FI66019B - Foerfarande foer selektiv hydrering av triglyceridolja - Google Patents

Foerfarande foer selektiv hydrering av triglyceridolja Download PDF

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Publication number
FI66019B
FI66019B FI783817A FI783817A FI66019B FI 66019 B FI66019 B FI 66019B FI 783817 A FI783817 A FI 783817A FI 783817 A FI783817 A FI 783817A FI 66019 B FI66019 B FI 66019B
Authority
FI
Finland
Prior art keywords
catalyst
hydrogenation
oil
reactor
acetone
Prior art date
Application number
FI783817A
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English (en)
Finnish (fi)
Other versions
FI66019C (fi
FI783817A (fi
Inventor
Jan Kuiper
Original Assignee
Unilever Nv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever Nv filed Critical Unilever Nv
Publication of FI783817A publication Critical patent/FI783817A/fi
Publication of FI66019B publication Critical patent/FI66019B/fi
Application granted granted Critical
Publication of FI66019C publication Critical patent/FI66019C/fi

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/12—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fats And Perfumes (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Claims (12)

1. Förfarande för selektiv hydrering av triglyceridolja, som inne-häller flere än en dubbelbindning mellan kolatomerna, i närvaro av en katalytiskt aktiv metall ur gruppen VIII i det periodiska systemet, som kan vara promoterad av en metall ur en annan grupp i nämnda system kännetecknat därav, att katalyten är behandlad med en basisk förening med formeln AX, där A Mr antingen RiR2R3R4N+? R2» R3» och R4 är var och en en alkyl-, cykloalkyl-, aryl- eller aralkylgrupp med 1-20 kol-atomer, som kan vara substituerad, eller A är ett grundämne ur gruppen I eller II i det periodiska systemet, eller ammonium, och X är hydroxyl; en svag syras anjon eller RO-, där R är en alkyl-grupp.
2. Förfarande enligt patentkravet 1, kännetecknat därav, att katalyten behandlas med en basisk förening före den sättes tili föreningen, som skall hydreras.
3. Förfarande enligt patentkravet 1, kännetecknat därav, att den basiska föreningens överskott avskiljes frän katalyten före katalyten tillsättes föreningen, som skall hydreras.
4. Förfarande enligt patentkravet 1, kännetecknat därav, att basiska föreningen tillsättes direkt föreningen, som skall hydreras.
5. Förfarande enligt patentkravet 4, kännetecknat därav, att basiska föreningen tillsättes 0,1 - 100 mol per m·^ förening, som skall hydreras.
6. Förfarande enligt n&got av patentkraven 1-5, kännetecknat därav, att den basiska föreningen loses i vatten eller i en organisk vätska eller deras blandning.
7. Förfarande enligt nägot av patentkraven 1-6, kännetecknat därav, att som basisk förening användes hydroxid.
FI783817A 1977-12-19 1978-12-13 Foerfarande foer selektiv hydrering av triglyceridolja FI66019C (fi)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB5275077 1977-12-19
GB5275077 1977-12-19

Publications (3)

Publication Number Publication Date
FI783817A FI783817A (fi) 1979-06-20
FI66019B true FI66019B (fi) 1984-04-30
FI66019C FI66019C (fi) 1984-08-10

Family

ID=10465150

Family Applications (1)

Application Number Title Priority Date Filing Date
FI783817A FI66019C (fi) 1977-12-19 1978-12-13 Foerfarande foer selektiv hydrering av triglyceridolja

Country Status (20)

Country Link
US (1) US4228088A (sv)
JP (1) JPS5498702A (sv)
AT (1) AT374819B (sv)
AU (1) AU521426B2 (sv)
BE (1) BE872854A (sv)
CA (1) CA1117972A (sv)
CH (1) CH639928A5 (sv)
DE (1) DE2854814A1 (sv)
DK (1) DK564678A (sv)
ES (1) ES476146A1 (sv)
FI (1) FI66019C (sv)
FR (1) FR2411818B1 (sv)
GB (1) GB2010309B (sv)
IN (1) IN148810B (sv)
IT (1) IT1109645B (sv)
NL (1) NL7812288A (sv)
NO (1) NO784259L (sv)
PT (1) PT68929A (sv)
SE (1) SE436428B (sv)
ZA (1) ZA787074B (sv)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7904781A (nl) * 1979-06-19 1980-12-23 Unilever Nv Werkwijze voor het selectief hydrogeneren van vetzuur- derivaten.
NL7904782A (nl) * 1979-06-19 1980-12-23 Unilever Nv Werkwijze voor het selectief hydrogeneren van vetzuurderivaten.
EP0061337A1 (en) * 1981-03-25 1982-09-29 Johnson Matthey Public Limited Company Catalytic process
US4424162A (en) 1981-08-31 1984-01-03 Uop Inc. Selective hydrogenation of fatty materials
NL8302590A (nl) * 1983-07-20 1985-02-18 Unilever Nv Nikkelboride in olie katalysator.
AU564008B2 (en) * 1984-07-11 1987-07-30 Unilever Plc Hydrogenation products
FR2573999B1 (fr) * 1984-12-05 1987-01-23 Rhone Poulenc Spec Chim Procede de fabrication de supports de catalyseurs a base d'alumine dont la durabilite est amelioree
US5225581A (en) * 1990-06-14 1993-07-06 Tulane Educational Fund Electrocatalytic process for the hydrogenation of edible and non-edible oils and fatty acids
US5208405A (en) * 1992-03-03 1993-05-04 Phillips Petroleum Company Selective hydrogenation of diolefins
US7585990B2 (en) * 2003-07-31 2009-09-08 Cargill, Incorporated Low trans-fatty acid fat compositions; low-temperature hydrogenation, e.g., of edible oils
EP1656439A4 (en) * 2003-07-31 2010-11-10 Cargill Inc FAT COMPOSITIONS WITH LOW TRANS-FATTY ACID CONTENT; TIEFTEMPERATURHYDRIERUNG, eg OF EDGE OILS

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1893155A (en) * 1932-06-18 1933-01-03 Catalyst Research Corp Hydrogenation process and catalyst therefor
BE564339A (sv) * 1957-02-05 1900-01-01
GB886477A (en) * 1958-03-31 1962-01-10 Engelhard Ind Inc Selective hydrogenation of fatty oils
GB932991A (en) * 1959-02-02 1963-07-31 Asahi Denka Kogyo Kk Method for producing a copper containing catalyst
US3117939A (en) * 1960-01-25 1964-01-14 Wesson Oil & Snowdrift Co Inc Hydrogenation catalysts
DE1181700B (de) * 1961-05-20 1964-11-19 Basf Ag Verfahren zur partiellen Hydrierung von cycloaliphatischen, mindestens zwei olefinische Doppelbindungen enthaltenden Verbindungen zu cycloaliphatischen Monoolefinen
US3201431A (en) * 1963-03-19 1965-08-17 Swift & Co Selective hydrogenation of malvalic and sterculic acids in cottonseed oil
US3919271A (en) * 1968-05-08 1975-11-11 Du Pont Catalysis by dispersions of metal halides in molten trihalostannate (II) and trihalogermanate (II) salts
IT963424B (it) * 1972-07-27 1974-01-10 Snam Progetti Processo di idrogenazione di idro carburi diolefinici a idrocarburi olefinici
JPS5338719B2 (sv) * 1972-12-25 1978-10-17
US3980720A (en) * 1972-12-25 1976-09-14 Toyo Soda Manufacturing Co., Ltd. Method of producing diol by hydrogenolysis of peroxide polymers with reactivation of Raney nickel catalyst
FR2259896B1 (sv) * 1974-02-01 1978-03-24 Inst Francais Du Petrole
FR2297241A1 (fr) * 1975-01-08 1976-08-06 Inst Zhirov Procede de transformation des graisses animales en graisse alimentaire plastique
US4117242A (en) * 1976-07-26 1978-09-26 Phillips Petroleum Company Suppression of side reactions in catalytic hydrogenation of diesters
CA1109855A (en) * 1976-11-24 1981-09-29 Jan F. Van Peppen Production of cyclohexanone

Also Published As

Publication number Publication date
FR2411818A1 (fr) 1979-07-13
GB2010309B (en) 1983-02-02
SE7813005L (sv) 1979-06-20
SE436428B (sv) 1984-12-10
ZA787074B (en) 1980-08-27
US4228088A (en) 1980-10-14
AU521426B2 (en) 1982-04-01
FR2411818B1 (fr) 1985-10-11
IT7869883A0 (it) 1978-12-18
CH639928A5 (de) 1983-12-15
JPS5498702A (en) 1979-08-03
FI66019C (fi) 1984-08-10
ES476146A1 (es) 1979-12-01
DK564678A (da) 1979-06-20
IT1109645B (it) 1985-12-23
AT374819B (de) 1984-06-12
CA1117972A (en) 1982-02-09
PT68929A (en) 1979-01-01
FI783817A (fi) 1979-06-20
BE872854A (fr) 1979-06-18
GB2010309A (en) 1979-06-27
NO784259L (no) 1979-06-20
NL7812288A (nl) 1979-06-21
IN148810B (sv) 1981-06-20
AU4259678A (en) 1979-06-28
ATA903078A (de) 1983-10-15
DE2854814A1 (de) 1979-06-21

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Owner name: UNILEVER N.V.