ES8200649A1 - Procedimiento de preparacion de derivados del acido ciclo- propano-carboxilico - Google Patents

Procedimiento de preparacion de derivados del acido ciclo- propano-carboxilico

Info

Publication number
ES8200649A1
ES8200649A1 ES497783A ES497783A ES8200649A1 ES 8200649 A1 ES8200649 A1 ES 8200649A1 ES 497783 A ES497783 A ES 497783A ES 497783 A ES497783 A ES 497783A ES 8200649 A1 ES8200649 A1 ES 8200649A1
Authority
ES
Spain
Prior art keywords
esters
cyclopropane
formyl
preparation
carboxylic acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES497783A
Other languages
English (en)
Other versions
ES497783A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Publication of ES497783A0 publication Critical patent/ES497783A0/es
Publication of ES8200649A1 publication Critical patent/ES8200649A1/es
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Indole Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PROCEDIMIENTO DE PREPARACION DE DERIVADOS DEL ACIDO CICLOPROPANO-CARBOXILICO DE FORMULA (I), EN QUE X1 Y X2, O SON UN RADICAL ALCOHILO O FORMAN ENTRE SI UN HOMOCICLO CARBONADO O UN HETEROCICLO. SE HACE REACCIONAR UN ACIDO 2,2-DIMETIL-3-FORMIL-CICLOPROPANO-1-CARBOXILICO EN FORMA TRANS, DE FORMULA (II), O UNA LACTONA CIS DEL ACIDO 2,2-DIMETIL-3-DIHIDROXIMETIL-CICLOPROPANO-1-CARBOXILICO DE FORMULA (III), CON UN RACTIVO DE DESHIDRACIA DE PIRIDINA O DE 4-DIMETIL-AMINOPIRIDINA, EN UN DISOLVETE ORGANICO NO POLAR. EL COMPUESTO RESULTANTE SE HACE REACCONAR CON ALCOHOL (RS)-A CIANO-3-FENOXIBENICILICO, EN UN DISOLVENTE NO POLAR. SE TRATA EL STER OBTENIDO CON UNA AMINA PRIMARIA Y CON UN AGENTE BASICO, SE HIDROLIZA Y SE SOMETE A REACCION CON FOSFORANO.
ES497783A 1979-12-17 1980-12-16 Procedimiento de preparacion de derivados del acido ciclo- propano-carboxilico Expired ES8200649A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7930843A FR2471369A1 (fr) 1979-12-17 1979-12-17 Nouvelles imines, derivant d'esters d'acides formyl cyclopropane carboxyliques, leur procede de preparation et leur application a la preparation d'esters insecticides

Publications (2)

Publication Number Publication Date
ES497783A0 ES497783A0 (es) 1981-11-01
ES8200649A1 true ES8200649A1 (es) 1981-11-01

Family

ID=9232838

Family Applications (1)

Application Number Title Priority Date Filing Date
ES497783A Expired ES8200649A1 (es) 1979-12-17 1980-12-16 Procedimiento de preparacion de derivados del acido ciclo- propano-carboxilico

Country Status (12)

Country Link
US (3) US4312817A (es)
EP (2) EP0030887B1 (es)
JP (1) JPS5692854A (es)
AT (1) ATE15654T1 (es)
CA (1) CA1186322A (es)
DE (1) DE3066213D1 (es)
DK (1) DK535780A (es)
ES (1) ES8200649A1 (es)
FR (1) FR2471369A1 (es)
HU (1) HU187287B (es)
IE (1) IE51213B1 (es)
PT (1) PT72209B (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2471369A1 (fr) 1979-12-17 1981-06-19 Roussel Uclaf Nouvelles imines, derivant d'esters d'acides formyl cyclopropane carboxyliques, leur procede de preparation et leur application a la preparation d'esters insecticides
FR2522323B2 (fr) * 1981-04-16 1989-07-21 Roussel Uclaf Nouveaux derives de l'acide cyclopropane carboxylique, leur procede de preparation, leur application a la lutte contre les parasites
FR2526422B1 (fr) * 1982-05-06 1985-09-20 Roussel Uclaf Nouveau procede de preparation de derives de l'acide cyclopropane carboxylique
US5028731A (en) * 1989-11-17 1991-07-02 Fmc Corporation Preparation of mixtures of cypermethrin or cyfluthrin isomers enriched in more active species
JPH0415988U (es) * 1990-05-30 1992-02-10
US7249512B2 (en) * 2005-01-24 2007-07-31 The Boeing Company Non-destructive stringer inspection apparatus and method
EP3022354B1 (en) 2013-08-23 2017-04-26 Dow Global Technologies LLC Textiles attached with low density polyurethane foams made using a combination of frothing and blowing methods

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3914279A (en) * 1972-02-25 1975-10-21 Du Pont Aminomethyleneaminomaleonitriles
DE2221771C3 (de) * 1972-05-04 1982-05-19 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von α-Iminonitrilen
GB1410080A (en) * 1972-12-21 1975-10-15 Nat Res Dev Oxime derivatives of 2,2-dimethyl-3-formyl cyclopropane carboxylic acid and their use as insecticides
US4277617A (en) * 1977-10-27 1981-07-07 Roussel Uclaf Process for the preparation of esters
JPS5837298B2 (ja) * 1977-12-01 1983-08-15 純郎 勝田 シクロプロパンカルボン酸エステル誘導体、シクロプロパンカルボン酸エステル誘導体の製造法、シクロプロパンカルボン酸エステル誘導体を含有する殺虫剤゜
DK158037C (da) * 1978-06-02 1990-08-13 Shell Int Research Fremgangsmaade til bekaempelse af acari ved hjaelp af oxyimino-substituerede cyclopropancarboxylsyreestere og z-isomerer af visse af disse estere til brug ved fremgangsmaaden
US4282249A (en) * 1978-06-02 1981-08-04 Shell Oil Company Oxyimino-substituted (1R, cis)-cyclopropanecarboxylate pesticides
IT1166681B (it) * 1979-03-09 1987-05-06 Montedison Spa Piretroidi
US4237163A (en) * 1979-06-11 1980-12-02 Shell Oil Company Hydrazono-substituted cyclopropanecarboxylate pesticides
US4219565A (en) * 1979-06-26 1980-08-26 Shell Oil Company Oxyimino-substituted cyclopropanecarboxylate pesticides
FR2471369A1 (fr) 1979-12-17 1981-06-19 Roussel Uclaf Nouvelles imines, derivant d'esters d'acides formyl cyclopropane carboxyliques, leur procede de preparation et leur application a la preparation d'esters insecticides

Also Published As

Publication number Publication date
PT72209A (fr) 1981-01-01
US4536345A (en) 1985-08-20
ATE15654T1 (de) 1985-10-15
JPS5692854A (en) 1981-07-27
EP0095794A1 (fr) 1983-12-07
US4434294A (en) 1984-02-28
ES497783A0 (es) 1981-11-01
US4312817A (en) 1982-01-26
PT72209B (fr) 1982-07-13
EP0030887B1 (fr) 1984-01-18
FR2471369B1 (es) 1982-06-11
EP0095794B1 (fr) 1985-09-18
IE802639L (en) 1981-06-17
DK535780A (da) 1981-06-18
IE51213B1 (en) 1986-11-12
CA1186322A (fr) 1985-04-30
HU187287B (en) 1985-12-28
FR2471369A1 (fr) 1981-06-19
EP0030887A3 (en) 1981-10-07
JPS6411013B2 (es) 1989-02-23
EP0030887A2 (fr) 1981-06-24
DE3066213D1 (en) 1984-02-23

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19970519