ES459000A1 - Catalyst for oxidation reactions and process for its production - Google Patents
Catalyst for oxidation reactions and process for its productionInfo
- Publication number
- ES459000A1 ES459000A1 ES459000A ES459000A ES459000A1 ES 459000 A1 ES459000 A1 ES 459000A1 ES 459000 A ES459000 A ES 459000A ES 459000 A ES459000 A ES 459000A ES 459000 A1 ES459000 A1 ES 459000A1
- Authority
- ES
- Spain
- Prior art keywords
- vanadium
- production
- catalyst
- oxidation reactions
- activated catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/0012—Galenical forms characterised by the site of application
- A61K9/0014—Skin, i.e. galenical aspects of topical compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
- A61K47/08—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing oxygen, e.g. ethers, acetals, ketones, quinones, aldehydes, peroxides
- A61K47/10—Alcohols; Phenols; Salts thereof, e.g. glycerol; Polyethylene glycols [PEG]; Poloxamers; PEG/POE alkyl ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Pharmacology & Pharmacy (AREA)
- Animal Behavior & Ethology (AREA)
- Medicinal Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Public Health (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Furan Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Activated catalyst for oxidation reactions on the basis of mixed oxides of vanadium and phosphorus, characterized in that the vanadium has an average valence of less than +3.9. The activated catalyst is produced using a process wherein a mixed oxide, in which the vanadium has an average valence of +3.9 to more than +4, is activated at temperatures of 300 DEG to 500 DEG C. by passing over it a gaseous hydrocarbon component having 2 to 6 carbon atoms with the exclusion of molecular oxygen. The activated catalyst is used for the production of maleic anhydride from straight-chain C4-hydrocarbons in the gaseous phase.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH646676A CH619870A5 (en) | 1976-05-21 | 1976-05-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES459000A1 true ES459000A1 (en) | 1978-04-01 |
Family
ID=4310071
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES459000A Expired ES459000A1 (en) | 1976-05-21 | 1977-05-20 | Catalyst for oxidation reactions and process for its production |
Country Status (18)
Country | Link |
---|---|
US (1) | US4181628A (en) |
JP (1) | JPS531190A (en) |
AT (2) | AT354407B (en) |
BE (1) | BE854917A (en) |
CA (1) | CA1092086A (en) |
CH (1) | CH619870A5 (en) |
DE (1) | DE2636800C2 (en) |
DK (1) | DK149584C (en) |
ES (1) | ES459000A1 (en) |
FR (1) | FR2351702A1 (en) |
GB (1) | GB1520708A (en) |
IE (1) | IE44903B1 (en) |
IL (1) | IL52130A (en) |
IT (1) | IT1078290B (en) |
LU (1) | LU77384A1 (en) |
NL (1) | NL7705586A (en) |
TR (1) | TR19832A (en) |
ZA (1) | ZA772916B (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4151116A (en) * | 1977-08-05 | 1979-04-24 | Halcon Research And Development Corporation | Preparation of maleic anhydride |
CA1140912A (en) * | 1979-07-30 | 1983-02-08 | Ramon A. Mount | Process for preparing phosphorus-vanadium-oxygen catalysts |
DE3010710A1 (en) * | 1980-03-20 | 1981-09-24 | Chemische Werke Hüls AG, 4370 Marl | METHOD FOR PRODUCING CATALYSTS FOR THE GAS PHASE OXIDATION OF SATURED AND / OR UNSATURATED C (ARROW DOWN) 4 (ARROW DOWN) HYDROCARBONS TO MALEIC ACID ANHYDRIDE |
US4315864A (en) * | 1980-10-22 | 1982-02-16 | Standard Oil Company (Ohio) | Preparation of maleic anhydride |
US4359405A (en) * | 1980-12-22 | 1982-11-16 | Monsanto Company | Solvent conditioning of phosphorus-vanadium-oxygen catalysts |
EP0056528A3 (en) * | 1981-01-02 | 1983-01-05 | Monsanto Company | Catalyst intermediate, catalyst prepared therefrom, and method for preparing maleic anhydride |
CA1202950A (en) * | 1981-12-28 | 1986-04-08 | The Standard Oil Company | In situ activation process for fluid bed oxidation catalysts |
US4748140A (en) * | 1981-12-28 | 1988-05-31 | The Standard Oil Company | In situ activation process for fluid bed oxidation catalysts |
US4435521A (en) | 1982-05-24 | 1984-03-06 | Exxon Research & Engineering Co. | Heterogeneous process for preparing vanadium phosphorus oxygen containing catalyst composition |
US4569925A (en) * | 1982-07-01 | 1986-02-11 | Exxon Research & Engineering Co. | Process for preparing a vanadium phosphorus oxygen catalyst composition by an organic solution method |
NO151026C (en) * | 1982-11-26 | 1985-01-30 | Saetersmoen A S | INSECTICID AND AKARICID MIXTURE CONTAINING GELATIN, AND USING THE MIXTURE FOR AA FIGHTING INSECT AND MEDICINE |
US4518523A (en) * | 1983-03-04 | 1985-05-21 | The Standard Oil Company | Method for adding make-up fluid bed oxidation catalysts for fluid bed oxidation catalysts containing the mixed oxides of vanadium and phosphorus |
US5168090A (en) * | 1990-10-04 | 1992-12-01 | Monsanto Company | Shaped oxidation catalyst structures for the production of maleic anhydride |
US5474960A (en) * | 1994-06-15 | 1995-12-12 | The Standard Oil Company | Process for reactivating a fluid bed catalyst in a reactor dipley |
JP3817763B2 (en) * | 1994-12-22 | 2006-09-06 | 三菱化学株式会社 | Method for producing maleic anhydride |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2474334A (en) * | 1947-04-10 | 1949-06-28 | Standard Oil Dev Co | Producing maleic acid by oxidation of cyclohexane |
US3156707A (en) * | 1962-05-17 | 1964-11-10 | Petro Tex Chem Corp | Oxidation of aliphatic hydrocarbons |
US3293268A (en) * | 1964-03-23 | 1966-12-20 | Princeton Chemical Res Inc | Production of maleic anhydride by oxidation of n-butane |
UST864008I4 (en) | 1968-12-18 | 1969-07-15 | Defensive publication | |
US3915892A (en) * | 1971-11-22 | 1975-10-28 | Chevron Res | Vanadium-phosphorus mixed oxide oxidation catalysts |
BE791770A (en) * | 1971-11-22 | 1973-05-22 | Chevron Res | VANADIUM OXIDE AND PHOSPHORUS OXIDATION CATALYSTS |
US3985775A (en) * | 1971-11-22 | 1976-10-12 | Chevron Research Company | Vanadium-phosphorus oxide oxidation of N-butane to maleic anhydride |
US3907833A (en) * | 1972-05-15 | 1975-09-23 | Celanese Corp | Process for oxidizing a hydrocarbon to maleic anhydride and acetic acid |
US3888886A (en) * | 1972-06-08 | 1975-06-10 | Mobil Oil Corp | Oxidation of alkanes to maleic anhydride using promoted vanadium-phosphorus catalyst |
US4017521A (en) | 1972-06-19 | 1977-04-12 | Chevron Research Company | Process for the manufacture of maleic anhydride using high surface area catalyst |
DE2353136A1 (en) | 1972-10-27 | 1974-05-02 | Standard Oil Co | PROCESS FOR REACTIVATING PHOSPHORUS-VANADIUM-OXYGEN CATALYSTS |
USB330354I5 (en) * | 1973-02-07 | 1975-01-28 | ||
NL165161C (en) * | 1973-04-16 | 1981-03-16 | Monsanto Co | PROCESS FOR PREPARING MALINIC ACID ANHYDRIDE AND FOR PREPARING A CATALYST SUITABLE FOR THIS. |
US4006167A (en) * | 1974-06-28 | 1977-02-01 | Ube Industries, Ltd. | Vapor phase oxidation of unsaturated aliphatic hydrocarbon to maleic anhydride using a catalyst consisting essentially of the oxides of vanadium, phosphorous, zirconium, and manganese |
US3975300A (en) * | 1974-07-01 | 1976-08-17 | Mobil Oil Corporation | One step method of preparation of vanadium-phosphorus complex in the absence of hydrogen halide |
US3977998A (en) * | 1974-09-03 | 1976-08-31 | Monsanto Company | Process for preparing phosphorus-vanadium-oxygen catalysts |
US4064070A (en) * | 1974-12-23 | 1977-12-20 | Chevron Research Company | Catalyst for producing maleic anhydride |
US4016105A (en) * | 1975-02-07 | 1977-04-05 | Petro-Tex Chemical Corporation | Catalyst preparative method |
US4018709A (en) * | 1975-03-17 | 1977-04-19 | Petro-Tex Chemical Corporation | Catalyst for preparing maleic anhydride from C4 hydrocarbons |
US4013586A (en) * | 1975-07-24 | 1977-03-22 | Monsanto Company | Vanadium catalysts prepared with phosphonates |
-
1976
- 1976-05-21 CH CH646676A patent/CH619870A5/de not_active IP Right Cessation
- 1976-08-16 DE DE2636800A patent/DE2636800C2/en not_active Expired
-
1977
- 1977-05-16 ZA ZA00772916A patent/ZA772916B/en unknown
- 1977-05-18 GB GB20878/77A patent/GB1520708A/en not_active Expired
- 1977-05-19 IE IE1029/77A patent/IE44903B1/en not_active IP Right Cessation
- 1977-05-20 JP JP5782177A patent/JPS531190A/en active Granted
- 1977-05-20 DK DK223577A patent/DK149584C/en active
- 1977-05-20 FR FR7715562A patent/FR2351702A1/en active Granted
- 1977-05-20 IL IL52130A patent/IL52130A/en unknown
- 1977-05-20 IT IT49482/77A patent/IT1078290B/en active
- 1977-05-20 NL NL7705586A patent/NL7705586A/en active Search and Examination
- 1977-05-20 LU LU77384A patent/LU77384A1/xx unknown
- 1977-05-20 AT AT363277A patent/AT354407B/en not_active IP Right Cessation
- 1977-05-20 TR TR19832A patent/TR19832A/en unknown
- 1977-05-20 ES ES459000A patent/ES459000A1/en not_active Expired
- 1977-05-23 US US05/799,331 patent/US4181628A/en not_active Expired - Lifetime
- 1977-05-23 BE BE177809A patent/BE854917A/en not_active IP Right Cessation
- 1977-05-24 CA CA279,058A patent/CA1092086A/en not_active Expired
-
1978
- 1978-06-07 AT AT0413978A patent/AT363277B/en active
Also Published As
Publication number | Publication date |
---|---|
DE2636800A1 (en) | 1977-12-08 |
CH619870A5 (en) | 1980-10-31 |
NL7705586A (en) | 1977-11-23 |
ZA772916B (en) | 1978-04-26 |
IT1078290B (en) | 1985-05-08 |
IE44903L (en) | 1977-11-21 |
LU77384A1 (en) | 1977-12-22 |
JPS531190A (en) | 1978-01-07 |
DK149584B (en) | 1986-08-04 |
DK223577A (en) | 1977-11-22 |
US4181628A (en) | 1980-01-01 |
ATA363277A (en) | 1979-06-15 |
IE44903B1 (en) | 1982-05-05 |
DK149584C (en) | 1987-01-12 |
FR2351702B1 (en) | 1982-09-03 |
DE2636800C2 (en) | 1986-02-27 |
GB1520708A (en) | 1978-08-09 |
AT354407B (en) | 1979-01-10 |
JPS616702B2 (en) | 1986-02-28 |
BE854917A (en) | 1977-11-23 |
AT363277B (en) | 1979-06-15 |
ATA413978A (en) | 1980-12-15 |
IL52130A0 (en) | 1977-07-31 |
IL52130A (en) | 1980-11-30 |
CA1092086A (en) | 1980-12-23 |
TR19832A (en) | 1980-01-28 |
FR2351702A1 (en) | 1977-12-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 19971103 |