ES388946A1 - Oestratrienes - Google Patents
OestratrienesInfo
- Publication number
- ES388946A1 ES388946A1 ES388946A ES388946A ES388946A1 ES 388946 A1 ES388946 A1 ES 388946A1 ES 388946 A ES388946 A ES 388946A ES 388946 A ES388946 A ES 388946A ES 388946 A1 ES388946 A1 ES 388946A1
- Authority
- ES
- Spain
- Prior art keywords
- group
- carbon atoms
- hydrogen atom
- less
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- HLCRYAZDZCJZFG-BDXSIMOUSA-N (8s,9s,13s,14s)-13-methyl-6,7,8,9,11,12,14,15,16,17-decahydrocyclopenta[a]phenanthrene Chemical compound C1CC2=CC=CC=C2[C@@H]2[C@@H]1[C@@H]1CCC[C@@]1(C)CC2 HLCRYAZDZCJZFG-BDXSIMOUSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- -1 alkali metal salt Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 230000000911 decarboxylating effect Effects 0.000 abstract 1
- 125000002541 furyl group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 125000004043 oxo group Chemical group O=* 0.000 abstract 1
- 125000001544 thienyl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07J—STEROIDS
- C07J71/00—Steroids in which the cyclopenta(a)hydrophenanthrene skeleton is condensed with a heterocyclic ring
- C07J71/0005—Oxygen-containing hetero ring
- C07J71/0026—Oxygen-containing hetero ring cyclic ketals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Steroid Compounds (AREA)
Abstract
Procedure for the preparation of estratriene of general formula: ** (See formula) ** wherein the dotted lines at positions 6-7 and 9-11 indicate the optional presence of another link; K represents a hydrogen atom, an aliphatic hydrocarbon group with less than 10 carbon atoms, a cycloalkyl group with less than 7 carbon atoms, an aryl group with less than 11 carbon atoms and which may be substituted by a nitro group or by methoxy groups, an adamantyl group, a furyl group or a thienyl group; R1 represents a hydrogen atom or an OR2 group, in which R2 represents a hydrogen atom, an aliphatic hydrocarbon group with less than 4 carbon atoms, a beta-dimethyluminoethyl group, an acyl residue derived from acetic acid or sulfuric acid or an alkali metal salt thereof, or a 1H-tetrazoyl group; and R3 represents a hydrogen atom, a hydroxyl group, an acetoxy group, or an oxo group, characterized in that it comprises decarboxylating an estratriene-17 β -carboxylic acid of general formula: ** (See formula) ** wherein R and R2 are defined as above and optionally convert, a estratriene of general formula: ** (See formula) ** thus obtained in another compound of general formula I. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1099570 | 1970-03-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES388946A1 true ES388946A1 (en) | 1973-05-01 |
Family
ID=9978105
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES388946A Expired ES388946A1 (en) | 1970-03-06 | 1971-03-05 | Oestratrienes |
Country Status (15)
Country | Link |
---|---|
AT (3) | AT323340B (en) |
BE (1) | BE763894A (en) |
CA (1) | CA934366A (en) |
CH (2) | CH583256A5 (en) |
DE (1) | DE2110577A1 (en) |
DK (1) | DK127419B (en) |
ES (1) | ES388946A1 (en) |
FR (1) | FR2085680B1 (en) |
GB (1) | GB1314191A (en) |
HU (1) | HU162819B (en) |
IE (1) | IE35107B1 (en) |
IL (1) | IL36355A0 (en) |
NL (1) | NL7103015A (en) |
SE (1) | SE369189B (en) |
ZA (1) | ZA711434B (en) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL6703781A (en) * | 1967-03-13 | 1968-09-16 | ||
GB1278705A (en) * | 1968-09-11 | 1972-06-21 | Koninklijke Gist Spiritus | Oestratrienes |
-
1970
- 1970-03-06 GB GB1099570A patent/GB1314191A/en not_active Expired
-
1971
- 1971-03-05 AT AT190471A patent/AT323340B/en not_active IP Right Cessation
- 1971-03-05 IL IL36355A patent/IL36355A0/en unknown
- 1971-03-05 IE IE273/71A patent/IE35107B1/en unknown
- 1971-03-05 SE SE02842/71A patent/SE369189B/xx unknown
- 1971-03-05 BE BE763894A patent/BE763894A/en unknown
- 1971-03-05 CH CH3265716A patent/CH583256A5/xx not_active IP Right Cessation
- 1971-03-05 CA CA107001A patent/CA934366A/en not_active Expired
- 1971-03-05 ES ES388946A patent/ES388946A1/en not_active Expired
- 1971-03-05 CH CH326571A patent/CH582199A5/xx not_active IP Right Cessation
- 1971-03-05 DK DK105271AA patent/DK127419B/en unknown
- 1971-03-05 AT AT552172A patent/AT316770B/en not_active IP Right Cessation
- 1971-03-05 AT AT551972A patent/AT323906B/en not_active IP Right Cessation
- 1971-03-05 FR FR7107789A patent/FR2085680B1/fr not_active Expired
- 1971-03-05 HU HUKO2409A patent/HU162819B/hu unknown
- 1971-03-05 NL NL7103015A patent/NL7103015A/xx unknown
- 1971-03-05 DE DE19712110577 patent/DE2110577A1/en active Pending
- 1971-03-05 ZA ZA711434A patent/ZA711434B/en unknown
Also Published As
Publication number | Publication date |
---|---|
HU162819B (en) | 1973-04-28 |
GB1314191A (en) | 1973-04-18 |
BE763894A (en) | 1971-09-06 |
FR2085680A1 (en) | 1971-12-31 |
NL7103015A (en) | 1971-09-08 |
CH582199A5 (en) | 1976-11-30 |
DK127419B (en) | 1973-11-05 |
IL36355A0 (en) | 1971-05-26 |
AT316770B (en) | 1974-07-25 |
IE35107L (en) | 1971-09-06 |
AT323340B (en) | 1975-07-10 |
CH583256A5 (en) | 1976-12-31 |
SE369189B (en) | 1974-08-12 |
IE35107B1 (en) | 1975-11-12 |
AT323906B (en) | 1975-08-11 |
FR2085680B1 (en) | 1975-08-01 |
ZA711434B (en) | 1971-11-24 |
DE2110577A1 (en) | 1971-09-16 |
CA934366A (en) | 1973-09-25 |
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