ES8306698A1 - "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido". - Google Patents

"un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".

Info

Publication number
ES8306698A1
ES8306698A1 ES515039A ES515039A ES8306698A1 ES 8306698 A1 ES8306698 A1 ES 8306698A1 ES 515039 A ES515039 A ES 515039A ES 515039 A ES515039 A ES 515039A ES 8306698 A1 ES8306698 A1 ES 8306698A1
Authority
ES
Spain
Prior art keywords
biphenyl
reaction
insecticidal
production
compositions containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES515039A
Other languages
English (en)
Other versions
ES515039A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FMC Corp
Original Assignee
FMC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/193,056 external-priority patent/US4329518A/en
Application filed by FMC Corp filed Critical FMC Corp
Publication of ES8306698A1 publication Critical patent/ES8306698A1/es
Publication of ES515039A0 publication Critical patent/ES515039A0/es
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/08—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D263/10—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C07C17/14—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms in the side-chain of aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/06—Compounds containing nitro groups bound to a carbon skeleton having nitro groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/07—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms
    • C07C205/11—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms having nitro groups bound to carbon atoms of six-membered aromatic rings
    • C07C205/12—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms having nitro groups bound to carbon atoms of six-membered aromatic rings the six-membered aromatic ring or a condensed ring system containing that ring being substituted by halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/13—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups
    • C07C205/19—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups bound to carbon atoms of six-membered aromatic rings and hydroxy groups bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/39—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by esterified hydroxy groups
    • C07C205/42—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by esterified hydroxy groups having nitro groups or esterified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/49—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups
    • C07C205/57—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C22/00—Cyclic compounds containing halogen atoms bound to an acyclic carbon atom
    • C07C22/02—Cyclic compounds containing halogen atoms bound to an acyclic carbon atom having unsaturation in the rings
    • C07C22/04—Cyclic compounds containing halogen atoms bound to an acyclic carbon atom having unsaturation in the rings containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/095—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/128—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by alcoholysis
    • C07C29/1285—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by alcoholysis of esters of organic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C07C29/40—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones with compounds containing carbon-to-metal bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/62—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/18—Monohydroxylic alcohols containing only six-membered aromatic rings as cyclic part
    • C07C33/24—Monohydroxylic alcohols containing only six-membered aromatic rings as cyclic part polycyclic without condensed ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/40—Halogenated unsaturated alcohols
    • C07C33/46—Halogenated unsaturated alcohols containing only six-membered aromatic rings as cyclic parts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/48—Halogenated derivatives
    • C07C35/50—Alcohols with at least two rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/562—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with nitrogen as the only hetero atom
    • C07C45/565—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with nitrogen as the only hetero atom by reaction with hexamethylene-tetramine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/33—Polycyclic acids
    • C07C63/331—Polycyclic acids with all carboxyl groups bound to non-condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/68—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings containing halogen
    • C07C63/72—Polycyclic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PROCEDIMIENTO PARA LA OBTENCION DE COMPUESTOS DE 1,1 -BIFENIL -3-ILMETILO SUSTITUIDO, DE FORMULA (I), EN LA QUE Y ES HIDROXILO O GRUPO DESPLAZABLE POR CARBOXILATO; A ES FLUOR O CLORO EN POSICIONES 2 Y 4; B ES 0 Y A ES 2. CONSISTE EN LA REACCION DE UN COMPUESTO DE FORMULA (I), EN LA QUE Y ES HIDROGENO Y TODOS LOS DEMAS SIMBOLOS TIENEN EL MISMO SIGNIFICADO ANTERIOR, CON N-BROMOSUCCINIMIDA; SEGUIDA DE LA REACCION DE INTERCAMBIO DE BROMO CON OTRO GRUPO ELIMINABLE. LA REACCION CON N-BROMOSUCCINIMIDA SE LLEVA A CABO EN TETRACLORURO DE CARBONO, EN PRESENCIA DE PEROXIDO DE BENZOILO, A LA TEMPERATURA AMBIENTE. ESTOS COMPUESTOS TIENEN APLICACIONES EN AGRICULTURA COMO INSECTICIDAS Y ACARICIDAS.
ES515039A 1980-10-02 1982-08-16 "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido". Granted ES515039A0 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/193,056 US4329518A (en) 1979-09-18 1980-10-02 Insecticidal [1,1'-biphenyl]-3-ylmethyl esters
US06/265,940 US4402973A (en) 1980-10-02 1981-05-21 Insecticidal (1,1'-biphenyl)-3-ylmethyl esters

Publications (2)

Publication Number Publication Date
ES8306698A1 true ES8306698A1 (es) 1983-06-01
ES515039A0 ES515039A0 (es) 1983-06-01

Family

ID=26888637

Family Applications (7)

Application Number Title Priority Date Filing Date
ES505939A Expired ES8301876A1 (es) 1980-10-02 1981-10-01 Un procedimiento para preparar esteres piretroides de 1,1'-bifenil-3-ilmetilo.
ES515040A Granted ES515040A0 (es) 1980-10-02 1982-08-16 "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".
ES515039A Granted ES515039A0 (es) 1980-10-02 1982-08-16 "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".
ES515041A Expired ES8306700A1 (es) 1980-10-02 1982-08-16 "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".
ES515042A Expired ES8306701A1 (es) 1980-10-02 1982-08-16 "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".
ES515043A Expired ES8306702A1 (es) 1980-10-02 1982-08-16 "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".
ES515044A Granted ES515044A0 (es) 1980-10-02 1982-08-16 "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".

Family Applications Before (2)

Application Number Title Priority Date Filing Date
ES505939A Expired ES8301876A1 (es) 1980-10-02 1981-10-01 Un procedimiento para preparar esteres piretroides de 1,1'-bifenil-3-ilmetilo.
ES515040A Granted ES515040A0 (es) 1980-10-02 1982-08-16 "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".

Family Applications After (4)

Application Number Title Priority Date Filing Date
ES515041A Expired ES8306700A1 (es) 1980-10-02 1982-08-16 "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".
ES515042A Expired ES8306701A1 (es) 1980-10-02 1982-08-16 "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".
ES515043A Expired ES8306702A1 (es) 1980-10-02 1982-08-16 "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".
ES515044A Granted ES515044A0 (es) 1980-10-02 1982-08-16 "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".

Country Status (13)

Country Link
US (1) US4402973A (es)
EP (3) EP0143152A3 (es)
AU (1) AU549629B2 (es)
BR (1) BR8106334A (es)
DD (1) DD202098A5 (es)
DE (1) DE3173892D1 (es)
DK (1) DK435281A (es)
ES (7) ES8301876A1 (es)
GR (2) GR78174B (es)
HU (1) HU190370B (es)
IE (1) IE52416B1 (es)
MX (1) MX6916E (es)
TR (3) TR22442A (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4668792A (en) * 1978-12-04 1987-05-26 Fmc Corporation Intermediates to insecticidal [1,1'-biphenyl]-3-ylmethyl esters
US4536591A (en) * 1981-05-21 1985-08-20 Fmc Corporation Insecticidal [1,1'-biphenyl]-3-ylmethyl esters
FR2536748A1 (fr) * 1982-11-25 1984-06-01 Roussel Uclaf Nouveaux esters derives d'acides 2,2-dimethyl cyclopropane carboxyliques et d'alcools biaryliques, leur procede de preparation et leur application a la lutte contre les parasites
USH49H (en) 1983-01-10 1986-04-01 Fmc Corporation Process for producing 3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylates
US4552892A (en) * 1983-03-11 1985-11-12 Fmc Corporation Acaricidal difluoroethenylcyclopropanecarboxylates
US4740637A (en) * 1984-07-26 1988-04-26 Fmc Corporation Process for hydroxymethylation
CA1284665C (en) * 1984-07-26 1991-06-04 Eric George Delmar Process for hydroxymethylation
JPH0674238B2 (ja) * 1985-09-30 1994-09-21 財団法人相模中央化学研究所 ２，２−ジメチルシクロプロパンカルボン酸誘導体
DE3907069A1 (de) * 1989-03-04 1990-09-06 Basf Ag Substituierte 2-phenyl-alk(en)yl-1-yl-cyclopropancarbonsaeurebenzylester, verfahren zu ihrer herstellung und ihre verwendung zur bekaempfung von schaedlingen
DE10007411A1 (de) 2000-02-18 2001-08-23 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE10013914A1 (de) 2000-03-21 2001-09-27 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
AR029677A1 (es) 2000-06-29 2003-07-10 Bayer Ag Combinaciones de compuestos activos con propiedades insecticidas y acaricidas
DE10055941A1 (de) 2000-11-10 2002-05-23 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE10059606A1 (de) 2000-12-01 2002-06-06 Bayer Ag Wirkstoffkombinationen
DE10353281A1 (de) 2003-11-14 2005-06-16 Bayer Cropscience Ag Wirkstoffkombination mit insektiziden und akariziden Eigenschaften
DE102004001271A1 (de) 2004-01-08 2005-08-04 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
DE102004006324A1 (de) * 2004-02-10 2005-08-25 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
DE102006046688B3 (de) * 2006-09-29 2008-01-24 Siemens Ag Kälteanlage mit einem warmen und einem kalten Verbindungselement und einem mit den Verbindungselementen verbundenen Wärmerohr
DE102007045953B4 (de) 2007-09-26 2018-07-05 Bayer Intellectual Property Gmbh Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
EP2127522A1 (de) 2008-05-29 2009-12-02 Bayer CropScience AG Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
CN102448304B (zh) 2009-03-25 2015-03-11 拜尔农作物科学股份公司 具有杀昆虫和杀螨特性的活性成分结合物
EP2382865A1 (de) 2010-04-28 2011-11-02 Bayer CropScience AG Synergistische Wirkstoffkombinationen
EP2446742A1 (de) 2010-10-28 2012-05-02 Bayer CropScience AG Insektizide oder akarizide Zusammensetzungen enthaltend Mono- oder Disacchariden als Wirkungsverstärker
WO2012150221A2 (de) 2011-05-04 2012-11-08 Bayer Cropscience Ag Neue halogenierte benzylalkoholester der cyclopropancarbonsäure als schädlingsbekämpfungsmittel
WO2012150205A1 (de) 2011-05-04 2012-11-08 Bayer Cropscience Ag Neue substituierte benzylalkoholester der cyclopropancarbonsäure als schädlingsbekämpfungsmittel
WO2012150208A1 (de) 2011-05-04 2012-11-08 Bayer Cropscience Ag Verwendung von substituierten benzylalkoholestern der cyclopropancarbonsäure zur bekämpfung von insektizid-resistenten insekten

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL56400A (en) * 1976-09-21 1984-07-31 Roussel Uclaf Alpha-cyano-3-phenoxybenzyl and 3,4,5,6-tetrahydrophthalimidomethyl esters of 2,2-dimethyl-3-(1,2,2,2-tetrahaloethyl)cyclopropane-carboxylic acids,process for preparing them and insecticidal,acaricidal and nematocidal compositions containing them
SE441179B (sv) * 1976-09-21 1985-09-16 Roussel Uclaf Nya cyklopropankarboxylsyror med polyhalogenerad substituent, sett for framstellning derav samt anvendning derav i pesticidkompositioner
US4130657A (en) * 1977-10-20 1978-12-19 Fmc Corporation [1,1'-Biphenyl]-3-ylmethyl 3-(2,2-dihaloethenyl)-2,2-dimethylcyclopropanecarboxylates
DE2860436D1 (en) * 1977-11-01 1981-02-26 Ciba Geigy Ag Phenoxy-alpha-vinylbenzyl esters of cyclopropane carboxylic acids, process for their preparation and their use as pesticides
US4238505A (en) * 1978-01-20 1980-12-09 Fmc Corporation Insecticidal biphenylmethyl perhaloalkylvinylcyclopropanecarboxylates
IN150399B (es) * 1978-01-20 1982-09-25 Fmc Corp
US4214004A (en) * 1978-12-04 1980-07-22 Fmc Corporation Insecticidal cyclopropanecarboxylates from substituted [1,1'-biphenyl]-3-ylmethyl compounds
US4271639A (en) * 1979-02-12 1981-06-09 Anselm Talalay Manufacture of sponge rubber spheres
US4226872A (en) * 1979-08-24 1980-10-07 Zoecon Corporation Pyridyl esters of α-substituted amino acids
US4226802A (en) * 1979-10-29 1980-10-07 Zoecon Corporation 2-(4-Trifluoromethylphenylamino)-3-methylbutanoic acid esters and intermediates therefor
US4235777A (en) * 1979-11-19 1980-11-25 Zoecon Corporation Benzylpyrrolylmethyl esters of 3-(1,2-dibromo-2,2-dichloroethyl)-2,2-dimethylcyclopropanecarboxylic acid

Also Published As

Publication number Publication date
EP0049977B1 (en) 1986-02-26
ES505939A0 (es) 1983-01-01
EP0143152A2 (en) 1985-06-05
ES515042A0 (es) 1983-06-01
MX6916E (es) 1986-11-11
ES8306699A1 (es) 1983-06-01
TR22064A (tr) 1986-03-06
ES8301876A1 (es) 1983-01-01
DD202098A5 (de) 1983-08-31
ES8306701A1 (es) 1983-06-01
IE52416B1 (en) 1987-10-28
ES8306703A1 (es) 1983-06-01
EP0049977A1 (en) 1982-04-21
DK435281A (da) 1982-04-03
EP0143153A2 (en) 1985-06-05
GR78175B (es) 1984-09-26
US4402973A (en) 1983-09-06
ES515040A0 (es) 1983-06-01
TR22442A (tr) 1987-06-23
DE3173892D1 (en) 1986-04-03
TR22076A (tr) 1986-03-14
ES515041A0 (es) 1983-06-01
ES515043A0 (es) 1983-06-01
AU7599081A (en) 1982-04-08
ES8306702A1 (es) 1983-06-01
EP0143153A3 (en) 1985-07-17
ES515044A0 (es) 1983-06-01
BR8106334A (pt) 1982-06-22
ES515039A0 (es) 1983-06-01
EP0143152A3 (en) 1985-07-17
AU549629B2 (en) 1986-02-06
GR78174B (es) 1984-09-26
ES8306700A1 (es) 1983-06-01
HU190370B (en) 1986-08-28

Similar Documents

Publication Publication Date Title
ES8306698A1 (es) "un procedimiento para fabricar un compuesto de 1,1'-bifenil-3-ilmetilo sustuido".
ES8703853A1 (es) Procedimiento para la obtencion de arilciclopropil-cetonas
ES467727A1 (es) Un procedimiento para la produccion de un ester piridilmeti-lico sustituido de un compuesto ciclopropanocarboxilico.
ES474176A1 (es) Procedimiento para la preparacion de polimeros reticulados
UA27871C2 (uk) Похідні 3,6-дизаміщеного-1,2,4,5-тетразину для боротьби з кліщами, акарицидна композиція на їх основі, спосіб її отримання, спосіб зменшення кількості кліщів
ES2025239B3 (es) Procedimiento para la obtencion de cf3i.
GB1394099A (en) 2,5-dioxoimidazolidines as selective herbicides
ES8800168A1 (es) Procedimiento para preparar derivados de carbamoilimidazol fungicidas
BG48931A3 (en) Method for preparing of pyretroids
ES2026416A6 (es) Procedimiento para la preparacion de triazolil-isopropanol.
ATE13052T1 (de) Substituierte 3-(1,2-dibrom-alkyl)-2,2-dimethylcyclo-propan-1-carbons|ureester, verfahren sowie zwischenprodukte zu ihrer herstellung und ihre verwendung in schaedlingsbekaempfungsmitteln.
ES452444A1 (es) Un procedimiento para la preparacion de composiciones utilespara el control de la vegetacion indeseable.
JPS5744665A (en) Improvement of initial discoloration of chlorine-containing resin composition
IL57555A0 (en) 1-phenyl-3-benzoyl-urea derivatives,their production and their use as insecticides
JPS54120653A (en) Flame retardant ethylene-propylene copolymer composition
GEP19970942B (en) Insecticidal composition
AU542497B2 (en) Preparation of vinyl compounds
JPS52103530A (en) Production of acrylic carbon fibers
GB1426187A (en) Pesticidal vinyl esters of thiophosphoric acids
GB1252087A (es)
JPS5527116A (en) Preparation of organic sulfur compound
GB1370393A (en) Thiocarbonic compounds
JPS57188564A (en) Novel delta 1-pyrroline thiolactim ethers and manufacture
JPS5427531A (en) N-trichloroacetyl-n'-substituted benzoylhydrazine derivatives and agricultural and horticultural fungicides containing them
GB1323281A (en) Cycloalkylphenylcarbamates a process for their preparation and their use as insecticides acaricides and fungicides