ES8200325A1 - Preparation of tertiary amines, and a catalyst for use therein - Google Patents
Preparation of tertiary amines, and a catalyst for use thereinInfo
- Publication number
- ES8200325A1 ES8200325A1 ES495138A ES495138A ES8200325A1 ES 8200325 A1 ES8200325 A1 ES 8200325A1 ES 495138 A ES495138 A ES 495138A ES 495138 A ES495138 A ES 495138A ES 8200325 A1 ES8200325 A1 ES 8200325A1
- Authority
- ES
- Spain
- Prior art keywords
- alcohols
- carboxylate
- aromatic
- mixture
- components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 150000003512 tertiary amines Chemical class 0.000 title 1
- -1 aromatic alcohols Chemical class 0.000 abstract 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 229920001744 Polyaldehyde Polymers 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001414 amino alcohols Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 150000003934 aromatic aldehydes Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000007942 carboxylates Chemical group 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 229920000768 polyamine Polymers 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 150000003139 primary aliphatic amines Chemical class 0.000 abstract 1
- 150000003333 secondary alcohols Chemical class 0.000 abstract 1
- 150000005619 secondary aliphatic amines Chemical class 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
- C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
- C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
- C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
- B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/16—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/17—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Tertiary monoamines and polyamines are prepared by reacting primary aromatic alcohols, aromatic aldehydes, secondary alcohols, ketones, polyether alcohols, aliphatic or aromatic polyhydric alcohols, polyaldehydes, amino alcohols and ethylene oxide adducts thereof with ammonia, a primary aliphatic amine or a secondary aliphatic amine, in the presence of a homogeneous colloidal catalyst prepared by reducing a mixture of components A and B, provided that at least one of A and B is a carboxylate or a mixture of components A, B and C, wherein A is a copper or silver carboxylate or intramolecular complex, component B is a Group VIII, manganese or zinc carboxylate or intramolecular complex, and component C is a fatty acid or alkali metal or alkaline earth metal carboxylate thereof.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11902179A JPS5643246A (en) | 1979-09-17 | 1979-09-17 | Preparation of tertiary amine |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8200325A1 true ES8200325A1 (en) | 1981-11-01 |
ES495138A0 ES495138A0 (en) | 1981-11-01 |
Family
ID=14751013
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES495138A Granted ES495138A0 (en) | 1979-09-17 | 1980-09-17 | A PROCEDURE FOR THE PREPARATION OF A TERTIARY AMINE |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS5643246A (en) |
BR (1) | BR8005955A (en) |
CA (1) | CA1129428A (en) |
DE (1) | DE3034433A1 (en) |
ES (1) | ES495138A0 (en) |
FR (1) | FR2464940A1 (en) |
GB (1) | GB2059792B (en) |
IT (1) | IT8024709A0 (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3338432A1 (en) * | 1983-10-22 | 1985-05-02 | Hoechst Ag, 6230 Frankfurt | METHOD FOR PRODUCING TERTIA AMINES |
US5266730A (en) * | 1987-10-16 | 1993-11-30 | Kao Corporation | Process for preparing N-substituted amine |
DE3852959T2 (en) * | 1987-10-16 | 1995-09-28 | Kao Corp | Process for the preparation of N-substituted amine. |
GB8819663D0 (en) * | 1988-08-18 | 1988-09-21 | Bp Chem Int Ltd | Chemical process |
CA2032449A1 (en) * | 1990-01-24 | 1991-07-25 | John F. Knifton | "twin-tailed" polyoxyalkylene tertiary amines |
KR101384413B1 (en) * | 2005-08-09 | 2014-04-10 | 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 | Alkylamino alkyloxy (alcohol) monoalkyl ether for acid gas scrubbing process |
DE102011004465A1 (en) * | 2010-09-10 | 2012-03-15 | Evonik Degussa Gmbh | Process for direct amination of secondary alcohols with ammonia to primary amines |
CN110407706A (en) * | 2019-07-22 | 2019-11-05 | 中国日用化学研究院有限公司 | A kind of homogeneous catalyst system preparing fat tertiary amine and application |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54125603A (en) * | 1978-03-16 | 1979-09-29 | Kao Corp | Preparation of aliphatic amine |
-
1979
- 1979-09-17 JP JP11902179A patent/JPS5643246A/en active Granted
-
1980
- 1980-09-11 GB GB8029402A patent/GB2059792B/en not_active Expired
- 1980-09-12 DE DE19803034433 patent/DE3034433A1/en not_active Withdrawn
- 1980-09-15 FR FR8019824A patent/FR2464940A1/en active Granted
- 1980-09-17 IT IT8024709A patent/IT8024709A0/en unknown
- 1980-09-17 CA CA360,415A patent/CA1129428A/en not_active Expired
- 1980-09-17 ES ES495138A patent/ES495138A0/en active Granted
- 1980-09-17 BR BR8005955A patent/BR8005955A/en unknown
Also Published As
Publication number | Publication date |
---|---|
FR2464940B1 (en) | 1983-12-02 |
GB2059792A (en) | 1981-04-29 |
CA1129428A (en) | 1982-08-10 |
JPS5643246A (en) | 1981-04-21 |
GB2059792B (en) | 1983-12-21 |
FR2464940A1 (en) | 1981-03-20 |
ES495138A0 (en) | 1981-11-01 |
BR8005955A (en) | 1981-03-31 |
IT8024709A0 (en) | 1980-09-17 |
DE3034433A1 (en) | 1981-04-02 |
JPS6130651B2 (en) | 1986-07-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Patent lapsed |
Effective date: 19960506 |