FR2133126A5 - Bis-(perfluoroalkyl)-methanol prodn - by catalytic hydrogenation of aliphatic perfluoroketones - Google Patents
Bis-(perfluoroalkyl)-methanol prodn - by catalytic hydrogenation of aliphatic perfluoroketonesInfo
- Publication number
- FR2133126A5 FR2133126A5 FR7112530A FR7112530A FR2133126A5 FR 2133126 A5 FR2133126 A5 FR 2133126A5 FR 7112530 A FR7112530 A FR 7112530A FR 7112530 A FR7112530 A FR 7112530A FR 2133126 A5 FR2133126 A5 FR 2133126A5
- Authority
- FR
- France
- Prior art keywords
- perfluoroketones
- prodn
- perfluoroalkyl
- bis
- aliphatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 aliphatic perfluoroketones Chemical class 0.000 title 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Substances OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- IYRWEQXVUNLMAY-UHFFFAOYSA-N carbonyl fluoride Chemical class FC(F)=O IYRWEQXVUNLMAY-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- VBZWSGALLODQNC-UHFFFAOYSA-N hexafluoroacetone Chemical compound FC(F)(F)C(=O)C(F)(F)F VBZWSGALLODQNC-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/34—Halogenated alcohols
- C07C31/40—Halogenated alcohols perhalogenated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Title cpds. as ind. solvents, esp. for polymers, are produced by hydrogenating perfluoroketones (pref. 1,1,1,3,3,3-hexafluoro-2-propanone) in the liq. phase at an elevated temp. and press, in the presence of a metallic Pd catalyst activated by means of an alkali metal (pref. Na) oxide, hydroxide, carbonate and/or bicarbonate. Quantitative yields at mild temp. and press. condtns. are obtd.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7112530A FR2133126A5 (en) | 1971-04-08 | 1971-04-08 | Bis-(perfluoroalkyl)-methanol prodn - by catalytic hydrogenation of aliphatic perfluoroketones |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7112530A FR2133126A5 (en) | 1971-04-08 | 1971-04-08 | Bis-(perfluoroalkyl)-methanol prodn - by catalytic hydrogenation of aliphatic perfluoroketones |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2133126A5 true FR2133126A5 (en) | 1972-11-24 |
Family
ID=9075001
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7112530A Expired FR2133126A5 (en) | 1971-04-08 | 1971-04-08 | Bis-(perfluoroalkyl)-methanol prodn - by catalytic hydrogenation of aliphatic perfluoroketones |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2133126A5 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2493831A1 (en) * | 1980-11-11 | 1982-05-14 | Central Glass Co Ltd | PROCESS FOR PREPARING 1,1,1,3,3,3-HEXAFLUOROPROPANE-2-OL BY HEXAFLUOROACETONE HYDRATE VAPOR CATALYST REACTION WITH HYDROGEN |
FR2552424A1 (en) * | 1983-09-27 | 1985-03-29 | Central Glass Co Ltd | PROCESS FOR PREPARING 1,1,1,3,3,3-HEXAFLUOROPROPANE-2-OL BY HYDROGENOLYSIS OF HEXAFLUOROACETONE HYDRATE |
EP0169141A1 (en) * | 1984-07-18 | 1986-01-22 | Elf Atochem S.A. | Process for the synthesis of trifluoro-2,2,2 ethanol and hexafluoro-1,1,1,3,3,3 isopropanol |
-
1971
- 1971-04-08 FR FR7112530A patent/FR2133126A5/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2493831A1 (en) * | 1980-11-11 | 1982-05-14 | Central Glass Co Ltd | PROCESS FOR PREPARING 1,1,1,3,3,3-HEXAFLUOROPROPANE-2-OL BY HEXAFLUOROACETONE HYDRATE VAPOR CATALYST REACTION WITH HYDROGEN |
FR2552424A1 (en) * | 1983-09-27 | 1985-03-29 | Central Glass Co Ltd | PROCESS FOR PREPARING 1,1,1,3,3,3-HEXAFLUOROPROPANE-2-OL BY HYDROGENOLYSIS OF HEXAFLUOROACETONE HYDRATE |
EP0169141A1 (en) * | 1984-07-18 | 1986-01-22 | Elf Atochem S.A. | Process for the synthesis of trifluoro-2,2,2 ethanol and hexafluoro-1,1,1,3,3,3 isopropanol |
FR2567875A1 (en) * | 1984-07-18 | 1986-01-24 | Atochem | PROCESS FOR THE SYNTHESIS OF 2,2,2-TRIFLUORO ETHANOL AND 1,1,1,3,3,3-ISOPROPYLIC HEXAFLUORO ALCOHOL |
US4647706A (en) * | 1984-07-18 | 1987-03-03 | Atochem | Process for the synthesis of 2,2,2-trifluoroethanol and 1,1,1,3,3,3-hexafluoroisopropanol |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS5019708A (en) | ||
CA976766A (en) | Method for the selective extraction of metals from aqueous solutions by means of neo-alkyl-hydroxamic acids | |
GB1120723A (en) | ªß-branched aldehydes | |
ES380942A1 (en) | Elution process for the regeneration of spent activated carbon | |
ES420451A1 (en) | Semimanufactured product for use in jewelry | |
CS179419B2 (en) | Process for continuous preparation of lower alcohols,especially isopropanol. | |
FR2133126A5 (en) | Bis-(perfluoroalkyl)-methanol prodn - by catalytic hydrogenation of aliphatic perfluoroketones | |
GB1086447A (en) | Hydrogenation of unsaturated aldehydes | |
ES432075A1 (en) | Process for making an ethynylation catalyst | |
ES412860A1 (en) | Process for producing propylene oxide | |
JPS4955635A (en) | ||
GB1086639A (en) | Production of cyclododecene | |
ES415801A1 (en) | Process for preparing saturated ketones and a catalyst for realizing the process | |
YU40626B (en) | Process for obtaining a new veratryl-4-methyl-5-ethyl-7,8-dimethoxy-2,3-diazabicyclo |5.4.0¨undecapantante(1,3,6,8,10) | |
FR2108849A1 (en) | Dehydrogenation of isopentene - using grp via,vb and ia or iia metal oxides | |
ES395133A1 (en) | Preparation of cyclohexanone by selective vapour | |
BE779060A (en) | 2,2,4-trimethyl 3-hydroxypentyl isobutyrate - by catalytic condensation of isobutyraldehyde in presence of water | |
GB1448226A (en) | Bimetallic-disc thermal switches | |
BE799541A (en) | Alkyl trans-chrysanthemates prepn - from cis isomers using alkali metal catalyst | |
NL152891B (en) | PROCESS FOR THE PURIFICATION OF REACTION MIXTURES OBTAINED IN OXYALKYLENATION PROCESSES OF HYDROXY COMPOUNDS IN THE PRESENCE OF BASIC METAL HYDROXIDE CATALYSTS. | |
FR2139714A1 (en) | 2-ethoxycarbonyl-5-hydroxy-3-piperazinomethyl indoles - - with analgesic,hypotensive and respiratory analeptic activity | |
FR2085992A1 (en) | Purifying polyhydantoins free from pheno-lics | |
GB1316820A (en) | Method of producing cyclohexanone | |
ES300609A1 (en) | Procedure for the polymerization of omega-laurinlactamo (Machine-translation by Google Translate, not legally binding) | |
FR2233852A5 (en) | 4,4-dimethyldioxane -1,3-prepn - using recycled aq formaldehyde phase |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |