ES8207230A1 - Metodo para recuperar molibdeno unido organicamente, insolu-ble en agua, de residuos organicos de catalizador agotado derivados de la epoxidacion de olefinas - Google Patents

Metodo para recuperar molibdeno unido organicamente, insolu-ble en agua, de residuos organicos de catalizador agotado derivados de la epoxidacion de olefinas

Info

Publication number
ES8207230A1
ES8207230A1 ES502086A ES502086A ES8207230A1 ES 8207230 A1 ES8207230 A1 ES 8207230A1 ES 502086 A ES502086 A ES 502086A ES 502086 A ES502086 A ES 502086A ES 8207230 A1 ES8207230 A1 ES 8207230A1
Authority
ES
Spain
Prior art keywords
molybdenum
aqueous solution
liquid
recovery
catalyst residue
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES502086A
Other languages
English (en)
Other versions
ES502086A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Verizon Laboratories Inc
Original Assignee
GTE Laboratories Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GTE Laboratories Inc filed Critical GTE Laboratories Inc
Publication of ES8207230A1 publication Critical patent/ES8207230A1/es
Publication of ES502086A0 publication Critical patent/ES502086A0/es
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G39/00Compounds of molybdenum
    • C01G39/003Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G39/00Compounds of molybdenum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C22B3/24Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/28Amines
    • C22B3/282Aliphatic amines
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/28Amines
    • C22B3/288Quaternary ammonium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00Obtaining refractory metals
    • C22B34/30Obtaining chromium, molybdenum or tungsten
    • C22B34/34Obtaining molybdenum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00Obtaining refractory metals
    • C22B34/30Obtaining chromium, molybdenum or tungsten
    • C22B34/34Obtaining molybdenum
    • C22B34/345Obtaining molybdenum from spent catalysts
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/009General processes for recovering metals or metallic compounds from spent catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)

Abstract

METODO PARA RECUPERAR MOLIBDENO UNIDO ORGANICAMENTE, INSOLUBLE EN AGUA, DE RESIDUOS ORGANICOS DE CATALIZADOR AGOTADO DERIVADOS DE LA EPOXIDACION DE OLEFINAS. CONSTA DE LAS SIGUIENTES ETAPAS: 1. PONER EN CONTACTO EL RESIDUO DE CATALIZADOR AGOTADO CON UNA SOLUCION ACUOSA QUE CONTIENE UN AGENTE OXIDANTE DURANTE UN PERIODO SUFICIENTE PARA OXIDAR UNA PORCION DE DICHO MOLIBDENO A UNA FORMA SOLUBLE EN AGUA, DE MAYOR ESTADO DE OXIDACION Y PARA TRANSFERIR UNA PORCION DE DICHO MOLIBDENO A LA SOLUCION ACUOSA. 2. SEPARAR LA SOLUCION ACUOSA QUE CONTIENE EL MOLIBDENO. 3. AISLAR DICHO MOLIBDENO. EL AGENTE OXIDANTE SE ELIGE DE ENTRE EL PEROXIDO DE HIDROGENO, ACIDO NITRICO, HIPOCLORITO SODICO, PEROXIDO SODICO, CLORO Y OZONO. EL RESIDUO ORGANICO COMPRENDE EL RESIDUO SEMISOLIDO DERIVADO DE LA CONCENTRACION DE RESIDUOS DE CATALIZADOR PROCEDENTES DE LA EPOXIDACION DE OLEFINAS.
ES502086A 1980-05-12 1981-05-11 Metodo para recuperar molibdeno unido organicamente, insolu-ble en agua, de residuos organicos de catalizador agotado derivados de la epoxidacion de olefinas Granted ES502086A0 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14905880A 1980-05-12 1980-05-12
US06/233,401 US4328191A (en) 1980-05-12 1981-02-13 Process for the recovery of molybdenum from spent catalysts

Publications (2)

Publication Number Publication Date
ES8207230A1 true ES8207230A1 (es) 1982-09-01
ES502086A0 ES502086A0 (es) 1982-09-01

Family

ID=26846439

Family Applications (1)

Application Number Title Priority Date Filing Date
ES502086A Granted ES502086A0 (es) 1980-05-12 1981-05-11 Metodo para recuperar molibdeno unido organicamente, insolu-ble en agua, de residuos organicos de catalizador agotado derivados de la epoxidacion de olefinas

Country Status (3)

Country Link
US (1) US4328191A (es)
ES (1) ES502086A0 (es)
NL (1) NL8101942A (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0197271B1 (en) * 1985-03-04 1989-04-19 Kabushiki Kaisha Toshiba Methods for preparing high-purity molybdenum or tungsten powder and high-purity oxides powder of the same
US5290527A (en) * 1992-11-05 1994-03-01 Texaco Chemical Company Molybdenum recovery
US5439657A (en) * 1994-05-16 1995-08-08 Arco Chemical Technology, L.P. Molybdenum catalyst separation
US5736112A (en) * 1995-05-08 1998-04-07 Huntsman Specialty Chemicals Corporation Aqueous oxidation of organic molybdenum compounds
US5503813A (en) * 1995-05-12 1996-04-02 Arco Chemical Technology, L.P. Molybdenum recovery from epoxidate
US6062482A (en) * 1997-09-19 2000-05-16 Pentech Energy Solutions, Inc. Method and apparatus for energy recovery in an environmental control system
US20100084327A1 (en) * 2008-09-16 2010-04-08 Paul Goranson Recovery and precipitation of various elements and compounds
US8216532B1 (en) 2011-06-17 2012-07-10 Vierheilig Albert A Methods of recovering rare earth elements
CN108396141B (zh) * 2018-05-03 2019-09-10 中南大学 一种钼的清洁冶金方法
RU2683319C1 (ru) * 2018-12-18 2019-03-28 федеральное государственное бюджетное образовательное учреждение высшего образования "Казанский национальный исследовательский технологический университет" (ФГБОУ ВО "КНИТУ") Способ получения катализатора для эпоксидирования олефинов

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD69605A (es) *
US3453068A (en) * 1967-06-22 1969-07-01 Atlantic Richfield Co Recovery of molybdenum from organic solutions
US3598519A (en) * 1969-06-30 1971-08-10 Sylvania Electric Prod Purification of molybdenum
US3763303A (en) * 1971-12-13 1973-10-02 American Metal Climax Inc Recovery of molybdenum from spent catalyst
US4046852A (en) * 1976-05-19 1977-09-06 Amax Inc. Purification process for technical grade molybdenum oxide
JPS549193A (en) * 1977-06-23 1979-01-23 Daido Oxygen Method of separating and recovering molybdnum and tungsten

Also Published As

Publication number Publication date
NL8101942A (nl) 1981-12-01
US4328191A (en) 1982-05-04
ES502086A0 (es) 1982-09-01

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