ES402312A1 - A procedure for the production of 1-rent (alkenil) 6,7-oxocinolin-3-carbonitrilos and its intermediate products. (Machine-translation by Google Translate, not legally binding) - Google Patents

A procedure for the production of 1-rent (alkenil) 6,7-oxocinolin-3-carbonitrilos and its intermediate products. (Machine-translation by Google Translate, not legally binding)

Info

Publication number
ES402312A1
ES402312A1 ES402312A ES402312A ES402312A1 ES 402312 A1 ES402312 A1 ES 402312A1 ES 402312 A ES402312 A ES 402312A ES 402312 A ES402312 A ES 402312A ES 402312 A1 ES402312 A1 ES 402312A1
Authority
ES
Spain
Prior art keywords
methylenedioxyquinolin
oxocinolin
translation
production
machine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES402312A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eli Lilly and Co
Original Assignee
Eli Lilly and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eli Lilly and Co filed Critical Eli Lilly and Co
Publication of ES402312A1 publication Critical patent/ES402312A1/en
Expired legal-status Critical Current

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Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fodder In General (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

A process for the production of 1-alkyl (or alkenyl) 6,7-oxocinolin-3-carbonitriles and their intermediates of the following formula: ** (see formula) ** Where r is a member of the group consisting of methyl, ethyl, N-propyl, isopropyl, N-butyl, β -hiroxyethyl and allyl, which process consists of: (a) catalytically reducing 2'-nitro-4'-5'-methylenedioxy-acetophenone to 2'-amino-4', 5'-methylenedioxyacetophenone; (b) diazotizing the 2-amino-4'5'-methylenedioxyacetophenone with nitrous acid and cyclizing to form 6,7-methylenedioxyquinolin-4-ol; (c) treating with bromine 6,7-methylenedioxycinolin-4-ol to produce 3-bromo-6,7-methylenedioxyquinolin-4-ol; (d) treating cuprous cyanide with 3-bromo-6,7-methylenedioxyquinolin-4-ol to form 6,7-methylenedioxyquinolin-4-ol-3-carbonitrile; y (e) alkylating 6,7-methylenedioxyquinolin-4-ol-3-carbonitrile with alkyl, alkenyl or β-hydroxyethyl bromide, chloride, iodide or sulfate to form the carbonitrile which corresponds to the above formula. (Machine-translation by Google Translate, not legally binding)
ES402312A 1969-02-04 1972-05-02 A procedure for the production of 1-rent (alkenil) 6,7-oxocinolin-3-carbonitrilos and its intermediate products. (Machine-translation by Google Translate, not legally binding) Expired ES402312A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US79654669A 1969-02-04 1969-02-04
US88888069A 1969-12-29 1969-12-29

Publications (1)

Publication Number Publication Date
ES402312A1 true ES402312A1 (en) 1976-04-01

Family

ID=27121747

Family Applications (2)

Application Number Title Priority Date Filing Date
ES376173A Expired ES376173A1 (en) 1969-02-04 1970-02-03 A method for the preparation of 6,7-metilendioxi 4 (ih) -oxocinmolin-3-carboxilic acids. (Machine-translation by Google Translate, not legally binding)
ES402312A Expired ES402312A1 (en) 1969-02-04 1972-05-02 A procedure for the production of 1-rent (alkenil) 6,7-oxocinolin-3-carbonitrilos and its intermediate products. (Machine-translation by Google Translate, not legally binding)

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES376173A Expired ES376173A1 (en) 1969-02-04 1970-02-03 A method for the preparation of 6,7-metilendioxi 4 (ih) -oxocinmolin-3-carboxilic acids. (Machine-translation by Google Translate, not legally binding)

Country Status (2)

Country Link
JP (1) JPS4914240B1 (en)
ES (2) ES376173A1 (en)

Also Published As

Publication number Publication date
JPS4914240B1 (en) 1974-04-05
ES376173A1 (en) 1972-09-01

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