FI75606B - RENGOERINGSFOERFARANDE OCH -ANORDNING FOER KATOD- OCH / ELLER ANODPLATTOR. - Google Patents

Description

1 75606

Cleaning method and apparatus for cathode and / or anode plates

The present invention relates to a cleaning method 5 and apparatus for cathode and / or anode plates, in particular Cu cathode plates, obtained by electrolytic cleaning of metals, which are lifted in groups suspended from rods or lugs from an electrolysis bath and washed by water jets.

10 Electrolytic cleaning of copper takes place in electrolysis baths or electrolyte solutions, with pure copper adhering as cathode plates to base plates, which are thin plates of pure copper. These base plates are provided with loops from which they are hung in groups of 15 on rods at predetermined distances from each other in electrolysis baths. A method and an apparatus for producing base plates for electrolytic cleaning are described, for example, in DE patents 2,618,679 and 2,644,631. Pure copper adheres to base plates which hang in an electrolysis bath, initially becoming very thin base plates, preferably 0.8 mm thick, weighing 100 kg or more. These cathode plates are usually suspended on electrolysis baths in groups of 8, 16, 32 or 64 plates and, after being cleaned with copper, are also lifted out of the baths in groups of 8, 16, 32 or 64 plates.

The cathode plates must be washed after they have been removed from the electrolysis bath so that they are cleaned of electrolyte solution waste. For this purpose, the cathode plates 30 are usually suspended on support rods and passed through the washing device successively with their flat sides in a vertical position and the distances between the cathode plates then corresponding to the distances between the cathode plates in the electrolysis bath. Since these distances are generally relatively small, for example about 10 to 12 cm, it is possible to spray the flat sides of the cathode plates through the washing device only from the side surfaces or from the top and bottom with water jets. It has now been found that the washing result of the cathode plates is generally unsatisfactory and that impurities, in particular waste electrolyte solution, remain in the cathode plates. After washing, the support rods are removed from the cathode plates so that they can be reused. The cathode plates detached from the rods are then stacked to form plate bundles.

It is an object of the invention to provide, for cathode and / or anode plates obtained by electrolytic cleaning, an improved cleaning method which achieves a very high degree of cleaning of the plates.

This object is solved in the case of cathode plates by the method according to the invention, which is characterized by the features set forth in the first claim, and in the case of anode plates by the second method according to the invention, which is characterized by the feature part of the second claim.

The method according to the invention has the advantage that the Todi and / or anode plates can be sprayed on all sides, including the flat sides, with reduced power by means of water jets, since they are no longer transferred through the washing device to the rods or cores in successive groups at short distances from each other. relative to the pages.

According to the invention, it is advantageous to remove the rods before washing the cathode plates and to wash them afterwards. This has the advantage that the cleaning of the cathode plates is considerably improved, since the rods are removed before washing and thus prevent contaminants from remaining in the area between the rods and the loops, where the water jets do not reach.

35 The cathode and / or anode plates are preferably supported at various points on their surface, if possible by means of pins 3 75606 or linearly, specifically at their lower edge, or when rotated 180 ° vertically, from their upper side and preferably washed in a substantially vertical position and / or by successively passing the anode plates through a mini-stage washing process. It may be advantageous for the cathode and / or anode plates to move during the washing process so that their flat sides are parallel to the conveying direction in order to move the plates successively to different stages of the washing process.

According to the invention, the removal of the rods can take place as an ejection function and / or by pulling them out of the loops of the cathode plates.

In one embodiment of the method according to the invention, the loops are cut open to remove the rods and preferably bent upwards. The advantage of this method is that the rods are easier to remove and the insides of the loops that have been cut open and preferably bent upwards can be cleaned more easily.

In another embodiment of the method according to the invention, the loops are completely cut off from the roof plates. The advantage of this method is that the loops can be washed separately from the cathode plates and rods. However, it may also be advantageous that the loops detached from the bars are then added to the crude copper.

According to the invention, it is advantageous to wash the rods after they have been removed from the cathode plates. The rods can then be stacked in the tank. When using bars with a cross-section that increases the transport capacity and whose dimensions are larger vertically than horizontally, according to the invention the bars can be placed in the container so that their cross-sectional profile comes in a predetermined direction.

The device 35 according to the invention used for the application of the above-mentioned method for cathode plates is characterized by the features set forth in the sixth claim 4,75606. Accordingly, the device according to the invention used for applying the method for anode plates is characterized by the features set forth in the ninth claim.

In a modified apparatus according to the invention, the plates can be guided through the washing device in pairs on a second conveyor inclined upwards to form a V-shape, moved against each other after the washing device and then stacked together.

Other preferred constructions of the device according to the invention are set out in claims 11 to 25.

The invention is described below with the aid of schematic drawings related to structural examples. In the drawings 15, Fig. 1 is a schematic plan view of an apparatus in which cathode plates are washed by the method of the invention; Fig. 2 is a side view of the apparatus of Fig. 1, Fig. 3 shows transfer of cathode plates from a first to a second chain conveyor, Fig. 4 is an enlarged plan view, Figs. rod stacking and turning device in two different positions, Figures 7 and 8 show plan and side views of the arrangement of spray nozzles in the washing chambers, Figures 9 and 10 show, first and side views, respectively, a first structural example of a washed cathode plate removal and stacking device , Figures 11 and 12 show a front and side view, respectively, of another structural example of a washed cathode plate removal and stacking device, Figure 13 shows the gripping portion of the removal and stacking device of Figures 11 and 12, and Figure 14 shows a modified transfer device.

Il 5 75606

The device shown as a structural example in Figures 1 and 2 and used to apply the method according to the invention comprises a feed device 2 with a first chain conveyor 4 comprising two chain tracks. Cathode plates 6 are arranged in the chain conveyor 4 and removed in groups by a crane or similar electrolysis baths. and suspended, for example, in units of 8, 16, 32 or 64 plates from the loops 8 to the support rods 10, the plates being then conveyed then perpendicular to their flat sides. The motor 12 drives the chain conveyor 4 periodically. At the end of the conveyor 4 there is a second chain conveyor 14, which is also used intermittently and to which the cathode plates 6 are transferred one by one by a first transfer device 21 and which conveys them further parallel to their flat sides through a washing device 16 to a second transfer device 18.

The second chain conveyor 14 comprises only one chain track. The outer circumference of the track is provided with support parts 22 (ku-20 va 3), the upper end of which has a large, outwardly extending groove 24 in which the lower edge of the cathode plates 6 is placed. In every second support part 22, the groove at its rear end, viewed in the conveying direction, is provided with a transverse wall 26, which ensures that the cathode plate 6 in the groove remains therein.

The transfer of the cathode plates from the first to the second chain conveyor takes place at the return point 21 of the first chain conveyor, whereby this conveyor releases the rods 10 comprising the cathode plates 6 one by one as its chains move to the lower track. The plates 6 first remain upright and support the second chain conveyor 14 5 ° inclined in the direction of the previous conveyor on adjustable rails or rollers 27, 28 as shown in detail in Figure 3. To remove the rods 10 from the loops 8, a movable push rod 52 of the hydraulic cylinder 50 is provided, which engages the end face of the rods 10 on the washing machine 16 6 75606 and moves the rods until their other end enters the operating range of the conveyor rollers 54 which pull the rods 10 completely out. of loops 8.

5 The rods pass through the washing machine 56 (Fig. 4) if they are cleaned of impurities. The rods 10 are then stacked by a stacking device 58 in a container 94. In order to obtain rods of rectangular cross-section, oval or teardrop-shaped in the uniform position required for their subsequent use, the stacking device 58 is constructed as a hydraulically operated turning device. It has two double-arm levers 60, as shown in Figures 5 and 6, fixed non-rotatably to the shaft 62. In each case, the shaft is fixed at its ends as a rotating structure to a first slider 64 which moves on a guide rail 66 to a second slider 68 supported by a spring 70 to the body of the device 72.

The second arm 74 of the double arm levers 60 has a claw recess 76 corresponding to the profile of the rods 10 into which the rods are inserted when they are pulled out of the cathode plate 6. The second arm 78 of the double arm lever 60 is connected by arm 80 to an arm 82 secured by a horizontal intermediate 83 to the second slider 68. The lever arm 84 is mounted non-rotatably in the center of the shaft 62 having the double arm levers 60 and engages the piston rod 86 of the hydraulic cylinder 88 with the cylinder 88 articulated to the shaft 90 of the device 72.

When the piston rod 86 is retracted, the claws 76 are in a position in which their opening is in line with the axis of the rods 10 drawn from the loops 8 of the cathode plates 6.

With the piston rod 86 out, the bars 10 in the claws 76 pivot 90 ° and are lowered onto the rails 92,

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75606 arranged in a container 94 which can accommodate a large number of rods 10 (Figure 2).

The container 94 can be adjusted vertically so that the rods 10 can be pushed onto rails 92 which are arranged one on top of the other. Once the tank is filled, it is transported away so that the rods can be reused and the empty tank replaced with the tank that was removed.

The second chain conveyor 14 carries the cathode plates detached from the rods 10. Before these plates enter the washing chambers of the washing device 16, they are moved by means of guide rails or rollers 29 to an angle of about 5 ° with respect to their previous position. In this position, the plates are conveyed by rails or rollers 30 which hold them in an inclined position as they pass through the washing chambers 31, 32 and 33 15, where the impurities therein are removed by hot water jets directed to both flat surfaces of the plates and also to the loops 8. For this purpose, both longitudinal walls of the washing chambers have spray nozzles 34 arranged at regular intervals 20 at the height of the plates (Figures 7 and 8). In order to also cause the washing liquid to come into contact with the area under the loops 8, nozzles 36 directed to this area are connected to the rinsing water pipe. The washing device is divided into three chambers, the last of which is supplied with clean water, with the previous chambers receiving wastewater from the next chamber corresponding to it.

When the cathode plates come out of the last washing chamber 33, they are further turned by moving them along rollers or rails 38 from the previous inclination position-30 to an inclination of about 45 °. In this position, the gripping device 100 grips their side edges or the area of their upper edge and picks them up at the stacking station.

This device for gripping and transferring the cleaned cathode plates 6 (Figures 9 and 10) comprises a column 106 articulated to the base 102 in a vertical plane perpendicular to the conveying direction 8 75606 of the second chain conveyor 14 and having a cantilever arm 108 at its upper end. whose piston rod 112 engages a lever arm 114 attached to the lower end of the post 106. The U-shaped conveying member 116 is secured to the cantilever arm 108 and pivots on a vertical axis 118. Each leg 120 of the conveying member 116 has a gripping arm 124 pivoting on the shaft 122. The gripping arms have a rear extension 126 the piston rod 127 of one or two hydraulic cylinders 128 attached to the conveying part 116 is connected.

In order to be able to grip the cathode plates 6 in an inclined position in the chain conveyor, the column 106 comprising the transport part 116 is tilted so much that the gripping arms 124 come into the area of the side edges of the cathode plates 6.

When the cylinders 128 are actuated, the gripping arms 124 engage the plates 6. When the column 106 is pivoted back to the vertical position by the hydraulic cylinder 110, the plates 6 move onto a vertically adjustable table 130 where they are stacked. From there, they are then transferred by means of a transport device (not shown in the figures) to the unloading stations.

Since the conveying part 116 is articulated on the vertical axis 118 of the cantilever arm 108, the cathode plates 6 in the gripping arms 124 can be pivoted on said shaft 118 and therefore stacked so that the loops 8 reach the desired position. To provide this pivoting movement, a hydraulic drive 132 is provided in the cantilever arm 108 which reciprocates a rack associated with a gear fixed to a shaft fixedly connected to the transport portion 116.

In the second construction of the gripping and stacking device 100 of the cleaned cathode plates 6 (Figs. 11, 12 and 13), a clamping gripping device 150 attached to the cantilever arm 160 engages the oriented center portion of the upper edge of the plates 6. The hydraulic cylinder 152 opens and closes said gripping device.

Il 75606 9

The gripping device 150 and the hydraulic cylinder 152 are housed in a carriage 154 formed by two flat steel bars 156 connected by an intermediate portion 155 and four wheels 158, which is moved by a second hydraulic cylinder 164 in two U-steels 162 attached to the cantilever 160. The hydraulic cylinder thereof and its piston rod 170 are articulated to arms 166 and 168 attached to the upper end and intermediate portion 155 of the cantilever arm 160, respectively.

The piston rod 172 of the hydraulic cylinder 152 driving the clamping gripping portion 150 is attached to the intermediate portion 155 of the carriage 154. When pressure is applied to the cylinder 152, it pushes back into the carriage and turns the drive member 174

The cantilever arm comprising the carriage 154 and the gripping device 150 is attached to a post 184 which pivots on the horizontal axis 182 perpendicular to the conveying direction of the second chain conveyor 14 at such an angle that the direction of travel of the carriage 154 20 at the second end position A of the post , and in the second end position B again in the horizontal direction. In this position, the cathode plate is moved to the lifting table 130. In order to cause the column 184, the support point 182 of which is located on the base 186, to pivot, a hydraulic cylinder 188 is provided with a piston rod 190 connected to the column 192. When the column is pivoted out of position A has gripped the cathode plates 6, in position B, where the plates move to a horizontal position, they are pulled over the guide surface 193 of the kaa-30 Reva, which is provided with one or more rollers 195 to reduce friction.

The drives 12 and 15 of both chain conveyors 4 and 14 and the drive of the push rod 52 and the stacking devices 20 and 58 are controlled relative to their operating time by a known control device (not shown in the figures) so that the operation of the whole device is flexible.

10 75606

In the construction in which the cathode plates are guided in pairs close to each other through the washing device, each of the two cathode plates entering the transfer device by the first chain conveyor can be placed in the second chain-5 conveyor so that they pass side by side through the washing device.

The cathode plates are tilted upwards relative to each other in a V-shape, opening with a second chain conveyor, so that the spray nozzles can be directed to both the opposite surfaces and the outer surfaces of the cathode plates 10.

After the washing device, the paired cathode plates are moved together and then stacked by the stacking device at the same time.

Fig. 14 shows a device in which the cathode-15 plates 6 are placed in pairs on the support parts 22 'of the chain conveyor 14 passing from the chain conveyor 4 through the washing device 16. For this purpose, a transfer device 200 is provided located at the end of the chain conveyor 4 mainly in the region of its return roller 4a and comprises on each side of said conveyor an upwardly directed arm 202 provided with recesses 204 at its upper end at a distance from cathode plates suspended on the chain conveyor 4. Each arm is attached at its lower end to two lever pins 206 supported by lever arms 210, 25 and 212 attached to two synchronously rotating shafts attached to support arms 207. The support arms 207 are welded to the machine body 209. As soon as the two cathode plates have entered the return roller 4a of the chain conveyor 4, the shafts 208 rotating by a drive not shown 30, the upper end of the arms 202 in the recesses 204 grips the plates and lifts them away from the chain conveyor. 4. As the shafts 208 continue to rotate, the cathode plates are moved over the support portions 22 'of the chain conveyor 14. The plates are guided by guide members 214, 35 215, 216 so that they tilt relative to each other in a V-shape on the support members. The rods 10 are then removed

II

75606 11 of the cathode plate loops with an ejection device corresponding to the devices 50, 52 and the cathode plates are conveyed through the washing device 16 in pairs. In the present case, the support members 22 'preferably have two grooves 222 and 224 which are arranged symmetrically with respect to the center line 220, so that a certain distance is also given to the cathode plates in the lower region.

It is also possible to construct the transfer device 200 so as to lift the cathode plates in bundles of three plates 10 from the chain conveyor 4 and fan them onto the support parts of the chain conveyor 14. In this case, the arms 202 are provided with three recesses 204 spaced apart from the cathode plates to lift the three cathode plates from the conveyor simultaneously.

The transfer device 200 is preferably designed so that the middle of the three cathode plates is lowered substantially into the region of the centerline 220. The middle plate remains in an approximately vertical position by means of a suitable control device. Said center plate guide device preferably extends for 20 minutes from the end side of the conveyor 14 from the support portion 22 'to the right and left of the center line 220 in substantially the same plane as the guide 216 extends to the transfer area. In the next washing device 16 in sequence, the respective guides can be arranged for the three cathode plates above the chain-25 conveyor 14.

When moving three cathode plates at a time, it is preferred that the support portions 22 'of the chain conveyor 14 be provided with three grooves to keep the lower ends of the three plates at a predetermined distance from each other.

It is also possible to design the transfer devices and control devices so that more than three cathode plates are placed in a fan-like manner on the support parts of the chain conveyor 14 at a time.

If two or three or more cathode plates are placed on the chain conveyor 14 at a time, inclined approximately V-shaped or substantially fan-shaped relative to each other, the washing device 16 comprises additional nozzles extending between two, three or more cathode plates from above and spraying in this case, behind the washing device 5, guiding devices are arranged which move two, three or more cathode plates relatively close to each other, so that the gripping parts 116 intended to grip more than one plate can grip them together to transfer them to the table 130.

Instead of the transfer device according to Fig. 3, the transfer device of Fig. 14 can be used to transfer one cathode plate at a time, if the arms 202 are designed accordingly and each is provided with only one recess 204.

15 The washing of the cathode plates is described in the above-mentioned description of the drawings. The anode plates can be washed in the same way, so that there are no rods to be removed, and therefore the removal of the rods is omitted. However, in the case of scrap anodes with an uneven bottom edge, it is preferable to use instead of or in combination with the transfer device a gripping device which grips the anode plates in the area of their side edges, in particular in the area of the side edges of their lugs. lifts the first anode plate from the chain conveyor 4 or the arms of the transfer device 200 when the arms 202 are in their highest position and then turns the anode plate upside down at its upper edge onto the support portions of the chain conveyor 14 substantially V-shaped or substantially fan-like relative to each other.

Il

Claims (13)

13 75606 A cleaning method for the electrolytic cleaning of metals, in particular copper, for cathode plates obtained from an electrolytic bath 5, the cathode plates being lifted from the electrolysis bath in groups suspended from support rod support loops and then washed by water jets, characterized in that by pulling them from the carrier loops or by cutting and / or detaching the carrier loops and the cathode plates are supported at their lower edges in a substantially vertical position individually or in pairs approximately V-shaped inclined relative to each other or three or more plates together expensive apart, in a direction parallel to the flat sides and at least the flat sides of the plates are sprayed with jets performing relative movement along the flat sides 20. 2. A cleaning method for the electrolytic cleaning of metals, in particular copper, for anode plates obtained from an electrolytic bath, the anode plates being lifted from the electrolysis bath in support loops in groups 25 and then washed with water jets, characterized in that the anode plates are supported in a substantially vertical position or three or more plates together tilted apart by a chain conveyor and in the above position the plates pass through a step approximately parallel to their flat sides and at least the flat sides of the plates are sprayed with jets performing relative movement along the flat sides. A method according to claim 2, characterized in that the scrap anodes to be washed are placed upside down and washed at the top with the support of a chain conveyor. A method according to claim 1, characterized in that the support rods removed from the cathode plates are washed separately and, after washing, are stacked in a warehouse, Method according to Claim 1 or 4, characterized in that when rods with a load-bearing, in particular rectangular, cross-sectional profile having greater dimensions at a height of 10 than in width are used, the rods are placed in the container by orienting their cross-sectional profile in advance. Apparatus for applying the method according to one or more of claims 1, 4 and 5, comprising a conveying device for receiving and feeding the cathode plates suspended on support bars to a washing device through which the cathode plates are guided and sprayed with water, characterized in that the conveying device comprises a first chain conveyor (4) , which takes the cathode plates in groups and whose transport direction is perpendicular to the flat sides of the cathode plates (6) and at the end of which is arranged a transfer device (21; 200) which moves the cathode plates (6) individually or in pairs approximately V-shaped or three or more plates tilted apart substantially fan-shaped to a second chain conveyor (14) having a conveying direction parallel to the flat sides of the cathode plates (6), the transfer device (21) being provided with a device (50, 54) for pushing out and pulling out the support rods (10) ), which detaches the can rods (10) when the cathode plates 30 have been transferred to the second chain conveyor (14), and that the second chain conveyor (14) successively conveys the substantially vertical or inclined cathode plates (6) through the washing device (16), and that the washing device (16) is connected a stacking device (20) for stacking the cleaned cathode plates 35 (6) in bundles. Il 15 75606 Device according to Claim 6, characterized in that in the device for pushing out and pulling out the support rods (10), the support rods are moved a first distance by the hydraulic push rod (52) and then pulled completely out of the loops (8) by means of transport rollers (54). in the region of or behind the transport rollers (54) there is a washing device (56) for the support bars (10), which is connected to a support bar stacking device (58) which stacks the support bars (10) 10 in the storage (94). Device according to Claim 7, characterized in that when using support bars (10) with a load-bearing cross-sectional profile having greater dimensions in height than in width, the stacking device (58) for the support bars (10) is provided with gripping parts (76). adapted to the cross-sectional profile of the support bars so as to place the support bars (10) in the warehouse (94) so that their cross-sectional profile is uniformly oriented in a predetermined manner by rotating the support bars (10) preferably 90 ° about their longitudinal axis (94) with their larger cross-sectional dimension in the horizontal direction. Apparatus for applying the method 25 according to claim 2 or 3, comprising a conveying device for receiving and feeding the anode plates suspended in its carrier loops to a washing device through which the anode plates are guided and sprayed with water, characterized in that the conveying device comprises a first chain conveyor (4). and in which the conveying direction is perpendicular to the flat sides of the anode plates and at the end of which a transfer device (21; 200) is arranged which transfers the anode plates individually or in pairs approximately V-shaped inclined with respect to each other 35 or three or more plates inclined apart in a substantially fan-like manner ° 6 (14), the conveying direction of which is parallel to the flat sides of the anode plates, and that the second chain conveyor (14) conveys the substantially vertical or inclined anode plates successively through the washing device (16), and that the washing-5 device (16) ) is connected to a stacking device (20) for stacking cleaned anode plates in bundles. Device according to Claim 9, characterized in that a transfer device 10 for holding the scrap anode plates in place of or in combination with the transfer device (200) grips the scrap anode plates in the region of their front faces, in particular in the front faces of their carrier loops. 4) or from the transfer device (200) and then turned so that they 15 are placed upside down on their upper sides in the support parts (22; 22 ') of the chain conveyor (14). Device according to one or more of Claims 6 to 10, characterized in that the second chain conveyor has support parts (22; 22 ') with at least one upwardly widening groove (24; 222; 224), and in that the plates (6 ) when moving from the first (4) to the second chain conveyor (14) the lower or upper edge of the plates is placed in the support parts (22; 22 '), and stops (27, 28; 214, 215, 216) are provided which hold the plates (6) during a position 25 inclined by at least about 5 ° in the conveying direction of the first chain conveyor (4). Device according to one or more of Claims 6 to 11, characterized in that the washing device for the plates (6) has three chambers (31, 32, 33) in which spray nozzles (34) are arranged at the height of the plates (6) divided by the plates (6). to spray the flat sides, and that pure water is supplied to the last chamber (33) in the direction of movement of the plates (6), and waste water is supplied to the previous chambers (31, 32) from the next corresponding chamber 35 (32, 33), and that the washing device (16) is and / or roller guides (38) which pivot the plates (6) in all II. 75606 to about 45 °, and a vertically movable table (130) is provided for stacking the washed plates (6), to which is connected a column (106, 184) comprising a cantilever arm (108, 160) which pivots on a horizontal axis (104, 5). 182) in the direction of the inclined plates (6), and comprises a U-shaped gripping part (116) engaging the side edges of the inclined plates (6) and pivotally attached to the vertical axis (118) of the cantilever arm (108), placing the plates (6) horizontally on a table ( 130), or comprises a gripping part (150) which grips the front edge of the inclined plates (6) and, as the column (184) pivots back, pulls the plates over the curved guide surface (193) to a horizontal position. Device according to one or more of Claims 6 to 12, characterized in that the second chain conveyor (14) is provided with support parts (22 ') for receiving always two V-shaped plates (6) or three or more fan-inclined plates. to receive the plate (6), and that the washing device (16) has nozzles (34) which spray between two, three or more plates and their outer surfaces, and that control devices are arranged behind the washing device to control two, three or more plates substantially attached to each other so that the gripping members can grip them together to stack them on the table (130). 75606