ES440270A1 - Disubstituted n- aminomethylene- thiol -thiono- phosphoric acid ester amides process for their production and their use as insecti cides and acaricides - Google Patents
Disubstituted n- aminomethylene- thiol -thiono- phosphoric acid ester amides process for their production and their use as insecti cides and acaricidesInfo
- Publication number
- ES440270A1 ES440270A1 ES440270A ES440270A ES440270A1 ES 440270 A1 ES440270 A1 ES 440270A1 ES 440270 A ES440270 A ES 440270A ES 440270 A ES440270 A ES 440270A ES 440270 A1 ES440270 A1 ES 440270A1
- Authority
- ES
- Spain
- Prior art keywords
- alkyl
- formula
- thiono
- aminomethylene
- acaricides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 2
- 230000000895 acaricidal effect Effects 0.000 title 1
- 239000000642 acaricide Substances 0.000 title 1
- 230000000749 insecticidal effect Effects 0.000 title 1
- 239000002917 insecticide Substances 0.000 title 1
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 150000001241 acetals Chemical class 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- -1 aminomethylidene Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 150000003949 imides Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
- 150000003582 thiophosphoric acids Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
- C07F9/6533—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/24—Esteramides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/24—Esteramides
- C07F9/2454—Esteramides the amide moiety containing a substituent or a structure which is considered as characteristic
- C07F9/2458—Esteramides the amide moiety containing a substituent or a structure which is considered as characteristic of aliphatic amines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/572—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/59—Hydrogenated pyridine rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Procedure for preparing imides of esters of N- (aminomethylidene) -thiolphosphoric and -thionophosphoric acids, of the formula: **(See formula)** where R is C 1-6 -alkyl, R'is C 1-6 -alkyl, alkenyl or C2-C6-alkynyl, C 1 -C 4 -alkylmereaptoalkyl in each alkyl group or N-alkyl-carbamoylmethyl, while R'' and E'''which may be the same or different, represent alkyl or alkenyl each with 2 to 6 carbon atoms or together with the nitrogen atom can form a heterocyclic ring that I can be interrupted by further oxygen, sulfur, or nitrogen atoms, and X is an oxygen or sulfur atom; characterized in that amides of esters of thiophosphoric acids, respectively thionophosphorya of formula: **(See formula)** they are reacted with acetals of formamide of the formula: **(See formula)** in which formulas (II) and (III), R, R', R'', R''' and X have the meanings indicated above and Alk represents a low molecular weight alkyl radical, at temperatures between 0 and 150ºC., preferably between 100 and 130ºC., optionally in the presence of a solvent. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2216552A DE2216552C3 (en) | 1972-04-06 | 1972-04-06 | Disubstituted N- [aminomethylidene] -thiol- (thiono) -phosphoric acid esterimides, process for their preparation and their use as insecticides and acaricides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES440270A1 true ES440270A1 (en) | 1977-03-16 |
Family
ID=5841151
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES413374A Expired ES413374A1 (en) | 1972-04-06 | 1973-04-05 | Disubstituted n- aminomethylene- thiol -thiono- phosphoric acid ester amides process for their production and their use as insecti cides and acaricides |
| ES440270A Expired ES440270A1 (en) | 1972-04-06 | 1975-08-14 | Disubstituted n- aminomethylene- thiol -thiono- phosphoric acid ester amides process for their production and their use as insecti cides and acaricides |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES413374A Expired ES413374A1 (en) | 1972-04-06 | 1973-04-05 | Disubstituted n- aminomethylene- thiol -thiono- phosphoric acid ester amides process for their production and their use as insecti cides and acaricides |
Country Status (21)
| Country | Link |
|---|---|
| JP (2) | JPS4913122A (en) |
| AT (1) | AT322908B (en) |
| BE (1) | BE797792A (en) |
| BR (1) | BR7302379D0 (en) |
| CH (1) | CH582994A5 (en) |
| CS (2) | CS183687B2 (en) |
| DD (1) | DD107934A5 (en) |
| DE (1) | DE2216552C3 (en) |
| DK (1) | DK134320C (en) |
| EG (1) | EG10754A (en) |
| ES (2) | ES413374A1 (en) |
| FR (1) | FR2179214B1 (en) |
| GB (1) | GB1377329A (en) |
| HU (1) | HU168160B (en) |
| IL (1) | IL41933A (en) |
| IT (1) | IT981879B (en) |
| NL (1) | NL7304849A (en) |
| PL (1) | PL86814B1 (en) |
| RO (2) | RO65819A (en) |
| TR (1) | TR17151A (en) |
| ZA (1) | ZA732384B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RO65820A (en) * | 1974-09-12 | 1980-06-15 | Bayer A.G.,De | PROCESS FOR PREPARING NEW PHOSPHORIC ESTERS |
| JPS5423479U (en) * | 1977-07-19 | 1979-02-15 | ||
| DE2737403A1 (en) * | 1977-08-19 | 1979-02-22 | Bayer Ag | N- (AMINOMETHYLENE) - (MONO- AND DITHIO) -PHOSPHORSAEUREDIESTERAMIDES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS INSECTICIDES, ACARICIDES AND NEMATICIDES |
| LU85892A1 (en) * | 1985-05-10 | 1986-12-05 | Wurth Paul Sa | METHOD FOR CONTROLLING THE LOADING OF A TANK OVEN |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3121084A (en) * | 1962-09-17 | 1964-02-11 | Du Pont | Selected n, n, n'-trisubstituted amidines and their preparation by reaction of compounds with-nh2 groups with amide acetals |
| DE2118469C3 (en) * | 1971-04-16 | 1980-02-14 | Bayer Ag, 5090 Leverkusen | N- (Dimenthylaminomethyliden) -thiol (thiono) phosphoric acid ester imides, process for their preparation and their use as insecticides and acaricides |
| BE792901A (en) * | 1971-12-17 | 1973-06-18 | Ciba Geigy | PHOSPHOROUS AMIDINES AND PESTICIDE PRODUCTS CONTAINING THEM |
-
1972
- 1972-04-06 DE DE2216552A patent/DE2216552C3/en not_active Expired
-
1973
- 1973-03-21 DD DD169627A patent/DD107934A5/xx unknown
- 1973-03-28 CS CS7300002271A patent/CS183687B2/en unknown
- 1973-03-28 CS CS7600006200A patent/CS183697B2/en unknown
- 1973-03-29 RO RO7383028A patent/RO65819A/en unknown
- 1973-03-29 RO RO7300074333A patent/RO62884A/en unknown
- 1973-04-03 JP JP48037482A patent/JPS4913122A/ja active Pending
- 1973-04-03 TR TR17151A patent/TR17151A/en unknown
- 1973-04-03 BR BR732379A patent/BR7302379D0/en unknown
- 1973-04-03 IL IL41933A patent/IL41933A/en unknown
- 1973-04-03 JP JP48037483A patent/JPS4913336A/ja active Pending
- 1973-04-04 CH CH484073A patent/CH582994A5/xx not_active IP Right Cessation
- 1973-04-04 IT IT22593/73A patent/IT981879B/en active
- 1973-04-04 EG EG126/73A patent/EG10754A/en active
- 1973-04-04 PL PL1973161700A patent/PL86814B1/pl unknown
- 1973-04-05 ES ES413374A patent/ES413374A1/en not_active Expired
- 1973-04-05 GB GB1635273A patent/GB1377329A/en not_active Expired
- 1973-04-05 AT AT299073A patent/AT322908B/en not_active IP Right Cessation
- 1973-04-05 ZA ZA732384A patent/ZA732384B/en unknown
- 1973-04-05 DK DK184873A patent/DK134320C/en active
- 1973-04-05 BE BE129657A patent/BE797792A/en unknown
- 1973-04-06 FR FR7312444A patent/FR2179214B1/fr not_active Expired
- 1973-04-06 HU HUBA2903A patent/HU168160B/hu unknown
- 1973-04-06 NL NL7304849A patent/NL7304849A/xx not_active Application Discontinuation
-
1975
- 1975-08-14 ES ES440270A patent/ES440270A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ZA732384B (en) | 1974-01-30 |
| RO62884A (en) | 1978-01-15 |
| NL7304849A (en) | 1973-10-09 |
| AT322908B (en) | 1975-06-10 |
| JPS4913122A (en) | 1974-02-05 |
| ES413374A1 (en) | 1976-06-16 |
| IL41933A0 (en) | 1973-06-29 |
| DD107934A5 (en) | 1974-08-20 |
| FR2179214A1 (en) | 1973-11-16 |
| DE2216552A1 (en) | 1973-10-11 |
| DE2216552C3 (en) | 1980-10-30 |
| PL86814B1 (en) | 1976-06-30 |
| CS183687B2 (en) | 1978-07-31 |
| CH582994A5 (en) | 1976-12-31 |
| CS183697B2 (en) | 1978-07-31 |
| JPS4913336A (en) | 1974-02-05 |
| GB1377329A (en) | 1974-12-11 |
| EG10754A (en) | 1976-11-30 |
| IL41933A (en) | 1977-10-31 |
| IT981879B (en) | 1974-10-10 |
| TR17151A (en) | 1974-04-25 |
| HU168160B (en) | 1976-03-28 |
| DK134320B (en) | 1976-10-18 |
| RO65819A (en) | 1981-07-30 |
| BE797792A (en) | 1973-10-05 |
| DE2216552B2 (en) | 1980-03-06 |
| BR7302379D0 (en) | 1974-02-07 |
| DK134320C (en) | 1977-04-12 |
| FR2179214B1 (en) | 1977-02-04 |
| AU5422973A (en) | 1974-10-10 |
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