ES484574A1 - Procedimiento para la obtencion de esteres de acido ciclo- propancarboxilico sustituidos por fluoralquenilo de efecto insecticida - Google Patents
Procedimiento para la obtencion de esteres de acido ciclo- propancarboxilico sustituidos por fluoralquenilo de efecto insecticidaInfo
- Publication number
- ES484574A1 ES484574A1 ES484574A ES484574A ES484574A1 ES 484574 A1 ES484574 A1 ES 484574A1 ES 484574 A ES484574 A ES 484574A ES 484574 A ES484574 A ES 484574A ES 484574 A1 ES484574 A1 ES 484574A1
- Authority
- ES
- Spain
- Prior art keywords
- esters
- spiders
- fluoro
- alkenyl
- processes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/44—Iso-indoles; Hydrogenated iso-indoles
- C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
- C07D209/49—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide and having in the molecule an acyl radical containing a saturated three-membered ring, e.g. chrysanthemumic acid esters
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/58—Preparation of carboxylic acid halides
- C07C51/60—Preparation of carboxylic acid halides by conversion of carboxylic acids or their anhydrides or esters, lactones, salts into halides with the same carboxylic acid part
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/58—One oxygen atom, e.g. butenolide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
- C07D333/14—Radicals substituted by singly bound hetero atoms other than halogen
- C07D333/16—Radicals substituted by singly bound hetero atoms other than halogen by oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Environmental Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Indole Compounds (AREA)
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
- Furan Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Catching Or Destruction (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
1. Procedimiento para la obtención de esteres de ácido ciclopropancarboxílico sustituidos por fluoralquenilo de efecto insecticida, de fórmula I **(Fórmula 01)** donde R1 significa H, cloro, bromo, C1-4-alquilo, C1-4- halógenoalquilo, R2 significa cloro, bromo, C1-4-alquilo ó C1-4-halógenoalquilo, R3 significa halógeno, CF3 ó R1-CR-R2 y R significa el resto de un alcohol usual en los piretroides, caracterizado porque se hace reaccionar un ácido, o su derivado reactivo, de fórmula II **(Fórmula 02)**, donde R1, R2 y R3 tiene el significado anteriormente indicado y Z1 significa halógeno u OH, con un alcohol o su derivado reactivo de fórmula III R-Z2 (III) donde R tiene el significado anteriormente indicado y Z2 significa OH, Cl, o Br, en caso dado en presencia de disolventes, aceptores de ácido y/o catalizadores de transferencia de bases.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782842541 DE2842541A1 (de) | 1978-09-29 | 1978-09-29 | Fluoralkenylsubstituierte cyclopropancarbonsaeureester und ihre verwendung als insektizide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES484574A1 true ES484574A1 (es) | 1980-06-16 |
Family
ID=6050908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES484574A Expired ES484574A1 (es) | 1978-09-29 | 1979-09-28 | Procedimiento para la obtencion de esteres de acido ciclo- propancarboxilico sustituidos por fluoralquenilo de efecto insecticida |
Country Status (21)
| Country | Link |
|---|---|
| EP (1) | EP0009709B1 (es) |
| JP (1) | JPS5549341A (es) |
| AT (1) | ATE6249T1 (es) |
| AU (1) | AU531782B2 (es) |
| BG (1) | BG30623A3 (es) |
| BR (1) | BR7906171A (es) |
| CA (1) | CA1141389A (es) |
| CS (1) | CS209935B2 (es) |
| DD (1) | DD147907A5 (es) |
| DE (2) | DE2842541A1 (es) |
| DK (1) | DK409179A (es) |
| EG (1) | EG13891A (es) |
| ES (1) | ES484574A1 (es) |
| GR (1) | GR70672B (es) |
| IL (1) | IL58332A0 (es) |
| PL (1) | PL218599A1 (es) |
| PT (1) | PT70222A (es) |
| RO (1) | RO78868A (es) |
| SU (1) | SU1071196A3 (es) |
| TR (1) | TR20542A (es) |
| ZA (1) | ZA795166B (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3364135D1 (en) * | 1982-04-05 | 1986-07-24 | Ici Plc | Method for combating insect pests, and novel cyclopropane carboxylates useful as active ingredients therein |
| DE3312543A1 (de) * | 1983-04-07 | 1984-10-11 | Bayer Ag, 5090 Leverkusen | 2,2-dimethyl-3-(2-halogen-vinyl)-cyclopropancarbonsaeureester, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel |
| FR2687152A1 (fr) * | 1992-02-07 | 1993-08-13 | Roussel Uclaf | Nouveaux esters pyrethrinouides derives d'alcool furanique ou thiophenique, leur procede de preparation et leur application comme pesticides. |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5813522B2 (ja) * | 1974-10-24 | 1983-03-14 | 住友化学工業株式会社 | 新しいシクロプロパンカルボン酸エステルを含有する殺虫、殺ダニ剤 |
| US4183948A (en) * | 1977-01-24 | 1980-01-15 | Imperial Chemical Industries Limited | Halogenated esters |
| GB2000764B (en) * | 1977-03-23 | 1982-04-28 | Ici Ltd | Halogenated esters |
| IN150399B (es) * | 1978-01-20 | 1982-09-25 | Fmc Corp |
-
1978
- 1978-09-29 DE DE19782842541 patent/DE2842541A1/de not_active Withdrawn
-
1979
- 1979-09-17 DE DE7979103488T patent/DE2966668D1/de not_active Expired
- 1979-09-17 AT AT79103488T patent/ATE6249T1/de not_active IP Right Cessation
- 1979-09-17 EP EP79103488A patent/EP0009709B1/de not_active Expired
- 1979-09-21 CS CS796378A patent/CS209935B2/cs unknown
- 1979-09-24 BG BG044933A patent/BG30623A3/xx unknown
- 1979-09-25 PT PT70222A patent/PT70222A/pt unknown
- 1979-09-26 IL IL58332A patent/IL58332A0/xx unknown
- 1979-09-26 BR BR7906171A patent/BR7906171A/pt unknown
- 1979-09-26 SU SU792815597A patent/SU1071196A3/ru active
- 1979-09-27 GR GR60132A patent/GR70672B/el unknown
- 1979-09-27 TR TR20542A patent/TR20542A/xx unknown
- 1979-09-28 JP JP12427579A patent/JPS5549341A/ja active Pending
- 1979-09-28 CA CA000336559A patent/CA1141389A/en not_active Expired
- 1979-09-28 DD DD79215891A patent/DD147907A5/de unknown
- 1979-09-28 AU AU51311/79A patent/AU531782B2/en not_active Ceased
- 1979-09-28 ES ES484574A patent/ES484574A1/es not_active Expired
- 1979-09-28 DK DK409179A patent/DK409179A/da not_active Application Discontinuation
- 1979-09-28 ZA ZA00795166A patent/ZA795166B/xx unknown
- 1979-09-28 PL PL21859979A patent/PL218599A1/xx unknown
- 1979-09-29 EG EG573/79A patent/EG13891A/xx active
- 1979-09-29 RO RO7998813A patent/RO78868A/ro unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0009709B1 (en) | 1984-02-15 |
| CA1141389A (en) | 1983-02-15 |
| GR70672B (es) | 1982-12-06 |
| ZA795166B (en) | 1980-10-29 |
| DK409179A (da) | 1980-03-30 |
| CS209935B2 (en) | 1981-12-31 |
| RO78868B (ro) | 1983-07-30 |
| EP0009709A1 (de) | 1980-04-16 |
| BR7906171A (pt) | 1980-05-27 |
| RO78868A (ro) | 1983-08-03 |
| SU1071196A3 (ru) | 1984-01-30 |
| PL218599A1 (es) | 1980-06-16 |
| AU5131179A (en) | 1980-04-03 |
| BG30623A3 (en) | 1981-07-15 |
| ATE6249T1 (de) | 1984-03-15 |
| DE2966668D1 (en) | 1984-03-22 |
| AU531782B2 (en) | 1983-09-08 |
| DE2842541A1 (de) | 1980-05-22 |
| PT70222A (en) | 1979-10-01 |
| IL58332A0 (en) | 1979-12-30 |
| DD147907A5 (de) | 1981-04-29 |
| JPS5549341A (en) | 1980-04-09 |
| EG13891A (en) | 1982-09-30 |
| TR20542A (tr) | 1981-10-21 |
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