ES8308344A1 - In-mold coating composition and method of in-mold coating - Google Patents
In-mold coating composition and method of in-mold coatingInfo
- Publication number
- ES8308344A1 ES8308344A1 ES515071A ES515071A ES8308344A1 ES 8308344 A1 ES8308344 A1 ES 8308344A1 ES 515071 A ES515071 A ES 515071A ES 515071 A ES515071 A ES 515071A ES 8308344 A1 ES8308344 A1 ES 8308344A1
- Authority
- ES
- Spain
- Prior art keywords
- groups
- group
- based oligomer
- mold coating
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011248 coating agent Substances 0.000 title 1
- 239000008199 coating composition Substances 0.000 title 1
- 238000000576 coating method Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 2
- 229930195729 fatty acid Natural products 0.000 abstract 2
- 239000000194 fatty acid Substances 0.000 abstract 2
- 150000004665 fatty acids Chemical class 0.000 abstract 2
- 239000004593 Epoxy Substances 0.000 abstract 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 159000000007 calcium salts Chemical class 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- -1 free radical peroxide Chemical class 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 1
- 239000011118 polyvinyl acetate Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 150000003751 zinc Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/026—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
- C08F299/065—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes from polyurethanes with side or terminal unsaturations
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Epoxy Resins (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
An FRP molding can be in-mold coated using a one-component free radical peroxide initiated composition of (a) a polymerizable oligomer selected from the group consisting of (1) a polyurethane based oligomer having at least two acrylate groups, (2) an epoxy based oligomer having at least two acrylate groups and (3) a polyester based oligomer having a plurality of internal ethylenically unsaturated groups and mixtures of the same, (b) a copolymerizable ethylenically unsaturated monomer, (c) a zinc salt of a fatty acid having at least 10 carbon atoms, (d) an accelerator for the peroxide initiator and (e) polyvinyl acetate. Optionally and desirably the composition additionally contains (f) a mono- unsaturated compound having a -CO- group and a -NH2, -NH- and/or -OH group, (g) a liquid copolymerizable compound having from 2-4 vinyl groups, being free of urethane, cycloaliphatic and aromatic groups and having a molecular weight of up to about 1500, (h) a calcium salt of a fatty acid having at least 10 carbon atoms and (i) a filler.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US31659281A | 1981-11-02 | 1981-11-02 |
Publications (2)
Publication Number | Publication Date |
---|---|
ES515071A0 ES515071A0 (en) | 1983-08-16 |
ES8308344A1 true ES8308344A1 (en) | 1983-08-16 |
Family
ID=23229708
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES515071A Expired ES8308344A1 (en) | 1981-11-02 | 1982-08-17 | In-mold coating composition and method of in-mold coating |
Country Status (12)
Country | Link |
---|---|
JP (1) | JPS6019941B2 (en) |
AU (1) | AU533510B2 (en) |
BR (1) | BR8205098A (en) |
CA (1) | CA1186429A (en) |
DE (1) | DE3229292C2 (en) |
ES (1) | ES8308344A1 (en) |
FR (1) | FR2515666B1 (en) |
GB (1) | GB2108987B (en) |
IT (1) | IT1195951B (en) |
MX (1) | MX173523B (en) |
SE (1) | SE455947B (en) |
ZA (1) | ZA825562B (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1338542C (en) * | 1982-09-13 | 1996-08-20 | Leonard Ornstein | Specimen mounting adhesive composition |
US4515710A (en) * | 1983-07-18 | 1985-05-07 | Gencorp Inc. | In-mold coating composition |
JPS6160764A (en) * | 1984-09-03 | 1986-03-28 | Dainichi Seika Kogyo Kk | Coating composition for thin metallic film |
JPS62143917A (en) * | 1985-12-17 | 1987-06-27 | Nippon Retsuku Kk | Resin composition for use in electronic parts sealing |
DE3642527A1 (en) * | 1986-12-12 | 1988-06-23 | Hans Ing Grad Germar | Process for producing GRP mouldings with tough and resilient polyurethane surfaces and moulding produced according to this process |
EP0311288A3 (en) * | 1987-09-30 | 1992-01-08 | Westinghouse Electric Corporation | Improvements in or relating to resin compositions curable with ultraviolet light |
DE3839940A1 (en) * | 1988-11-26 | 1990-05-31 | Stockhausen Chem Fab Gmbh | Aqueous polyurethane and polyurethane-urea dispersions, and process for the flocking of elastomeric mouldings using these dispersions |
US5084353A (en) * | 1989-05-12 | 1992-01-28 | Gencorp Inc. | Thermosetting in-mold coating compositions |
JP2600519B2 (en) * | 1990-08-13 | 1997-04-16 | いすゞ自動車株式会社 | FRP molding plating method |
JP2686682B2 (en) * | 1991-10-16 | 1997-12-08 | いすゞ自動車株式会社 | Manufacturing method of molded products |
DE69408195T2 (en) * | 1993-04-26 | 1998-11-05 | Gencorp Inc | Conductive molded coatings |
JP3404546B2 (en) * | 1995-03-23 | 2003-05-12 | 大日本塗料株式会社 | Mold coating method |
DE19528929C2 (en) * | 1995-08-07 | 1999-07-01 | Feron Aluminium | Process for the production of plastic films which are used for the production of film capacitors |
WO2004085549A2 (en) * | 2003-03-19 | 2004-10-07 | Omnova Solutions Inc. | Optical quality coating |
JP2007313395A (en) * | 2006-05-24 | 2007-12-06 | Rimtec Kk | In-mold coating method and coated molding |
WO2022018136A1 (en) | 2020-07-21 | 2022-01-27 | Ncapt Ab | METHOD FOR SURFACE TREATMENT PRIOR TO COATING and GLUING |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2104575B2 (en) * | 1970-02-02 | 1980-04-10 | Union Carbide Corp., New York, N.Y. (V.St.A.) | Low shrinkage curable unsaturated polyester compositions |
US3997627A (en) * | 1973-08-29 | 1976-12-14 | Mitsubishi Rayon Co., Ltd. | Polyester molding compositions containing hydroxy containing vinyl monomers and coated molded articles thereof |
CA1096082A (en) * | 1976-11-01 | 1981-02-17 | Kenneth E. Atkins | Uniformly pigmented, low shrinking polyester molding compositions |
DE2846573A1 (en) * | 1978-10-26 | 1980-05-08 | Roehm Gmbh | LIQUID TO PASTE-SHAPED, LOCKABLE PLASTIC MATERIAL |
US4189517A (en) * | 1978-11-08 | 1980-02-19 | The General Tire & Rubber Company | Low-shrink in-mold coating |
DE2851340A1 (en) * | 1978-11-28 | 1980-06-04 | Bayer Ag | Copolymerisable moulding compsns. based on unsatd. polyurethane(s) - for containers, vehicle parts, etc, with improved impact strength |
JPS5580423A (en) * | 1978-12-13 | 1980-06-17 | Hitachi Chem Co Ltd | Low shrinkage unsaturated polyester resin composition |
DE2914984A1 (en) * | 1979-04-12 | 1980-11-13 | Consortium Elektrochem Ind | METHOD FOR PRODUCING POLYMERISATS |
US4239808A (en) * | 1979-06-13 | 1980-12-16 | The General Tire & Rubber Company | In-mold coating of sheet molding compound moldings |
-
1982
- 1982-01-04 MX MX190806A patent/MX173523B/en unknown
- 1982-08-02 ZA ZA825562A patent/ZA825562B/en unknown
- 1982-08-03 GB GB08222414A patent/GB2108987B/en not_active Expired
- 1982-08-03 CA CA000408586A patent/CA1186429A/en not_active Expired
- 1982-08-03 AU AU86709/82A patent/AU533510B2/en not_active Ceased
- 1982-08-05 DE DE3229292A patent/DE3229292C2/en not_active Expired
- 1982-08-17 ES ES515071A patent/ES8308344A1/en not_active Expired
- 1982-08-17 SE SE8204737A patent/SE455947B/en not_active IP Right Cessation
- 1982-08-18 FR FR8214270A patent/FR2515666B1/en not_active Expired
- 1982-08-31 BR BR8205098A patent/BR8205098A/en not_active IP Right Cessation
- 1982-09-02 IT IT23105/82A patent/IT1195951B/en active
- 1982-10-29 JP JP57189383A patent/JPS6019941B2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB2108987B (en) | 1985-08-21 |
SE8204737D0 (en) | 1982-08-17 |
DE3229292A1 (en) | 1983-05-11 |
MX173523B (en) | 1994-03-11 |
BR8205098A (en) | 1983-08-09 |
AU8670982A (en) | 1983-05-12 |
ZA825562B (en) | 1985-11-27 |
GB2108987A (en) | 1983-05-25 |
ES515071A0 (en) | 1983-08-16 |
IT1195951B (en) | 1988-11-03 |
JPS58125762A (en) | 1983-07-26 |
DE3229292C2 (en) | 1986-01-16 |
FR2515666A1 (en) | 1983-05-06 |
SE8204737L (en) | 1983-05-03 |
FR2515666B1 (en) | 1986-12-26 |
JPS6019941B2 (en) | 1985-05-18 |
SE455947B (en) | 1988-08-22 |
IT8223105A0 (en) | 1982-09-02 |
AU533510B2 (en) | 1983-12-01 |
CA1186429A (en) | 1985-04-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 20000201 |