FR2086699A5 - Hydrogeneration of conjugated diolefinsand a - - Google Patents
Hydrogeneration of conjugated diolefinsand a -Info
- Publication number
- FR2086699A5 FR2086699A5 FR7012441A FR7012441A FR2086699A5 FR 2086699 A5 FR2086699 A5 FR 2086699A5 FR 7012441 A FR7012441 A FR 7012441A FR 7012441 A FR7012441 A FR 7012441A FR 2086699 A5 FR2086699 A5 FR 2086699A5
- Authority
- FR
- France
- Prior art keywords
- cpd
- diolefinsand
- hydrogeneration
- conjugated
- nhr
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/31—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Hydrogenation of title cpds. is effected with H2 in the presence of a catalyst composed of a transition metal cpd. spec. a Ni cpd. and an Al cpd. and in the presence of a tert amine. pref. pyridine, the Al cpd. having the formula:- Al Hu X3-n or Me (Al Hm X'4-m)p (where n is 1 or 2; m is 1, 2 or 3; Me is a mono-or divalent Gp. Ia or IIa metal; p is the valency of the metal Me; X is OR, NR2, NHR or SR; X1 is R, OR, NR2, NHR or SR; each R is opt. substd. monovalent hydrocarbon or Awo R gps. together form a bivalent radical -A-Z-B in which A and B are alkylene and Z is H, S, Al, alkylene, NH or N-hydrocarbyl).
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7012441A FR2086699A5 (en) | 1970-04-06 | 1970-04-06 | Hydrogeneration of conjugated diolefinsand a - |
BE765033A BE765033R (en) | 1970-04-06 | 1971-03-31 | NEW HYDROGENATION PROCESS AND CORRESPONDING HYDROGENATION CATALYSTS |
NL7104400A NL7104400A (en) | 1970-04-06 | 1971-04-01 | |
DE19712116313 DE2116313A1 (en) | 1968-09-05 | 1971-04-03 | Hydrogeneration of conjugated diolefinsand |
US00131495A US3784481A (en) | 1970-04-06 | 1971-04-05 | Hydrogenation catalysts containing a transition metal salt and an aluminum hydride compound |
IT22791/71A IT987530B (en) | 1970-04-06 | 1971-04-06 | HYDROGENATION PROCEDURE AND CORRESPONDING HYDROGENATION CATALLYSTS |
GB26021/71A GB1294795A (en) | 1970-04-06 | 1971-04-19 | Hydrogenation process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7012441A FR2086699A5 (en) | 1970-04-06 | 1970-04-06 | Hydrogeneration of conjugated diolefinsand a - |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2086699A5 true FR2086699A5 (en) | 1971-12-31 |
Family
ID=9053518
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7012441A Expired FR2086699A5 (en) | 1968-09-05 | 1970-04-06 | Hydrogeneration of conjugated diolefinsand a - |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2086699A5 (en) |
-
1970
- 1970-04-06 FR FR7012441A patent/FR2086699A5/en not_active Expired
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |