ES8500208A1 - Production of acyl halides and carboxylic acids and esters therefrom - Google Patents
Production of acyl halides and carboxylic acids and esters therefromInfo
- Publication number
- ES8500208A1 ES8500208A1 ES523258A ES523258A ES8500208A1 ES 8500208 A1 ES8500208 A1 ES 8500208A1 ES 523258 A ES523258 A ES 523258A ES 523258 A ES523258 A ES 523258A ES 8500208 A1 ES8500208 A1 ES 8500208A1
- Authority
- ES
- Spain
- Prior art keywords
- acid
- organic compound
- carbon monoxide
- acyl
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/04—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/58—Preparation of carboxylic acid halides
Abstract
In a carbonylation process for a producing acyl halides, e.g. acyl fluorides, the carbon monoxide and anhydrous acid such as hydrogen fluoride are premixed to form a single liquid phase which is reacted in a second reactor with an organic compound, i.e. an ester or an olefin, e.g. propylene, to produce an acyl halide, e.g., isobutyryl fluoride. In the second reactor the temperature is 0- 90 DEG C and the pressure 34-340 bars. The mole ratio of anhydrous acid to organic compounds is 1-100 moles of anhydrous acid per mole of organic compound and the mole ratio of carbon monoxide to organic compound is 1 to 5 moles of carbon monoxide per mole of organic compound. The acyl halide product may be hydrolysed to form the corresponding carboxylic acid which may in turn be oxydehydrogenated in the organic phase to form the corresponding unsaturated acid, e.g., acrylic acid or methacrylic acid.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28213081A | 1981-07-10 | 1981-07-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES523258A0 ES523258A0 (en) | 1984-10-01 |
| ES8500208A1 true ES8500208A1 (en) | 1984-10-01 |
Family
ID=23080232
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES513956A Expired ES8400376A1 (en) | 1981-07-10 | 1982-06-04 | Production of acyl halides and carboxylic acids and esters therefrom |
| ES523258A Expired ES8500208A1 (en) | 1981-07-10 | 1983-06-01 | Production of acyl halides and carboxylic acids and esters therefrom |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES513956A Expired ES8400376A1 (en) | 1981-07-10 | 1982-06-04 | Production of acyl halides and carboxylic acids and esters therefrom |
Country Status (19)
| Country | Link |
|---|---|
| JP (1) | JPS6024089B2 (en) |
| KR (1) | KR850001912B1 (en) |
| AT (1) | AT392066B (en) |
| AU (1) | AU532911B1 (en) |
| BE (1) | BE893415A (en) |
| BR (1) | BR8203330A (en) |
| CA (1) | CA1192576A (en) |
| CH (1) | CH656608A5 (en) |
| DD (1) | DD207900A5 (en) |
| DE (1) | DE3221173C2 (en) |
| ES (2) | ES8400376A1 (en) |
| FR (1) | FR2512811B1 (en) |
| GB (1) | GB2101591B (en) |
| IT (1) | IT1195931B (en) |
| NL (1) | NL187626C (en) |
| PL (1) | PL140231B1 (en) |
| RO (1) | RO83931B (en) |
| SE (1) | SE452609B (en) |
| ZA (1) | ZA823929B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0759531B2 (en) * | 1986-11-04 | 1995-06-28 | 三菱瓦斯化学株式会社 | Method for synthesizing isobutyryl fluoride |
| US5463095A (en) * | 1993-06-15 | 1995-10-31 | Mitsubishi Gas Chemical Company, Inc. | Process for the production of esters |
| BR102012020205A2 (en) * | 2012-08-13 | 2014-08-19 | Cesar Roque Ecker | MORTAR APPLICATOR |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE972291C (en) * | 1954-05-16 | 1959-07-02 | Studiengesellschaft Kohle Mbh | Process for the production of monocarboxylic acids from olefins, carbon monoxide and water |
| DE973077C (en) * | 1954-07-30 | 1959-11-26 | Studiengesellschaft Kohle Mbh | Process for the production of carboxylic acids from olefins and carbon oxide |
| DE1064941B (en) * | 1957-04-24 | 1959-09-10 | Studiengesellschaft Kohle Mbh | Process for the preparation of mixtures of saturated aliphatic or cycloaliphatic monocarboxylic acid alkyl esters |
| US3065242A (en) * | 1960-02-23 | 1962-11-20 | Du Pont | Production of acyl halides, carboxylic acids and lactones |
| GB942367A (en) * | 1961-04-29 | 1963-11-20 | Basf Ag | Continuous production of carboxylic acids from olefines, carbon monoxide and water |
| NL6816940A (en) * | 1967-11-28 | 1969-05-30 | ||
| BE755997A (en) * | 1969-09-11 | 1971-03-10 | Bp Chem Int Ltd | PRODUCTION OF DICARBOXYLIC ACIDS |
| DE2750719A1 (en) * | 1977-11-12 | 1979-05-17 | Roehm Gmbh | Isobutyric acid prepn. by boron tri:fluoride-catalysed carbonylation - of propylene, isopropanol, ether and/or ester deriv. in aliphatic carboxylic acid medium |
-
1982
- 1982-06-04 RO RO107796A patent/RO83931B/en unknown
- 1982-06-04 AT AT0217782A patent/AT392066B/en not_active IP Right Cessation
- 1982-06-04 BE BE0/208267A patent/BE893415A/en not_active IP Right Cessation
- 1982-06-04 JP JP57096066A patent/JPS6024089B2/en not_active Expired
- 1982-06-04 IT IT21709/82A patent/IT1195931B/en active
- 1982-06-04 DE DE3221173A patent/DE3221173C2/en not_active Expired
- 1982-06-04 AU AU84608/82A patent/AU532911B1/en not_active Ceased
- 1982-06-04 FR FR8209811A patent/FR2512811B1/en not_active Expired
- 1982-06-04 KR KR8202508A patent/KR850001912B1/en active
- 1982-06-04 ZA ZA823929A patent/ZA823929B/en unknown
- 1982-06-04 PL PL1982236785A patent/PL140231B1/en unknown
- 1982-06-04 CH CH3477/82A patent/CH656608A5/en not_active IP Right Cessation
- 1982-06-04 ES ES513956A patent/ES8400376A1/en not_active Expired
- 1982-06-04 SE SE8203478A patent/SE452609B/en not_active IP Right Cessation
- 1982-06-04 DD DD82240468A patent/DD207900A5/en not_active IP Right Cessation
- 1982-06-04 NL NLAANVRAGE8202269,A patent/NL187626C/en not_active IP Right Cessation
- 1982-06-04 GB GB08216302A patent/GB2101591B/en not_active Expired
- 1982-06-04 CA CA000404491A patent/CA1192576A/en not_active Expired
- 1982-06-07 BR BR8203330A patent/BR8203330A/en not_active IP Right Cessation
-
1983
- 1983-06-01 ES ES523258A patent/ES8500208A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SE452609B (en) | 1987-12-07 |
| CH656608A5 (en) | 1986-07-15 |
| JPS5810535A (en) | 1983-01-21 |
| BE893415A (en) | 1982-10-01 |
| RO83931A (en) | 1984-04-12 |
| GB2101591A (en) | 1983-01-19 |
| SE8203478L (en) | 1983-01-11 |
| AU532911B1 (en) | 1983-10-20 |
| AT392066B (en) | 1991-01-25 |
| NL187626B (en) | 1991-07-01 |
| DE3221173A1 (en) | 1983-01-27 |
| ZA823929B (en) | 1983-11-30 |
| IT8221709A0 (en) | 1982-06-04 |
| NL8202269A (en) | 1983-02-01 |
| ES513956A0 (en) | 1983-10-16 |
| DD207900A5 (en) | 1984-03-21 |
| FR2512811B1 (en) | 1985-07-05 |
| KR850001912B1 (en) | 1985-12-31 |
| RO83931B (en) | 1984-05-30 |
| IT1195931B (en) | 1988-11-03 |
| BR8203330A (en) | 1983-05-24 |
| JPS6024089B2 (en) | 1985-06-11 |
| PL140231B1 (en) | 1987-04-30 |
| ATA217782A (en) | 1990-07-15 |
| NL187626C (en) | 1991-12-02 |
| CA1192576A (en) | 1985-08-27 |
| PL236785A1 (en) | 1983-02-14 |
| KR840000464A (en) | 1984-02-22 |
| ES8400376A1 (en) | 1983-10-16 |
| ES523258A0 (en) | 1984-10-01 |
| FR2512811A1 (en) | 1983-03-18 |
| DE3221173C2 (en) | 1984-07-26 |
| GB2101591B (en) | 1985-11-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| MY118786A (en) | Iridium-catalysed carbonylation process for the production of a carboxylic acid | |
| TW345573B (en) | Purification of carboxylic acid and/or their anhydrides | |
| KR930703233A (en) | Method for preparing aliphatic carboxylic acid halomethyl ester | |
| NZ240009A (en) | Process for preparation of carboxylic acid anhydrides by reaction of co with a carboxylic acid ester or alkyl ether | |
| US5292941A (en) | Method for ozonizing unsaturated fatty acids or lower alkyl esters thereof and method for the oxidative decomposition of ozonized products | |
| ES8401023A1 (en) | Process for the production of a peroxy compound. | |
| ID28030A (en) | ESTER SYNTHESIS | |
| ES8400376A1 (en) | Production of acyl halides and carboxylic acids and esters therefrom | |
| GB1502713A (en) | Phosphonic acid production | |
| ES8207116A1 (en) | Process for the preparation of unsaturated carboxylic-acid esters. | |
| ATE45722T1 (en) | PROCESSES FOR THE JOINT PRODUCTION OF CARBONIC ACIDS AND CARBONIC ACID ANHYDRIDES AND, IF NECESSARY, CARBONIC ACID ESTERS. | |
| CA1194033A (en) | Process for the co-production of carboxylic acids and carboxylic acid esters | |
| JPS61502757A (en) | Production of carboxylic acid from alcohol using rhodium complex catalyst | |
| EP0075337B1 (en) | Process for the co-production of carboxylic acids and carboxylic acid esters | |
| US2939879A (en) | Process for preparing allyl esters of carboxylic acids | |
| US4810821A (en) | Preparation of alkylidene diesters | |
| ES8103006A1 (en) | Producing Sec-butanol from Linear Butenes | |
| EP0363218A3 (en) | Process for producing tricyclodecanecarboxylic acid esters | |
| ES8103012A1 (en) | Preparation of esters. | |
| JPS55142543A (en) | Method for prevention of decomposition of catalyst | |
| EP0135286B1 (en) | Production of carboxylic acids | |
| KR840000462A (en) | Process for preparing carboxylic acid from acyl fluoride fish by carbonylation reaction | |
| GB1223028A (en) | Preparation of carboxylic acids and/or esters | |
| JPS51136640A (en) | Process for continuous preparation of high purity terephthalic acid | |
| DE3160244D1 (en) | Process for producing acetic acid by carbonylation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19970303 |