ES8604398A1 - Procedimiento de fabricacion de un compuesto sililmetaloceno - Google Patents
Procedimiento de fabricacion de un compuesto sililmetalocenoInfo
- Publication number
- ES8604398A1 ES8604398A1 ES545076A ES545076A ES8604398A1 ES 8604398 A1 ES8604398 A1 ES 8604398A1 ES 545076 A ES545076 A ES 545076A ES 545076 A ES545076 A ES 545076A ES 8604398 A1 ES8604398 A1 ES 8604398A1
- Authority
- ES
- Spain
- Prior art keywords
- compounds
- metalocen
- silyl
- preparation
- substd
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title 2
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 title 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- 125000005090 alkenylcarbonyl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- QABCGOSYZHCPGN-UHFFFAOYSA-N chloro(dimethyl)silicon Chemical compound C[Si](C)Cl QABCGOSYZHCPGN-UHFFFAOYSA-N 0.000 abstract 1
- 238000006459 hydrosilylation reaction Methods 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 125000003906 silylidene group Chemical group [H][Si]([H])=* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
PROCEDIMIENTO DE FABRICACION DE UN COMPUESTO SILILMETALOCENO. CONSISTE EN HACER REACCIONAR, EN PRESENCIA DE UN CATALIZADOR DE HIDROSILILACION, UN METALOCENO DE FORMULA (I) DONDE M ES UN METAL DE TRANSICION COMO HIERRO, OSMIO Y OTROS; R1 REPRESENTA UN RADICAL ALIFATICO SATURADO O NO, SUSTITUIDO O NO, UN RADICAL AROMATICO, SUSTITUIDO O NO, UN RADICAL ALQUENILO CARBONILO, SUSTITUIDO O NO; R5 REPRESENTA H, O UN RADICAL ALQUENILO CARBONILO, SUSTITUIDO O NO; R5 REPRESENTA H, O UN RADICAL ALIFATICO O AROMATICO SUSTITUIDO O NO; Y N ES 1 O 2 E Y ES IGUAL A 5-(N-1), CON UN HALOGENOSILANO DE FORMULA (II) DONDE X ES HALOGENO COMO CLORO, BROMO O YODO; Y R2 Y R3 QUE PUEDEN SER IGUALES O DIFERENTES, SON H, UN RADICAL ALIFATICO SUSTITUIDO O NO, O UN RADICAL AROMATICO SUSTITUIDO O NO; Y DESPUES, REDUCIR EL PRODUCTO RESULTANTE PARA FORMAR EL COMPUESTO METALOCENO Y EXTRAER EL COMPUESTO DEL MEDIO REACCIONAL.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8411506A FR2567890B1 (fr) | 1984-07-20 | 1984-07-20 | Procede de fabrication de composes silylmetallocenes, et composes obtenus par ce procede |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8604398A1 true ES8604398A1 (es) | 1986-02-01 |
ES545076A0 ES545076A0 (es) | 1986-02-01 |
Family
ID=9306314
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES545076A Expired ES8604398A1 (es) | 1984-07-20 | 1985-07-11 | Procedimiento de fabricacion de un compuesto sililmetaloceno |
Country Status (9)
Country | Link |
---|---|
US (1) | US4661608A (es) |
EP (1) | EP0171307B1 (es) |
JP (1) | JPS6137797A (es) |
CA (1) | CA1243328A (es) |
DE (1) | DE3569117D1 (es) |
ES (1) | ES8604398A1 (es) |
FR (1) | FR2567890B1 (es) |
IL (1) | IL75655A (es) |
IN (1) | IN165162B (es) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3840772A1 (de) * | 1988-12-03 | 1990-06-07 | Hoechst Ag | Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente |
US5020026A (en) * | 1989-12-14 | 1991-05-28 | Texas Instruments Incorporated | Method and apparatus for reading and programming electrically programmable memory cells |
FR2682954B1 (fr) * | 1991-10-28 | 1993-12-10 | Poudres Explosifs Ste Nale | Procede de synthese d'un complexe organosilicophosphoroplatinique supporte sur alumine et procede d'hydrosilylation d'olefines. |
US8664417B2 (en) | 2009-10-19 | 2014-03-04 | Cbz Chemicals Limited | Process for the synthesis of 4-(dimethylsilyl) butylferrocene |
CN103665053B (zh) * | 2013-10-30 | 2016-10-26 | 苏州大学 | 一种双烯丙基三碳酯二茂铁单体及其制备方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3313835A (en) * | 1963-05-27 | 1967-04-11 | Gen Electric | Metallocenyl substituted organosilicon materials and a method for making them |
US3321501A (en) * | 1963-05-27 | 1967-05-23 | Gen Electric | Metallocenyl substituted organosilicon materials and a method for making them |
US3414597A (en) * | 1964-12-01 | 1968-12-03 | Gen Electric | Metallocenylaryl-substituted organosilicon materials |
-
1984
- 1984-07-20 FR FR8411506A patent/FR2567890B1/fr not_active Expired
-
1985
- 1985-06-26 IN IN503/DEL/85A patent/IN165162B/en unknown
- 1985-06-27 IL IL75655A patent/IL75655A/xx not_active IP Right Cessation
- 1985-06-28 US US06/749,803 patent/US4661608A/en not_active Expired - Lifetime
- 1985-06-28 DE DE8585401316T patent/DE3569117D1/de not_active Expired
- 1985-06-28 CA CA000486068A patent/CA1243328A/en not_active Expired
- 1985-06-28 EP EP85401316A patent/EP0171307B1/fr not_active Expired
- 1985-07-11 ES ES545076A patent/ES8604398A1/es not_active Expired
- 1985-07-15 JP JP15435785A patent/JPS6137797A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
JPS6137797A (ja) | 1986-02-22 |
EP0171307A1 (fr) | 1986-02-12 |
ES545076A0 (es) | 1986-02-01 |
DE3569117D1 (en) | 1989-05-03 |
FR2567890B1 (fr) | 1986-09-26 |
IL75655A (en) | 1988-08-31 |
FR2567890A1 (fr) | 1986-01-24 |
EP0171307B1 (fr) | 1989-03-29 |
US4661608A (en) | 1987-04-28 |
CA1243328A (en) | 1988-10-18 |
IN165162B (es) | 1989-08-19 |
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