cyclic olefin or a mixture thereof with another optionally halogenated cyclic olefin and/or with an optionally halogenated hydrocarbon polymer containing double bonds. In an alternative procedure the monomeric silylsubstituted material is replaced by the corresponding polymeric silylalkenamer, obtained in a previous batch. Where polymeric starting materials are employed, they undergo an analogous rupture at the double bonds with interchange of the resulting alkenylidene groups with the polymer being formed, to produce analogous silyl alkenamer/other alkenamer copolymeric materials. Where the polymeric silyl alkenamer alone is treated with the catalyst the resulting rearrangement of the mers leads to molecular weight regulation. Where appropriate, the electron-donor functions of the hydrolysable groups on the silyl group may be compensated by addition of a Lewis acid, typically constituted by an aluminium alkyl or halide such as is employed as cocatalyst with the transition metal compounds. In the examples, 5-methyldichlorosilylnorbornene is homopolymerized or 5-trichlorosilyl norbornene is copolymerized with cyclopentene, cyclopentene and cis,cis-cyclooctadiene-1,5 or cycloctane are copolymerized with 5-(trichlorosilylethyl) norbornene, 5-trimethoxysilylnorbornene or 3-(diethoxymethylsilyl)propyl - cyclooctene - 1 and cyclopentene are copolymerized and 5-(trichlorosilyl ethyl) norbornene or 1-trichlorosilyl cyclododecadiene-4,8 are reacted in the presence of cis - 1,4 - polybutadiene, the catalysts being WCl 6 -AlEtCl 2 -EtOH together with regulators such as octene-1, vinyl acetate, and 1,10 - bis(methyl - dichlorosilyl) - decene - (4). The silylpolyalkenamers may be hydrolysed and cross-linked via the silanol groups formed, or cross-linked via the double bonds using the usual sulphur and peroxy curing.
GB1277674A 1973-03-23 1974-03-22 Process for the manufacture of unsaturated optionally haloge nated hydrocarbon polymers with reactive silyl sidegroups Expired GB1461531A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19732314543 DE2314543C3 (en) 1973-03-23 1973-03-23 Process for the preparation of polymeric hydrocarbons with reactive silyl groups

Publications (1)

Publication Number Publication Date
GB1461531A true GB1461531A (en) 1977-01-13

Family

ID=5875692

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1277674A Expired GB1461531A (en) 1973-03-23 1974-03-22 Process for the manufacture of unsaturated optionally haloge nated hydrocarbon polymers with reactive silyl sidegroups

Country Status (7)

Country Link
JP (1) JPS5325359B2 (en)
CA (1) CA1026040A (en)
DE (1) DE2314543C3 (en)
FR (1) FR2222386B1 (en)
GB (1) GB1461531A (en)
IT (1) IT1003839B (en)
NL (1) NL7403942A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0029100A1 (en) * 1979-09-19 1981-05-27 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Coating composition comprising compounds that contain silyl groups and a hydrolysable ester
EP0050248A2 (en) * 1980-10-03 1982-04-28 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Vinyl-type resin composition

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3003893A1 (en) 1980-02-02 1981-10-15 Chemische Werke Hüls AG, 4370 Marl REACTIVE SILYL GROUPS CARRYING HOMO- OR COPOLYMERS OF 1,3-DIENES, PROCESS FOR THEIR PRODUCTION AND THE USE THEREOF
DE3167793D1 (en) * 1980-06-19 1985-01-31 Huels Chemische Werke Ag 1,3-diene-homo and copolymers containing reactive silyl groups, process for their preparation and their use
DE69711378T2 (en) * 1996-11-04 2002-10-24 The B.F. Goodrich Co., Richfield PHOTOSTRUCTURABLE DIELECTRIC COMPOSITIONS
JP2003082074A (en) * 2001-09-13 2003-03-19 Jsr Corp Norbornene ring-opened (co)polymer and hydrogenated product thereof
US8889806B2 (en) 2010-01-14 2014-11-18 Zeon Corporation Ring-opening polymer of cyclopentene and method of production of same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0029100A1 (en) * 1979-09-19 1981-05-27 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Coating composition comprising compounds that contain silyl groups and a hydrolysable ester
EP0050248A2 (en) * 1980-10-03 1982-04-28 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Vinyl-type resin composition
EP0050248A3 (en) * 1980-10-03 1983-02-16 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Vinyl-type resin composition

Also Published As

Publication number Publication date
DE2314543A1 (en) 1974-10-03
FR2222386A1 (en) 1974-10-18
JPS502800A (en) 1975-01-13
CA1026040A (en) 1978-02-07
FR2222386B1 (en) 1978-11-10
NL7403942A (en) 1974-09-25
IT1003839B (en) 1976-06-10
DE2314543C3 (en) 1980-09-11
JPS5325359B2 (en) 1978-07-26
DE2314543B2 (en) 1980-01-10

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee