ES8504834A1 - Procedimiento de preparacion de la tri(m-sulfofenil) fosfina - Google Patents

Procedimiento de preparacion de la tri(m-sulfofenil) fosfina

Info

Publication number
ES8504834A1
ES8504834A1 ES534819A ES534819A ES8504834A1 ES 8504834 A1 ES8504834 A1 ES 8504834A1 ES 534819 A ES534819 A ES 534819A ES 534819 A ES534819 A ES 534819A ES 8504834 A1 ES8504834 A1 ES 8504834A1
Authority
ES
Spain
Prior art keywords
triphenylphosphine
phosphine
sulphophenyl
sulfonation
h2so4
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES534819A
Other languages
English (en)
Other versions
ES534819A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc Recherches SA
Original Assignee
Rhone Poulenc Recherches SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Recherches SA filed Critical Rhone Poulenc Recherches SA
Publication of ES8504834A1 publication Critical patent/ES8504834A1/es
Publication of ES534819A0 publication Critical patent/ES534819A0/es
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/505—Preparation; Separation; Purification; Stabilisation
    • C07F9/5054—Preparation; Separation; Purification; Stabilisation by a process in which the phosphorus atom is not involved
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/505—Preparation; Separation; Purification; Stabilisation
    • C07F9/5095—Separation; Purification; Stabilisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCEDIMIENTO DE PREPARACION DE TRI(M-SULFOFENIL)FOSFINA (TPPTS).MEDIANTE SULFONACION DE LA TRIFENILFOSFINA (TPP) POR MEDIO DE UNA MEZCLA DE ACIDO Y ANHIDRIDO SULFURICOS CON POSTERIOR HIDROLISIS PARA DETENER LA REACCION DE SULFONACION. LA TEMPERATURA SE SITUA ENTRE 15JC Y 25JC; LA RELACION MOLAR SO3/TPP ES IGUAL O MAYOR QUE 8; Y EL CONTENIDO GLOBAL DE SO3 EN LA MEZCLA (SO3 B TPP B SO4H2) ES SUPERIOR AL 33 AL COMIENZO DE LA REACCION.DE APLICACION COMO LIGANDO PARA LA PREPARACION DE CATALIZADOR DE HIDROFORMILACION DE OLEFINAS CON RODIO.
ES534819A 1983-08-03 1984-08-02 Procedimiento de preparacion de la tri(m-sulfofenil) fosfina Granted ES534819A0 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8312776A FR2550202B1 (fr) 1983-08-03 1983-08-03 Procede de preparation de tri(m-sulfophenyl) phosphine

Publications (2)

Publication Number Publication Date
ES8504834A1 true ES8504834A1 (es) 1985-05-01
ES534819A0 ES534819A0 (es) 1985-05-01

Family

ID=9291357

Family Applications (1)

Application Number Title Priority Date Filing Date
ES534819A Granted ES534819A0 (es) 1983-08-03 1984-08-02 Procedimiento de preparacion de la tri(m-sulfofenil) fosfina

Country Status (9)

Country Link
US (1) US4668824A (es)
EP (1) EP0133410B1 (es)
JP (1) JPS60100590A (es)
AT (1) ATE28877T1 (es)
BR (1) BR8403776A (es)
CA (1) CA1219280A (es)
DE (1) DE3465312D1 (es)
ES (1) ES534819A0 (es)
FR (1) FR2550202B1 (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4716250A (en) * 1986-07-10 1987-12-29 Union Carbide Corporation Hydroformylation using low volatile/organic soluble phosphine ligands
US4731486A (en) * 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
EP0372313B1 (de) * 1988-12-02 1997-03-05 Hoechst Aktiengesellschaft Sulfonierte Phenylphosphane enthaltende Komplexverbindungen
IT1229512B (it) * 1989-01-27 1991-09-03 Eniricerche Spa Procedimento per la idroformilazione catalitica di.olefine
DE4040314A1 (de) * 1990-12-17 1992-06-25 Hoechst Ag Verfahren zur herstellung wasserloeslicher diphosphane
US5288818A (en) * 1991-08-20 1994-02-22 Exxon Chemical Patents Inc. Method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
US5215667A (en) * 1991-08-20 1993-06-01 Exxon Chemical Patents Inc. Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
DE4328384A1 (de) * 1993-08-24 1995-03-02 Bayer Ag Stabilisierte, flammwidrige Polycarbonatformmassen
DE4435190A1 (de) * 1994-09-30 1996-04-04 Hoechst Ag Verfahren zur Herstellung von sulfonierten Arylphosphinen
DE4435171A1 (de) * 1994-09-30 1996-04-04 Hoechst Ag 5-H-Phenyl(di-3,13-sulfonato)dibenzophosphol und ein Verfahren zu seiner Herstellung
US5817775A (en) * 1996-10-10 1998-10-06 Celanese International Corporation Phosphines and catalysts containing the same
CN1046530C (zh) * 1996-10-15 1999-11-17 中国石油化工总公司 三(间－磺酸盐苯基)膦的制备方法
FR2787786B1 (fr) * 1998-12-23 2001-02-02 Rhone Poulenc Fibres Procede de preparation de composes organophosphores sulfones hydrosolubles et la realisation de reactions organiques avec catalyse biphasique
CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
CN103254232B (zh) * 2013-05-27 2016-05-18 成都欣华源科技有限责任公司 水溶性三（间-磺酸盐苯基）膦的制备方法
CN111808134B (zh) * 2020-08-03 2022-08-12 山东京博石油化工有限公司 一种从磺化产物中提取三苯基膦磺酸盐的方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2314910A1 (fr) * 1975-06-20 1977-01-14 Rhone Poulenc Ind Procede d'hydroformylation des olefines
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
FR2349562A2 (fr) * 1976-04-29 1977-11-25 Rhone Poulenc Ind Procede d'hydroformylation des olefines
US4394322A (en) * 1980-08-18 1983-07-19 Gulf Research & Development Company Group VA ylides and process for preparing same
US4507247A (en) * 1980-11-24 1985-03-26 Gulf Research & Development Company Sulfonated Group Va ylides and process for preparing same
US4376870A (en) * 1980-12-05 1983-03-15 Monsanto Company Optically active phosphine compounds
US4346236A (en) * 1981-02-09 1982-08-24 Fmc Corporation Method of oxidizing tertiary-alkyl phosphines
DE3235030A1 (de) * 1982-09-22 1984-03-22 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von sulfonierten arylphosphinen

Also Published As

Publication number Publication date
FR2550202A1 (fr) 1985-02-08
BR8403776A (pt) 1985-07-02
JPS60100590A (ja) 1985-06-04
ATE28877T1 (de) 1987-08-15
FR2550202B1 (fr) 1986-03-21
JPH0421678B2 (es) 1992-04-13
EP0133410B1 (fr) 1987-08-12
ES534819A0 (es) 1985-05-01
CA1219280A (fr) 1987-03-17
DE3465312D1 (en) 1987-09-17
EP0133410A1 (fr) 1985-02-20
US4668824A (en) 1987-05-26

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Legal Events

Date Code Title Description
MM4A Patent lapsed

Effective date: 19960401