ES8503130A1 - Device for generating a reference potential by means of potentiometric lambda probes. - Google Patents
Device for generating a reference potential by means of potentiometric lambda probes.Info
- Publication number
- ES8503130A1 ES8503130A1 ES532854A ES532854A ES8503130A1 ES 8503130 A1 ES8503130 A1 ES 8503130A1 ES 532854 A ES532854 A ES 532854A ES 532854 A ES532854 A ES 532854A ES 8503130 A1 ES8503130 A1 ES 8503130A1
- Authority
- ES
- Spain
- Prior art keywords
- rich
- lean
- electrode
- counter
- passage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4075—Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts
- G01N27/4076—Reference electrodes or reference mixtures
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Abstract
In said method, the measuring electrode and the counter-electrode are exposed to exhaust gas and present an adjustment which causes alternating changes between the rich and lean operations. Furthermore the counter-electrode is so arranged that the sensitive time and the dead time upon the passage of gas from the rich to the lean operation deviate from the sensitive time and the dead time upon the gas passage from the lean to the rich operation. Therefore, the counter-electrode has asymmetric sensitive times. A rich reference is preferably used wherein the sensitive time and the dead time upon the gas passage from the lean to the rich is shorter than the passage from the rich to the lean. Furthermore, the counter-electrode is provided with an anti-diffusion layer which presents pores having diameters which are small with respect to the mean free travelling length of oxygen molecules. Thereby, the measuring electrode does not make loop oscillations in the rich to lean direction and generate a substantially constant potential which may be used as a reference potential for the probe.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19833319186 DE3319186A1 (en) | 1983-05-27 | 1983-05-27 | METHOD FOR GENERATING A REFERENCE POTENTIAL IN POTENTIOMETRIC LAMBDA PROBE |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8503130A1 true ES8503130A1 (en) | 1985-02-01 |
ES532854A0 ES532854A0 (en) | 1985-02-01 |
Family
ID=6199972
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES532854A Granted ES532854A0 (en) | 1983-05-27 | 1984-05-25 | PROCEDURE FOR OBTAINING A REFERENCE POTENTIAL WITH POTENTIOMETRIC LAMBDA PROBES |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0149619A1 (en) |
JP (1) | JPS60501474A (en) |
DE (1) | DE3319186A1 (en) |
ES (1) | ES532854A0 (en) |
IT (1) | IT1178480B (en) |
WO (1) | WO1984004816A1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3685791D1 (en) * | 1985-04-17 | 1992-07-30 | Bayer Diagnostic Gmbh | ELECTROCHEMICAL PROBE. |
DE3931235A1 (en) * | 1989-09-19 | 1991-03-28 | Max Planck Gesellschaft | Solid electrolyte gas-sensor without ionic transfer - uses minority carrier transport to make it free of surface polarisation and able to operate at low temperature |
DE102021111431A1 (en) | 2020-06-29 | 2021-12-30 | Dräger Safety AG & Co. KGaA | Surveillance system |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2304464C2 (en) * | 1973-01-31 | 1983-03-10 | Robert Bosch Gmbh, 7000 Stuttgart | Sensor for monitoring the functionality of catalytic converters in exhaust gas |
CA1015827A (en) * | 1974-11-18 | 1977-08-16 | General Motors Corporation | Air/fuel ratio sensor having catalytic and noncatalytic electrodes |
JPS5274385A (en) * | 1975-12-18 | 1977-06-22 | Nissan Motor | Airrfuel ratio detector |
GB2004067A (en) * | 1977-09-09 | 1979-03-21 | Bendix Autolite Corp | Solid electrolyte exhaust gas oxygen sensor |
JPS54149698A (en) * | 1978-05-16 | 1979-11-24 | Nippon Denso Co Ltd | Oxygen concentration detector |
FR2444272A1 (en) * | 1978-12-12 | 1980-07-11 | Thomson Csf | ELECTROCHEMICAL SENSOR OF SPECIES CONCENTRATIONS IN A FLUID MIXTURE OF THE TYPE WITH INTERNAL REFERENCE OF PARTIAL PRESSURE |
US4253934A (en) * | 1979-04-17 | 1981-03-03 | General Motors Corporation | Aging treatment for exhaust gas oxygen sensor |
JPS6034062B2 (en) * | 1979-05-25 | 1985-08-06 | 日産自動車株式会社 | Air fuel ratio detection device |
DE2922131A1 (en) * | 1979-05-31 | 1980-12-18 | Bosch Gmbh Robert | POLAROGRAPHIC PROBE FOR DETERMINING THE OXYGEN CONTENT IN GAS, ESPECIALLY IN EXHAUST GAS FROM COMBUSTION ENGINES |
JPS58158553A (en) * | 1982-03-17 | 1983-09-20 | Toyota Motor Corp | Oxygen sensor |
-
1983
- 1983-05-27 DE DE19833319186 patent/DE3319186A1/en not_active Withdrawn
-
1984
- 1984-05-09 EP EP84901968A patent/EP0149619A1/en not_active Withdrawn
- 1984-05-09 WO PCT/DE1984/000105 patent/WO1984004816A1/en not_active Application Discontinuation
- 1984-05-09 JP JP59501961A patent/JPS60501474A/en active Pending
- 1984-05-25 ES ES532854A patent/ES532854A0/en active Granted
- 1984-05-25 IT IT21098/84A patent/IT1178480B/en active
Also Published As
Publication number | Publication date |
---|---|
ES532854A0 (en) | 1985-02-01 |
WO1984004816A1 (en) | 1984-12-06 |
IT8421098A1 (en) | 1985-11-25 |
EP0149619A1 (en) | 1985-07-31 |
IT1178480B (en) | 1987-09-09 |
JPS60501474A (en) | 1985-09-05 |
DE3319186A1 (en) | 1984-11-29 |
IT8421098A0 (en) | 1984-05-25 |
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