ES395336A1 - Substituted vinyl esters of phosphorus acids - Google Patents
Substituted vinyl esters of phosphorus acidsInfo
- Publication number
- ES395336A1 ES395336A1 ES395336A ES395336A ES395336A1 ES 395336 A1 ES395336 A1 ES 395336A1 ES 395336 A ES395336 A ES 395336A ES 395336 A ES395336 A ES 395336A ES 395336 A1 ES395336 A1 ES 395336A1
- Authority
- ES
- Spain
- Prior art keywords
- radical
- lower alkyl
- formula
- phenyl
- alkyl radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003017 phosphorus Chemical class 0.000 title 1
- 229920001567 vinyl ester resin Polymers 0.000 title 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- -1 formylpropionic acid ester Chemical class 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 125000004966 cyanoalkyl group Chemical group 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 159000000011 group IA salts Chemical class 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229910052717 sulfur Chemical group 0.000 abstract 1
- 239000011593 sulfur Chemical group 0.000 abstract 1
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/113—Esters of phosphoric acids with unsaturated acyclic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/173—Esters of thiophosphoric acids with unsaturated acyclic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4078—Esters with unsaturated acyclic alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Procedure for the preparation of new pesticidal esters of the general formula ** (See formula) ** in which R1 represents a lower alkyl radical; R2 represents a lower alkyl or alkoxy radical or the phenyl radical; R3 represents a phenyl or phenyl-lower alkyl radical, optionally substituted, an alkyl, haloalkyl, cyano alkyl, alkenyl or lower alkynyl radical or an alkyl radical interrupted by one or more oxygen or sulfur atoms; and X represents oxygen or sulfur, except that R2 denotes a lower alkyl radical or the phenyl radical when R3 signifies a lower alkyl group, characterized by reacting an alkaline salt of a formylpropionic acid ester of the formula ** (See formula) ** in which R3 has the same meaning as before and It represents an alkali metal to me, with an ester halide of the formula ** (See formula) ** in which R1, R2 and X have the same meaning as before, while Hal represents halogen (in particular chlorine or bromine), the reaction being conducted at temperatures between 0º and 150ºC and preferably between 10º and 80ºC, in the presence or absence of a solvent, preferably chosen among inert organic solvents. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1413770A CH567363A5 (en) | 1970-09-24 | 1970-09-24 | Dimethyl-substd-vinyl phosphate - insecticide, acaricide |
| CH1152871A CH593614A5 (en) | 1971-08-05 | 1971-08-05 | Organo (thio) phosphorus cpds - insecticides, acaricides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES395336A1 true ES395336A1 (en) | 1973-12-01 |
Family
ID=25708494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES395336A Expired ES395336A1 (en) | 1970-09-24 | 1971-09-23 | Substituted vinyl esters of phosphorus acids |
Country Status (14)
| Country | Link |
|---|---|
| AT (1) | AT307153B (en) |
| AU (1) | AU458481B2 (en) |
| BE (1) | BE772966A (en) |
| BG (1) | BG19367A3 (en) |
| BR (1) | BR7106331D0 (en) |
| CA (1) | CA933939A (en) |
| DD (1) | DD102280A5 (en) |
| DE (1) | DE2147588C3 (en) |
| ES (1) | ES395336A1 (en) |
| FR (1) | FR2106313A5 (en) |
| GB (1) | GB1359331A (en) |
| HU (1) | HU163509B (en) |
| IL (1) | IL37739A (en) |
| NL (1) | NL7113109A (en) |
-
1971
- 1971-09-16 IL IL37739A patent/IL37739A/en unknown
- 1971-09-18 BG BG018583A patent/BG19367A3/en unknown
- 1971-09-20 AU AU33686/71A patent/AU458481B2/en not_active Expired
- 1971-09-20 CA CA123191A patent/CA933939A/en not_active Expired
- 1971-09-23 NL NL7113109A patent/NL7113109A/xx unknown
- 1971-09-23 BE BE772966A patent/BE772966A/en unknown
- 1971-09-23 AT AT825171A patent/AT307153B/en not_active IP Right Cessation
- 1971-09-23 FR FR7134246A patent/FR2106313A5/fr not_active Expired
- 1971-09-23 DD DD162573A patent/DD102280A5/xx unknown
- 1971-09-23 ES ES395336A patent/ES395336A1/en not_active Expired
- 1971-09-23 DE DE2147588A patent/DE2147588C3/en not_active Expired
- 1971-09-23 HU HUCI1160A patent/HU163509B/hu unknown
- 1971-09-23 GB GB4452571A patent/GB1359331A/en not_active Expired
- 1971-09-24 BR BR6331/71A patent/BR7106331D0/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IL37739A0 (en) | 1971-11-29 |
| AU458481B2 (en) | 1975-02-27 |
| DE2147588B2 (en) | 1973-12-06 |
| BE772966A (en) | 1972-03-23 |
| GB1359331A (en) | 1974-07-10 |
| NL7113109A (en) | 1972-03-28 |
| HU163509B (en) | 1973-09-27 |
| CA933939A (en) | 1973-09-18 |
| IL37739A (en) | 1975-04-25 |
| BG19367A3 (en) | 1975-06-15 |
| DE2147588C3 (en) | 1974-07-11 |
| DD102280A5 (en) | 1973-12-12 |
| AT307153B (en) | 1973-05-10 |
| AU3368671A (en) | 1973-03-29 |
| FR2106313A5 (en) | 1972-04-28 |
| BR7106331D0 (en) | 1973-04-10 |
| DE2147588A1 (en) | 1972-03-30 |
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