ES465979A1 - Un procedimiento para la preparacion de una dispersion acuo-sa de copolimero. - Google Patents
Un procedimiento para la preparacion de una dispersion acuo-sa de copolimero.Info
- Publication number
- ES465979A1 ES465979A1 ES465979A ES465979A ES465979A1 ES 465979 A1 ES465979 A1 ES 465979A1 ES 465979 A ES465979 A ES 465979A ES 465979 A ES465979 A ES 465979A ES 465979 A1 ES465979 A1 ES 465979A1
- Authority
- ES
- Spain
- Prior art keywords
- weight
- monomers
- esters
- acid
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006185 dispersion Substances 0.000 title abstract 3
- 229920001577 copolymer Polymers 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000012986 chain transfer agent Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 230000009477 glass transition Effects 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 229910052500 inorganic mineral Chemical class 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 abstract 1
- 239000011707 mineral Chemical class 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 abstract 1
- 229920001567 vinyl ester resin Polymers 0.000 abstract 1
- -1 vinyl esters ions Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paper (AREA)
Abstract
Un procedimiento para la preparación de una dispersión acuosa de copolímero soluble por adición de un agente alcalino encontrándose la temperatura de transición vítrea comprendida entre -60 y +140ºC, preferentemente entre -30 y + 100ºC y su valor K entre 20 y 130, preferentemente entre 20 y 80, el pH de la dispersión acuosa se encuentra comprendido entre 2 y 7 y su porcentaje de materias secas entre el 20 y 50%, preferentemente entre el 20 y 40% en peso caracterizado porque se someten dichos monómeros a reacción de interpolimerización en emulsión acuosa: a) del 0,75 al 5,75% en peso de uno o varios monómeros seleccionados entre el ácido acrílico, el ácido metacrílico, el ácido crotónico, el ácido itacónico, el anhídrido maleico y los semiésteres del ácido maleico, b) del 50 al 99,25% en peso de uno o varios monómeros seleccionados entre los ésteres del ácido acrílico o metacrílico con un alcohol que contiene de 1 a 18 átomos de carbono y los ésteres vinílicos de ácido carboxílicos ,que comprenden de 1 a 18 átomos de carbono o de ácidos minerales; c) del 0 al 49,25% en peso de uno o varios monómeros monoetilénicos, distintos a los ésteres anteriormente citados, formando homopolímeros insolubles en agua, y d) del 0 al 5 en peso de uno o varios monómeros monoetilénicos que comprenden por lo menos un grupo polar, en presencia de 0,01 al 5%, preferentemente del 0,1 al 1,5%, de un catalizador soluble en agua y del 0,01 al 5% de un agente de transferencia de cadena, expresándose los porcentajes con relación al peso total de los monómeros.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7701015A FR2377426A1 (fr) | 1977-01-14 | 1977-01-14 | Dispersions aqueuses de copolymeres solubilisables pour l'impression et l'enduction |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES465979A1 true ES465979A1 (es) | 1979-05-16 |
Family
ID=9185496
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES465979A Expired ES465979A1 (es) | 1977-01-14 | 1978-01-13 | Un procedimiento para la preparacion de una dispersion acuo-sa de copolimero. |
Country Status (8)
| Country | Link |
|---|---|
| BE (1) | BE862842A (es) |
| DE (1) | DE2801099A1 (es) |
| DK (1) | DK587677A (es) |
| ES (1) | ES465979A1 (es) |
| FR (1) | FR2377426A1 (es) |
| GB (1) | GB1560870A (es) |
| IT (1) | IT1106967B (es) |
| NL (1) | NL7800357A (es) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3101892A1 (de) * | 1981-01-22 | 1982-08-26 | Röhm GmbH, 6100 Darmstadt | Verfahren zur herstellung von waessrigen kunststoffdispersionen mit hohem pigmentbindevermoegen |
| DE3147007C2 (de) * | 1981-11-27 | 1983-10-06 | Roehm Gmbh, 6100 Darmstadt | Selbstvernetzende wäßrige Kunststoff dispersion |
| DE3531601A1 (de) * | 1985-09-04 | 1987-03-05 | Wacker Chemie Gmbh | Waermefester haftklebestoff |
| US4745025A (en) * | 1986-02-19 | 1988-05-17 | Air Products And Chemicals, Inc. | Nonwoven products bonded with binder emulsions of vinyl acetate/ethylene copolymers having improved solvent resistance |
| DE4122990C2 (de) * | 1991-07-11 | 1994-04-28 | Huber Fa Michael Muenchen | Wasserverdünnbare Bronze- oder Effektdruckfarbe, deren Verwendung und Verfahren zur Herstellung eines Bronze- oder Effektdruckes |
| JPH06509599A (ja) * | 1991-08-09 | 1994-10-27 | ミネソタ・マイニング・アンド・マニュファクチュアリング・カンパニー | 水ベース化学組成物 |
| DE4227974C2 (de) * | 1992-08-26 | 1996-04-18 | Stockhausen Chem Fab Gmbh | Alkoxygruppenhaltige Copolymerisate, Verfahren zu ihrer Herstellung und ihre Verwendung zum Nachgerben von Leder |
| DE4317035A1 (de) * | 1993-05-21 | 1994-11-24 | Basf Ag | Wäßrige Polymerisatdispersionen |
| DE4317036A1 (de) * | 1993-05-21 | 1994-11-24 | Basf Ag | Polymerisatpulver |
| US5821283A (en) * | 1995-10-06 | 1998-10-13 | Rohm And Haas Company | Ink composition and method for preparing |
| US6160059A (en) | 1996-07-26 | 2000-12-12 | Cook Composites And Polymers Co. | Bulk polymerization process for preparing solid acrylic resin |
| WO1999023119A1 (en) | 1997-10-31 | 1999-05-14 | Cognis Corporation | Continuous bulk polymerization process |
| JP4690006B2 (ja) * | 2004-10-06 | 2011-06-01 | 理想科学工業株式会社 | 孔版印刷用水性インキおよび孔版印刷方法 |
| CN114316117B (zh) * | 2020-09-30 | 2023-09-26 | 四川赛华睿科技有限责任公司 | 无氟处理剂及防油纸类制品 |
-
1977
- 1977-01-14 FR FR7701015A patent/FR2377426A1/fr active Granted
- 1977-12-30 DK DK587677A patent/DK587677A/da not_active Application Discontinuation
-
1978
- 1978-01-11 DE DE19782801099 patent/DE2801099A1/de not_active Withdrawn
- 1978-01-12 GB GB1151/78A patent/GB1560870A/en not_active Expired
- 1978-01-12 IT IT67051/78A patent/IT1106967B/it active
- 1978-01-12 BE BE184257A patent/BE862842A/xx not_active IP Right Cessation
- 1978-01-12 NL NL7800357A patent/NL7800357A/xx not_active Application Discontinuation
- 1978-01-13 ES ES465979A patent/ES465979A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IT7867051A0 (it) | 1978-01-12 |
| FR2377426B1 (es) | 1980-04-18 |
| GB1560870A (en) | 1980-02-13 |
| DE2801099A1 (de) | 1978-07-20 |
| BE862842A (fr) | 1978-07-12 |
| FR2377426A1 (fr) | 1978-08-11 |
| IT1106967B (it) | 1985-11-18 |
| DK587677A (da) | 1978-07-15 |
| NL7800357A (nl) | 1978-07-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19991108 |