ES471423A1 - Procedimiento de extraccion de uranio a partir de acido fos-forico de via humeda. - Google Patents

Procedimiento de extraccion de uranio a partir de acido fos-forico de via humeda.

Info

Publication number
ES471423A1
ES471423A1 ES471423A ES471423A ES471423A1 ES 471423 A1 ES471423 A1 ES 471423A1 ES 471423 A ES471423 A ES 471423A ES 471423 A ES471423 A ES 471423A ES 471423 A1 ES471423 A1 ES 471423A1
Authority
ES
Spain
Prior art keywords
uranium
solvent
ammonium
acid
stage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES471423A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Azote et Produits Chimiques SA
Orano Cycle SA
Original Assignee
Azote et Produits Chimiques SA
Compagnie Generale des Matieres Nucleaires SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Azote et Produits Chimiques SA, Compagnie Generale des Matieres Nucleaires SA filed Critical Azote et Produits Chimiques SA
Publication of ES471423A1 publication Critical patent/ES471423A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/026—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries liquid-liquid extraction with or without dissolution in organic solvents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Engineering & Computer Science (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

Procedimiento de extracción de uranio a partir de ácido fosfórico de vía húmeda, según el cual se trata el ácido previamente oxidado con un disolvente orgánico constituido por una mezcla de ácido dialquilo fosfórico, en particular, el ácido di(2-etilhexil) fosfórico y de óxido de traialquifosfina en particular el óxido de tri-n-octilfosfina, en solución en un disolvente inerte no reactivo a fin de obtener ácido fosfórico desuraniado y un extracto orgánico constituido por el disolvente que contiene la mayor parte del uranio, después se separa el uranio del extracto en forma de uranilo tricarbonato de amonio por reacción con el amoníaco y el carbonato de amonio, y se vuelve a tratar el extracto desuraniado en la etapa de extracción caracterizado por el hecho de que se trata el extracto en un aparato de reextracción que incluye al menos 2 etapas, preferentemente 3 etapas, se introduce el extracto que hay que tratar al principio de la primera etapa, se introduce al final de la primera etapa a contra-corriente, amoníaco en forma de gas o en solución acuosa, controlando el pH de la primera etapa a fin de mantenerlo en un valor de 8,0 a 8,5, se inyecta al final de la primera etapa una solución acuosa de carbonato de amonio en cantidad que represente del 50 al 80% de la cantidad estequiométrica necesaria para neutralizar el ácido dialquilfosfórico contenido en el disolvente y transformar el uranio en uranilo tricarbonato de amonio y se regenera el disolvente amoniado obtenido después de reextracción por tratamiento con ácido antes de devolver a tratar en la etapa de extracción.
ES471423A 1977-07-05 1978-07-04 Procedimiento de extraccion de uranio a partir de acido fos-forico de via humeda. Expired ES471423A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7720552A FR2396803A1 (fr) 1977-07-05 1977-07-05 Procede d'extraction d'uranium a partir d'acide phosphorique de voie humide

Publications (1)

Publication Number Publication Date
ES471423A1 true ES471423A1 (es) 1979-05-16

Family

ID=9192964

Family Applications (1)

Application Number Title Priority Date Filing Date
ES471423A Expired ES471423A1 (es) 1977-07-05 1978-07-04 Procedimiento de extraccion de uranio a partir de acido fos-forico de via humeda.

Country Status (16)

Country Link
US (1) US4238457A (es)
JP (1) JPS5930649B2 (es)
AU (1) AU517756B2 (es)
BR (1) BR7804296A (es)
CA (1) CA1106616A (es)
DE (1) DE2829306C2 (es)
ES (1) ES471423A1 (es)
FR (1) FR2396803A1 (es)
GB (1) GB2014120B (es)
JO (1) JO1084B1 (es)
NL (1) NL175323C (es)
PL (1) PL111715B1 (es)
SU (1) SU858572A3 (es)
TR (1) TR20717A (es)
YU (1) YU42928B (es)
ZA (1) ZA783145B (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2459205A2 (fr) * 1979-06-15 1981-01-09 Commissariat Energie Atomique Procede de recuperation de l'uranium present dans une solution d'acide phosphorique
US4374806A (en) * 1980-06-17 1983-02-22 Wyoming Mineral Corporation Raffinate wash of second cycle solvent in the recovery of uranium from phosphate rock
US4544530A (en) * 1980-10-10 1985-10-01 Institute Of Nuclear Energy Research Separation process for the recovery of uranium from wet-process phosphoric acid
US4652432A (en) * 1981-02-26 1987-03-24 Prodeco, Inc. Process for recovering uranium using an alkyl pyrophosphoric acid and alkaline stripping solution
US4652431A (en) * 1981-02-26 1987-03-24 Prodeco, Inc. Process for recovering uranium using an alkyl pyrophosphoric acid and alkaline stripping solution
FR2539549B1 (fr) * 1983-01-17 1988-10-14 Rhone Poulenc Chim Base Procede de recuperation globale de l'uranium, de l'yttrium, du thorium et des terres rares contenus dans une phase organique
US5419880A (en) * 1993-10-08 1995-05-30 Falconbridge, Ltd. Controlled acid-strong acid strip process
FR2990206B1 (fr) 2012-05-07 2014-06-06 Commissariat Energie Atomique Nouveaux composes bifonctionnels utiles comme ligands de l'uranium(vi), leurs procedes de synthese et leurs utilisations

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2859094A (en) * 1957-02-07 1958-11-04 John M Schmitt Uranium extraction process using synergistic reagents
US3711591A (en) * 1970-07-08 1973-01-16 Atomic Energy Commission Reductive stripping process for the recovery of uranium from wet-process phosphoric acid

Also Published As

Publication number Publication date
JPS5442322A (en) 1979-04-04
JO1084B1 (en) 1982-07-10
ZA783145B (en) 1979-06-27
DE2829306C2 (de) 1984-09-27
NL7806490A (nl) 1979-01-09
AU3755178A (en) 1980-01-03
GB2014120B (en) 1982-03-10
NL175323C (nl) 1984-10-16
YU42928B (en) 1989-02-28
YU156278A (en) 1982-08-31
JPS5930649B2 (ja) 1984-07-28
NL175323B (nl) 1984-05-16
BR7804296A (pt) 1979-02-28
DE2829306A1 (de) 1979-01-18
GB2014120A (en) 1979-08-22
TR20717A (tr) 1982-05-20
PL208156A1 (pl) 1979-04-23
CA1106616A (en) 1981-08-11
FR2396803A1 (fr) 1979-02-02
US4238457A (en) 1980-12-09
SU858572A3 (ru) 1981-08-23
FR2396803B1 (es) 1980-01-18
AU517756B2 (en) 1981-08-27
PL111715B1 (en) 1980-09-30

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19991102