ES460457A1 - Procedimiento mejorado para la hidroformilacion de una alfa-olefina. - Google Patents

Procedimiento mejorado para la hidroformilacion de una alfa-olefina.

Info

Publication number
ES460457A1
ES460457A1 ES460457A ES460457A ES460457A1 ES 460457 A1 ES460457 A1 ES 460457A1 ES 460457 A ES460457 A ES 460457A ES 460457 A ES460457 A ES 460457A ES 460457 A1 ES460457 A1 ES 460457A1
Authority
ES
Spain
Prior art keywords
aldehydes
amount
olefin
liquid phase
phase composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES460457A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ES460457A1 publication Critical patent/ES460457A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procedimiento mejorado para la hidroformilación de una alfa-olefina que contiene de 2 a 20 átomos de carbono para producir aldehídos a partir de ella, que comprende alimentar dicha olefina, monóxido de carbono e hidrógeno a una composición homogénea en fase líquida que contiene una cantidad catalítica de rodio-carbonilo complejado con una triarilfosfina presente en una cantidad mayor que la cantidad que forma complejo con dicho rodio-carbonilo, un disolvente que comprende productos de condensación de aldehídos, y los productos de aldehído de la reacción, en donde la temperatura de la composición es de aproximadamente 50ºC a aproximadamente 145ºC, la presión total de monóxido de carbono e hidrógeno es inferior a 31,5 Kg./cm2 absolutos, y la presión parcial atribuible al monóxido de carbono no es superior a aproximadamente al 75% de la presión total.
ES460457A 1976-07-07 1977-07-06 Procedimiento mejorado para la hidroformilacion de una alfa-olefina. Expired ES460457A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/703,130 US4221743A (en) 1976-07-07 1976-07-07 Hydroformylation process

Publications (1)

Publication Number Publication Date
ES460457A1 true ES460457A1 (es) 1978-10-01

Family

ID=24824139

Family Applications (1)

Application Number Title Priority Date Filing Date
ES460457A Expired ES460457A1 (es) 1976-07-07 1977-07-06 Procedimiento mejorado para la hidroformilacion de una alfa-olefina.

Country Status (18)

Country Link
US (1) US4221743A (es)
JP (1) JPS5833209B2 (es)
AR (1) AR226520A1 (es)
AT (1) AT352090B (es)
AU (1) AU516134B2 (es)
BE (1) BE856542A (es)
BR (1) BR7704416A (es)
CA (1) CA1090824A (es)
DE (1) DE2730527C2 (es)
ES (1) ES460457A1 (es)
FR (1) FR2357511A1 (es)
GB (1) GB1582349A (es)
IT (1) IT1080581B (es)
MX (1) MX146675A (es)
NL (1) NL189346C (es)
PL (1) PL103858B1 (es)
SE (1) SE446448B (es)
ZA (1) ZA773724B (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4215077A (en) * 1978-02-09 1980-07-29 Kuraray Co., Ltd. Hydroformylation of olefins
DE2840168A1 (de) * 1978-09-15 1980-03-27 Basf Ag Verfahren zur herstellung von aldehyden
US4297239A (en) * 1979-07-16 1981-10-27 Union Carbide Corporation Hydroformylation catalyst reactivation
FR2459683A1 (fr) * 1979-06-22 1981-01-16 Ugine Kuhlmann Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene
JPS5626830A (en) * 1979-08-10 1981-03-16 Kuraray Co Ltd Hydroformylation of lower olefin
US4687874A (en) * 1980-02-12 1987-08-18 Exxon Research And Engineering Company Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts
US4374278A (en) * 1980-02-28 1983-02-15 Union Carbide Corporation Hydroformylation catalyst reactivation
US4343950A (en) * 1980-06-16 1982-08-10 Union Carbide Corporation Rhodium-catalyzed oxidation process for producing carboxylic acids
US4605780A (en) * 1980-09-24 1986-08-12 Union Carbide Corporation Reactivation of rhodium complex hydroformylation catalysts
US4388476A (en) * 1981-05-01 1983-06-14 Eastman Kodak Company Hydroformylation process with rhodium catalyst and oxygen stabilization thereof
US4446074A (en) * 1981-12-24 1984-05-01 Union Carbide Corporation Preparation of rhodium complex compounds
US4528403A (en) * 1982-10-21 1985-07-09 Mitsubishi Chemical Industries Ltd. Hydroformylation process for preparation of aldehydes and alcohols
US4822917A (en) * 1986-12-23 1989-04-18 Mitsubishi Chemical Industries Limited Process for the hydroformylation of an olefin
US4873213A (en) * 1988-08-12 1989-10-10 Puckette Thomas A Low pressure rhodium catalyzed hydroformylation of olefins
US4861918A (en) * 1988-08-12 1989-08-29 Union Carbide Corporation Reactivation of hydroformylation catalysts
US4929767A (en) * 1988-08-12 1990-05-29 Union Carbide Chemicals And Plastics Company Inc. Treatment of rhodium catalysts
DE4316180A1 (de) * 1992-09-16 1994-11-17 Basf Ag Verfahren zur Herstellung von Aldehyden
US5290743A (en) * 1993-03-22 1994-03-01 Arco Chemical Technology L.P. Process for regenerating a deactivated rhodium hydroformylation catalyst system
GB0113079D0 (en) 2001-05-30 2001-07-18 Kvaerner Process Tech Ltd Process
JP3656250B2 (ja) 2002-04-26 2005-06-08 日本電気硝子株式会社 陰極線管用ガラス物品
US9174907B2 (en) 2012-06-04 2015-11-03 Dow Technology Investments Llc Hydroformylation process
CN104248994B (zh) * 2013-06-25 2018-03-20 中国石油化工股份有限公司 羰基化铑膦催化剂的活性恢复方法
TWI758353B (zh) * 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840363A (zh) * 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
EP3710161B1 (en) 2017-11-13 2024-10-16 Dow Technology Investments LLC Processes for recovery of rhodium from a hydroformylation process

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3520937A (en) * 1966-04-05 1970-07-21 Basf Ag Processing oxo reaction mixtures
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US3555098A (en) * 1967-12-13 1971-01-12 Union Oil Co Hydroformylation
GB1338237A (en) * 1969-12-22 1973-11-21 Union Carbide Corp Hydroformylation process
US3920754A (en) * 1970-09-11 1975-11-18 Celanese Corp Hydroformylation process
JPS511687A (en) * 1974-06-27 1976-01-08 Sadao Ukita Tenpura hanbaagunadono nenseizairyono katakeiseinisaishiteno atsumichoseisochi
JPS5123212A (en) * 1974-08-17 1976-02-24 Mitsubishi Chem Ind Arudehidono seizohoho

Also Published As

Publication number Publication date
PL199421A1 (pl) 1978-04-24
FR2357511B1 (es) 1983-10-07
SE7707905L (sv) 1978-01-08
JPS537608A (en) 1978-01-24
DE2730527C2 (de) 1983-10-20
ATA482277A (de) 1979-02-15
ZA773724B (en) 1978-05-30
AU516134B2 (en) 1981-05-21
BE856542A (fr) 1978-01-06
SE446448B (sv) 1986-09-15
IT1080581B (it) 1985-05-16
MX146675A (es) 1982-07-27
NL189346C (nl) 1993-03-16
PL103858B1 (pl) 1979-07-31
US4221743A (en) 1980-09-09
GB1582349A (en) 1981-01-07
FR2357511A1 (fr) 1978-02-03
BR7704416A (pt) 1978-05-02
DE2730527A1 (de) 1978-01-12
AT352090B (de) 1979-08-27
CA1090824A (en) 1980-12-02
JPS5833209B2 (ja) 1983-07-18
AU2676377A (en) 1979-01-11
AR226520A1 (es) 1982-07-30
NL7707498A (nl) 1978-01-10

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