FI125164B - Menetelmä ja laitteisto pyrolyysituotteen valmistamiseksi - Google Patents

Menetelmä ja laitteisto pyrolyysituotteen valmistamiseksi Download PDF

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Publication number
FI125164B
FI125164B FI20125784A FI20125784A FI125164B FI 125164 B FI125164 B FI 125164B FI 20125784 A FI20125784 A FI 20125784A FI 20125784 A FI20125784 A FI 20125784A FI 125164 B FI125164 B FI 125164B
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FI
Finland
Prior art keywords
pyrolysis
boiler
product
combustor
apparatus comprises
Prior art date
Application number
FI20125784A
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English (en)
Swedish (sv)
Other versions
FI20125784A (fi
Inventor
Jani Lehto
Original Assignee
Teknologian Tutkimuskeskus Vtt Oy
Valmet Technologies Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teknologian Tutkimuskeskus Vtt Oy, Valmet Technologies Oy filed Critical Teknologian Tutkimuskeskus Vtt Oy
Priority to FI20125784A priority Critical patent/FI125164B/fi
Priority to PCT/FI2013/050737 priority patent/WO2014006273A1/en
Priority to US14/412,947 priority patent/US10059883B2/en
Priority to CA2877967A priority patent/CA2877967C/en
Priority to EP13813352.5A priority patent/EP2870221B1/en
Publication of FI20125784A publication Critical patent/FI20125784A/fi
Application granted granted Critical
Publication of FI125164B publication Critical patent/FI125164B/fi

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
    • C10B49/22—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B21/00—Heating of coke ovens with combustible gases
    • C10B21/10—Regulating and controlling the combustion
    • C10B21/18—Recirculating the flue gases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B27/00—Arrangements for withdrawal of the distillation gases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
    • C10B49/04—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated
    • C10B49/08—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form
    • C10B49/10—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form according to the "fluidised bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • C10B57/06—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/006—General arrangement of incineration plant, e.g. flow sheets
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F23G5/14—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
    • F23G5/16—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/30—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a fluidised bed
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/10—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of field or garden waste or biomasses
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/026—Dust removal by centrifugal forces
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00—Pretreatment
    • F23G2201/30—Pyrolysing
    • F23G2201/303—Burning pyrogases
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00—Pretreatment
    • F23G2201/30—Pyrolysing
    • F23G2201/304—Burning pyrosolids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Environmental & Geological Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)
  • Gasification And Melting Of Waste (AREA)

Claims (9)

1. Menetelmä pyrolyysituotteen valmistamiseksi, jossa pyrolyysireaktoriin syötetään raaka-ainetta ja muodostetaan kaasumaisia pyrolyysituotejakeita ja sivutuotejakeita raaka-aineesta pyrolyysillä pyro-lyysireaktorissa, ja kondensoidaan kaasumaiset pyro-lysituotejakeet nestemäisiksi pyrolyysituotejakeiksi, tunnettu siitä, että menetelmä käsittää vaiheet - poltetaan vähintään yhtä pyrolyysireaktorista peräisin olevaa sivutuotejaetta, joka käsittää kiintoainekomponentteja, vähintään kahdessa polttolaitteessa siten, että sivutuotejae poltetaan osittain ensimmäisessä polttolaitteessa, sivutuote jakeen kiintoainekomponentit kierrätetään takaisin pyrolyysiprosessiin ja ensimmäisestä polttolaitteesta peräisin olevat savukaasut syötetään toiseen polttolaitteeseen, jossa savukaasut poltetaan energian muodostamiseksi, ja - otetaan talteen polttolaitteessa muodostunut energia.
2. Patenttivaatimuksen 1 mukainen menetelmä, tunnettu siitä, että säädetään lämpötilaa ensimmäisessä polttolaitteessa siten, että lämpötila on alle 700 °C.
3. Patenttivaatimuksen 1 tai 2 mukainen menetelmä, tunnettu siitä, että energia, joka otetaan talteen polttolaitteessa, syötetään syöttöveteen ja/tai kattilan höyrypiiriin.
4. Laitteisto pyrolyysituotteen valmistamiseksi, joka laitteisto käsittää - pyrolyysireaktorin (1) kaasumaisten pyrolyysituote j akeiden (3) ja sivutuotejakeiden (4,13,14,19) muodostamiseksi raaka-aineesta (5) pyrolyysillä, ja - vähintään yhden välineen raaka-aineen (5) syöttämiseksi pyrolyysireaktoriin (1), ja - kondensointilaitteen (15) kaasumaisten pyro-lysituotejakeiden (3) kondensoimiseksi nestemäisiksi pyrolyysituotejakeiksi (20), tunnettu siitä, että laitteisto käsittää - vähintään kaksi polttolaitetta (7,8), joissa poltetaan vähintään yhtä pyrolyysireaktorista (1) peräisin olevaa sivutuotejaetta (4,13,14,19), joka käsittää kiintoainekomponentteja, siten että sivutuotejae poltetaan osittain ensimmäisessä polttolaitteessa (7) ja ensimmäisestä polttolaitteesta peräisin olevat savukaasut (12) poltetaan toisessa polttolaitteessa (8) energian muodostamiseksi, - erotuslaitteen kiintoainekomponenttien (13, 14) erottamiseksi savukaasuista (12) ensimmäisen polttolaitteen (7) jälkeen ja välineet kiintoainekomponenttien kierrättämiseksi takaisin pyro-lyysiprosessiin, ja - välineet (9) polttolaitteessa (7,8) muodostuneen energian ottamiseksi talteen.
5. Patenttivaatimuksen 4 mukainen laitteisto, tunnettu siitä, että laitteisto käsittää säätölaitteen lämpötilan säätämiseksi ensimmäisessä polttolaitteessa (7) siten, että lämpötila on alle 700 °C.
6. Patenttivaatimuksen 4 tai 5 mukainen laitteisto, tunnettu siitä, että laitteisto käsittää kattilan (2) energiajakeiden (10,11) muodostamiseksi.
7. Jonkin patenttivaatimuksista 4-6 mukainen laitteisto, tunnettu siitä, että laitteisto käsittää välineet polttolaitteesta (7,8) talteen otetun energian syöttämiseksi syöttöveteen (17).
8. Jonkin patenttivaatimuksista 4-7 mukainen laitteisto, tunnettu siitä, että laitteisto käsittää välineet polttolaitteesta (7,8) talteen otetun energian syöttämiseksi kattilan (2) höyrypiiriin.
9. Jonkin patenttivaatimuksista 4-8 mukainen laitteisto, tunnettu siitä, että laitteisto käsittää lämmönvaihtimen (9) lämpöenergian ottamiseksi talteen sivutuotejakeen savukaasuista (12).
FI20125784A 2012-07-06 2012-07-06 Menetelmä ja laitteisto pyrolyysituotteen valmistamiseksi FI125164B (fi)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FI20125784A FI125164B (fi) 2012-07-06 2012-07-06 Menetelmä ja laitteisto pyrolyysituotteen valmistamiseksi
PCT/FI2013/050737 WO2014006273A1 (en) 2012-07-06 2013-07-05 Method and apparatus for producing a pyrolysis product
US14/412,947 US10059883B2 (en) 2012-07-06 2013-07-05 Method for producing a pyrolysis product
CA2877967A CA2877967C (en) 2012-07-06 2013-07-05 Method and apparatus for producing a pyrolysis product
EP13813352.5A EP2870221B1 (en) 2012-07-06 2013-07-05 Method and apparatus for producing a pyrolysis product

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20125784 2012-07-06
FI20125784A FI125164B (fi) 2012-07-06 2012-07-06 Menetelmä ja laitteisto pyrolyysituotteen valmistamiseksi

Publications (2)

Publication Number Publication Date
FI20125784A FI20125784A (fi) 2014-01-07
FI125164B true FI125164B (fi) 2015-06-30

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Family Applications (1)

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FI20125784A FI125164B (fi) 2012-07-06 2012-07-06 Menetelmä ja laitteisto pyrolyysituotteen valmistamiseksi

Country Status (5)

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US (1) US10059883B2 (fi)
EP (1) EP2870221B1 (fi)
CA (1) CA2877967C (fi)
FI (1) FI125164B (fi)
WO (1) WO2014006273A1 (fi)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2503065B (en) 2013-02-20 2014-11-05 Recycling Technologies Ltd Process and apparatus for treating waste comprising mixed plastic waste
CA2967668A1 (en) * 2014-11-17 2016-05-26 Anellotech, Inc. Processes for handling char in a catalytic fast pyrolysis process and char compositions
RU2763026C2 (ru) 2014-12-17 2021-12-24 Пилкингтон Груп Лимитед Печь
EP3081622A1 (de) * 2015-04-15 2016-10-19 L'AIR LIQUIDE, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren und anlage zur verbesserten herstellung von pyrolyseteer
FI127201B (fi) 2015-04-17 2018-01-31 Valmet Technologies Oy Pyrolyysihöyryjen katalyyttinen jalostus
EP4139418A1 (en) * 2020-04-20 2023-03-01 Teknologian Tutkimuskeskus VTT OY Method and apparatus for producing hydrocarbons and use
CN112460598B (zh) * 2020-12-02 2022-12-16 上海能辉科技股份有限公司 一种垃圾热解炉与燃煤锅炉多段耦合系统及工艺
US12043801B2 (en) * 2021-06-30 2024-07-23 E2 Technologies, Llc Apparatus and processes for pyrolysis of plastic feeds
FR3146141A1 (fr) 2023-02-23 2024-08-30 Axens Procede de production d’olefines par vapocraquage par valorisation d’un gaz de pyrolyse
CN116948667A (zh) * 2023-08-21 2023-10-27 武汉天源环保股份有限公司 一种固体废弃物碳化无氧热解工艺及系统

Family Cites Families (9)

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Publication number Priority date Publication date Assignee Title
US3853498A (en) * 1972-06-28 1974-12-10 R Bailie Production of high energy fuel gas from municipal wastes
US4432290A (en) 1979-10-30 1984-02-21 The Agency Of Industrial Science And Technology Method of pyrolyzing organic material using a two-bed pyrolysis system
DE3310534A1 (de) 1983-03-23 1984-10-04 C. Deilmann AG, 4444 Bad Bentheim Einrichtung zur gewinnung von energie aus pyrolisierbaren, kohlenstoffhaltigen abfallstoffen wechselnder zusammensetzung
FI120909B (fi) 2001-04-12 2010-04-30 Neste Oil Oyj Menetelmä hiilipitoisen materiaalin käsittelemiseksi
ITRM20050207A1 (it) 2005-05-02 2006-11-03 Pyrolb S R L Procedimento integrato per il trattamento di rifiuti mediante pirolisi e relativo impianto.
FI123180B (fi) 2007-10-11 2012-12-14 Valtion Teknillinen Laitteisto pyrolyysituotteen valmistamiseksi
FI20096152A (fi) * 2009-11-06 2011-05-23 Metso Power Oy Menetelmä ja laitteisto sellutehtaan mustalipeän käsittelemiseksi
US8404909B2 (en) 2009-12-09 2013-03-26 Chevron U.S.A. Inc. Method for capturing carbon dioxide from biomass pyrolysis process
CA2849299A1 (en) 2011-09-21 2013-03-28 Chevron U.S.A. Inc. Pyrolysis system using cooled flue gas for drying

Also Published As

Publication number Publication date
WO2014006273A1 (en) 2014-01-09
CA2877967C (en) 2021-04-27
US10059883B2 (en) 2018-08-28
EP2870221B1 (en) 2017-12-20
CA2877967A1 (en) 2014-01-09
FI20125784A (fi) 2014-01-07
US20150166895A1 (en) 2015-06-18
EP2870221A4 (en) 2016-05-25
EP2870221A1 (en) 2015-05-13

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