FR2071278A5 - Tertiary aliphatic amine production by - amination of alkyl halides - Google Patents

Tertiary aliphatic amine production by - amination of alkyl halides

Info

Publication number
FR2071278A5
FR2071278A5 FR6944604A FR6944604A FR2071278A5 FR 2071278 A5 FR2071278 A5 FR 2071278A5 FR 6944604 A FR6944604 A FR 6944604A FR 6944604 A FR6944604 A FR 6944604A FR 2071278 A5 FR2071278 A5 FR 2071278A5
Authority
FR
France
Prior art keywords
pref
amine
sec
halide
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR6944604A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PIERREFITTE AUBY SA
Original Assignee
PIERREFITTE AUBY SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PIERREFITTE AUBY SA filed Critical PIERREFITTE AUBY SA
Priority to FR6944604A priority Critical patent/FR2071278A5/en
Priority to DE2062548A priority patent/DE2062548C3/en
Priority to GB6049370A priority patent/GB1337285A/en
Priority to NLAANVRAGE7018610,A priority patent/NL170728C/en
Priority to US00099853A priority patent/US3764626A/en
Priority to LU62297D priority patent/LU62297A1/xx
Priority to BE760696A priority patent/BE760696A/en
Priority to SE7017390A priority patent/SE371814B/xx
Priority to ES386744A priority patent/ES386744A1/en
Priority to CH1898570A priority patent/CH529095A/en
Priority to JP70115229A priority patent/JPS5339403B1/ja
Application granted granted Critical
Publication of FR2071278A5 publication Critical patent/FR2071278A5/en
Expired legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/06—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms
    • C07C209/08—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00083—Coils

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Tert. aliphatic amine preparation by amination of alkyl halide with an aliphatic sec. amine takes place by preparing a reaction mixture in 2 parts. First consists of least one alkyl halide, predominantly 1-haloalkane, and second of an aliphatic sec. amine in a dipolar aprotic solvent, suitable for dissolving halide and sec. amine but not dissolving the tertiary amine when cold. First part pref. contains >=85 wt.% 1-haloalkane, pref. 4-22 (8-18) C alkyl bromide or -chloride, more pref. prepared by radical hydrohalogenation of alpha-olefins. Pref. each alkyl group of sec. amine NHR'R" has 1-18 (1-4)C atoms. Pref. solvents are DMF, hexamethyl phosphotriamide, THF and N-methyl pyrrolidone, pref. in 0.8-2 wt./wt. alkyl halide. Pref. mole ratio sec. amine : alkyl halide is 2 : 1, excess sec. amine being sufficient to bind hydrogen halide released. Pref. process takes place continuously at 20-150 degrees C., 2 bar. Pref. sec. amine in solvent and first part are charged upwards into vertical pref. glass reactor, heated with superimposed heating elements with temps. rising towards top. Product flows from top into cooler and decanter.
FR6944604A 1969-12-23 1969-12-23 Tertiary aliphatic amine production by - amination of alkyl halides Expired FR2071278A5 (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
FR6944604A FR2071278A5 (en) 1969-12-23 1969-12-23 Tertiary aliphatic amine production by - amination of alkyl halides
DE2062548A DE2062548C3 (en) 1969-12-23 1970-12-18 Process for the preparation of tertiary aliphatic amines by amination of an alkyl halide with a secondary aliphatic amine
NLAANVRAGE7018610,A NL170728C (en) 1969-12-23 1970-12-21 PROCESS FOR THE PREPARATION OF TERTIARY ALIPHATIC AMINES.
US00099853A US3764626A (en) 1969-12-23 1970-12-21 Method of synthetizing tertiary aliphatic amines by amination of alkyl halides
GB6049370A GB1337285A (en) 1969-12-23 1970-12-21 Method of synthesizing tertiary aliphatic amines by amination of alkyl halides
LU62297D LU62297A1 (en) 1969-12-23 1970-12-22
BE760696A BE760696A (en) 1969-12-23 1970-12-22 PROCESS FOR SYNTHESIS OF TERTIARY ALIPHATIC AMINES BY AMINATION OF ALKYL HALOGENIDES
SE7017390A SE371814B (en) 1969-12-23 1970-12-22
ES386744A ES386744A1 (en) 1969-12-23 1970-12-22 Method of synthetizing tertiary aliphatic amines by amination of alkyl halides
CH1898570A CH529095A (en) 1969-12-23 1970-12-22 Continuous or batch process for the production of tertiary aliphatic amines by amination of alkyl halides
JP70115229A JPS5339403B1 (en) 1969-12-23 1970-12-22

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR6944604A FR2071278A5 (en) 1969-12-23 1969-12-23 Tertiary aliphatic amine production by - amination of alkyl halides

Publications (1)

Publication Number Publication Date
FR2071278A5 true FR2071278A5 (en) 1971-09-17

Family

ID=9045043

Family Applications (1)

Application Number Title Priority Date Filing Date
FR6944604A Expired FR2071278A5 (en) 1969-12-23 1969-12-23 Tertiary aliphatic amine production by - amination of alkyl halides

Country Status (1)

Country Link
FR (1) FR2071278A5 (en)

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