FR2219217A1 - Removal of aromatics and sulphur cpds from hydrocarbons - by contact with a macroporous cation-exchange resin in ammonium form - Google Patents

Removal of aromatics and sulphur cpds from hydrocarbons - by contact with a macroporous cation-exchange resin in ammonium form

Info

Publication number
FR2219217A1
FR2219217A1 FR7306821A FR7306821A FR2219217A1 FR 2219217 A1 FR2219217 A1 FR 2219217A1 FR 7306821 A FR7306821 A FR 7306821A FR 7306821 A FR7306821 A FR 7306821A FR 2219217 A1 FR2219217 A1 FR 2219217A1
Authority
FR
France
Prior art keywords
hydrocarbons
aromatics
exchange resin
cpds
removal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7306821A
Other languages
French (fr)
Other versions
FR2219217B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7306821A priority Critical patent/FR2219217A1/en
Priority to DE2356519A priority patent/DE2356519A1/en
Priority to NL7315556A priority patent/NL7315556A/xx
Priority to GB5343173A priority patent/GB1415108A/en
Priority to JP48129105A priority patent/JPS506602A/ja
Publication of FR2219217A1 publication Critical patent/FR2219217A1/en
Application granted granted Critical
Publication of FR2219217B1 publication Critical patent/FR2219217B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • B01J49/53—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for cationic exchangers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Aromatic hydrocarbons and/or organic S cpds. are removed from their mixts. with more satd. hydrocarbons by (a) contacting the mixt. with an anhydrous macroporous cation - exchange resin in which the exchangeable cation is NH4+, N2H5+, R1NH3+, R1R2NH2+, R1R2R3NH+ or R1R2R3R4N+ (where R1 - R4 are opt. substd. hydrocarbyl) and (b) recovering the non-adsorbed hydrocarbons. Suitable feedstocks contain 0.05 - 20 wt.% aromatics and/or between 5 ppm and 3 wt. % of S cpds. The resin can be regenerated by (a) washing with a hydrocarbon that is easily sepd. from the adsorbed substances (pref. by distn.) or (b) purging with liq. or gaseous NH3.
FR7306821A 1972-11-16 1973-02-26 Removal of aromatics and sulphur cpds from hydrocarbons - by contact with a macroporous cation-exchange resin in ammonium form Granted FR2219217A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR7306821A FR2219217A1 (en) 1973-02-26 1973-02-26 Removal of aromatics and sulphur cpds from hydrocarbons - by contact with a macroporous cation-exchange resin in ammonium form
DE2356519A DE2356519A1 (en) 1972-11-16 1973-11-13 PROCESS FOR DEAROMIZATION AND DESULFURATION OF HYDROCARBON MIXTURES
NL7315556A NL7315556A (en) 1972-11-16 1973-11-13
GB5343173A GB1415108A (en) 1972-11-16 1973-11-16 Peocess for dearomatizing and desluphurizing hydrocarbon mixtures
JP48129105A JPS506602A (en) 1972-11-16 1973-11-16

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7306821A FR2219217A1 (en) 1973-02-26 1973-02-26 Removal of aromatics and sulphur cpds from hydrocarbons - by contact with a macroporous cation-exchange resin in ammonium form

Publications (2)

Publication Number Publication Date
FR2219217A1 true FR2219217A1 (en) 1974-09-20
FR2219217B1 FR2219217B1 (en) 1976-11-05

Family

ID=9115434

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7306821A Granted FR2219217A1 (en) 1972-11-16 1973-02-26 Removal of aromatics and sulphur cpds from hydrocarbons - by contact with a macroporous cation-exchange resin in ammonium form

Country Status (1)

Country Link
FR (1) FR2219217A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2512051A1 (en) * 1981-08-26 1983-03-04 Raffinage Cie Francaise Sulphur cpds. removed from reforming feedstocks, etc. - by contacting with cation exchange resin charged with Gp=IIb metal ions
EP0076227A2 (en) * 1981-09-30 1983-04-06 The Goodyear Tire & Rubber Company Resins for removal of organo-sulfur compounds from organic or aqueous media

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1513684A (en) * 1966-02-01 1968-02-16 Dow Chemical Co Separation and purification of nonionic organic compounds

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1513684A (en) * 1966-02-01 1968-02-16 Dow Chemical Co Separation and purification of nonionic organic compounds

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2512051A1 (en) * 1981-08-26 1983-03-04 Raffinage Cie Francaise Sulphur cpds. removed from reforming feedstocks, etc. - by contacting with cation exchange resin charged with Gp=IIb metal ions
EP0076227A2 (en) * 1981-09-30 1983-04-06 The Goodyear Tire & Rubber Company Resins for removal of organo-sulfur compounds from organic or aqueous media
EP0076227A3 (en) * 1981-09-30 1983-11-09 The Goodyear Tire & Rubber Company Resins for removal of organo-sulfur compounds from organic or aqueous media

Also Published As

Publication number Publication date
FR2219217B1 (en) 1976-11-05

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Legal Events

Date Code Title Description
ST Notification of lapse