ES444223A1 - Oxidation catalysts - Google Patents

Oxidation catalysts

Info

Publication number
ES444223A1
ES444223A1 ES444223A ES444223A ES444223A1 ES 444223 A1 ES444223 A1 ES 444223A1 ES 444223 A ES444223 A ES 444223A ES 444223 A ES444223 A ES 444223A ES 444223 A1 ES444223 A1 ES 444223A1
Authority
ES
Spain
Prior art keywords
catalyst
mixture
isobutylene
propylene
oxidation catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES444223A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of ES444223A1 publication Critical patent/ES444223A1/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/686—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

An improved ammoniacal oxidation process of propylene or vapor phase isobutylene to produce acrylonitrile or methacrylonitrile, by contacting propylene or isobutylene, ammonia, and molecular oxygen with a catalyst at a temperature of about 200ºC to about 600ºC, where the improvement comprises using as catalyst a catalyst of the formula Aa Cc Dd Cre Bif Mo12 Ox wherein A is an alkali metal, Tl, In, Ag, Cu, Sn, W, a rare earth metal or a mixture thereof; C is an element of group IIA or group IIb, Mn or a mixture thereof; D is Ni, Co, P, Ge, B or a mixture thereof; and in which a is 0 to 4; c is 0.5 to 20; d is 0 to 2; e and f are 0.1 to 12; and x is the number of oxygens required to satisfy the valence requirements of the other elements present. (Machine-translation by Google Translate, not legally binding)
ES444223A 1975-01-13 1976-01-12 Oxidation catalysts Expired ES444223A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US53540375A 1975-01-13 1975-01-13

Publications (1)

Publication Number Publication Date
ES444223A1 true ES444223A1 (en) 1977-05-01

Family

ID=24134033

Family Applications (1)

Application Number Title Priority Date Filing Date
ES444223A Expired ES444223A1 (en) 1975-01-13 1976-01-12 Oxidation catalysts

Country Status (13)

Country Link
JP (1) JPS5195991A (en)
AT (1) AT348978B (en)
BR (1) BR7600141A (en)
CA (1) CA1075669A (en)
DD (1) DD123739A5 (en)
DE (1) DE2600128A1 (en)
ES (1) ES444223A1 (en)
FR (1) FR2297082A1 (en)
GB (1) GB1497589A (en)
IN (1) IN145044B (en)
IT (1) IT1054781B (en)
NL (1) NL7600312A (en)
SU (1) SU718000A3 (en)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7909142A (en) * 1978-12-26 1980-06-30 Halcon Res & Dev CATALYST AND METHOD FOR PREPARING METHACRYLIC ACID.
NZ197767A (en) * 1980-08-04 1983-04-12 Merck & Co Inc Ammoxidation catalyst containing manganese chromium and molybdenum oxides
JPS57130548A (en) 1981-02-05 1982-08-13 Mitsubishi Chem Ind Ltd Catalyst composition
JP6138161B2 (en) 2012-01-30 2017-05-31 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Process for producing butadiene and / or butenes from n-butane
EP2897927B1 (en) 2012-09-20 2016-06-22 Basf Se Method for producing butadiene with removal of oxygen from c4 hydrocarbon streams
JP2016502549A (en) 2012-12-06 2016-01-28 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Oxidative dehydrogenation of n-butenes to butadiene
US9399606B2 (en) 2012-12-06 2016-07-26 Basf Se Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene
US10144681B2 (en) 2013-01-15 2018-12-04 Basf Se Process for the oxidative dehydrogenation of N-butenes to butadiene
KR20150105456A (en) 2013-01-15 2015-09-16 바스프 에스이 Method for producing 1,3-butadiene from n-butenes by oxidative dehydrogenation
KR20150105455A (en) 2013-01-16 2015-09-16 바스프 에스이 Method for producing butadiene by oxidative dehydrogenation of n-butenes by monitoring the peroxide-content during product processing
US20160152530A1 (en) 2013-07-10 2016-06-02 Basf Se Method for the oxidative dehydrogenation of n-butenes to butadiene
EP3063112B1 (en) 2013-10-30 2017-12-13 Basf Se Method for preparing 1,3-butadiene from n-butenes by oxidative dehydration
JP2017502988A (en) 2014-01-13 2017-01-26 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Reactor start-up for oxidative dehydrogenation of n-butene
DE102014203725A1 (en) 2014-02-28 2015-09-03 Basf Se Oxidation catalyst with saddle-shaped carrier shaped body
EP3180298B1 (en) 2014-08-12 2018-11-07 Basf Se Method for producing 1,3-butadiene from n-butenes by oxidative dehydrogenation
WO2016046009A1 (en) 2014-09-26 2016-03-31 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
CN107074691A (en) 2014-11-03 2017-08-18 巴斯夫欧洲公司 The method for preparing 1,3 butadiene from n-butene by oxidative dehydrogenation
EA034435B1 (en) 2014-11-14 2020-02-07 Басф Се Method for producing 1,3-butadienes by dehydrogenating n-butenes, a material flow containing butanes and 2-butenes being provided
WO2016150940A1 (en) 2015-03-26 2016-09-29 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
CN107428636A (en) 2015-03-26 2017-12-01 巴斯夫欧洲公司 1,3 butadiene are manufactured by oxidative dehydrogenation by n-butene
EP3274320B1 (en) 2015-03-26 2019-02-27 Basf Se Method for preparing 1.3-butadiene from n-butenes by oxidative dehydrogenation
WO2016151074A1 (en) 2015-03-26 2016-09-29 Basf Se Method for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
KR20180101361A (en) 2015-12-03 2018-09-12 바스프 에스이 Method for producing butadiene by oxidative dehydrogenation of n-butene
WO2017121739A1 (en) 2016-01-13 2017-07-20 Basf Se Method for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
CN108884003A (en) 2016-02-04 2018-11-23 巴斯夫欧洲公司 The method that 1,3- butadiene is prepared by n- butylene by oxidative dehydrogenation
EP3497073A1 (en) 2016-08-09 2019-06-19 Basf Se Method of starting up a reactor for the oxidative dehydrogenation of n-butenes
WO2018095776A1 (en) 2016-11-22 2018-05-31 Basf Se Method for producing 1,3-butadiene from n-butenes by oxidative dehydrogenation, comprising aqueous scrubbing of the c4 product gas flow
WO2018095840A1 (en) 2016-11-22 2018-05-31 Basf Se Method for producing 1,3-butadiene from n-butenes by oxidative dehydrogenation, comprising furan removal in the processing
WO2018095856A1 (en) 2016-11-22 2018-05-31 Basf Se Method for preparing 1,3-butadiene from n-butenes through oxidative dehydrogenation comprising methacrolein removal during processing
EP3323797A1 (en) 2016-11-22 2018-05-23 Basf Se Method for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation comprising an acidic washing of a c4 product gas flow
WO2018219996A1 (en) 2017-06-02 2018-12-06 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation in recycle gas mode with co2-enriched recycle gas
WO2018234158A1 (en) 2017-06-19 2018-12-27 Basf Se Method for producing 1,3-butadiene from n-butenes by means of oxidative dehydrogenation, including a scrubbing of the c4 product gas flow

Also Published As

Publication number Publication date
AT348978B (en) 1979-03-12
CA1075669A (en) 1980-04-15
GB1497589A (en) 1978-01-12
DE2600128A1 (en) 1976-07-15
BR7600141A (en) 1976-08-31
JPS5195991A (en) 1976-08-23
FR2297082B1 (en) 1982-02-26
DD123739A5 (en) 1977-01-12
NL7600312A (en) 1976-07-15
IT1054781B (en) 1981-11-30
FR2297082A1 (en) 1976-08-06
IN145044B (en) 1978-08-19
SU718000A3 (en) 1980-02-25
ATA10676A (en) 1978-08-15

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