ES384655A1 - Unsaturated quaternary ammonium compounds and copolymers containing them - Google Patents
Unsaturated quaternary ammonium compounds and copolymers containing themInfo
- Publication number
- ES384655A1 ES384655A1 ES384655A ES384655A ES384655A1 ES 384655 A1 ES384655 A1 ES 384655A1 ES 384655 A ES384655 A ES 384655A ES 384655 A ES384655 A ES 384655A ES 384655 A1 ES384655 A1 ES 384655A1
- Authority
- ES
- Spain
- Prior art keywords
- carbon atoms
- group
- alcohol
- acetoxy
- alcoholic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/28—Emulsion polymerisation with the aid of emulsifying agents cationic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
A polymerization process characterized in that it comprises copolymerizing with ethylenically unsaturated monomer a monomer emulsion stabilizer of the formula **(See formula)** wherein V is an ethylenically unsaturated radical selected from the following classes: a) ester-acid groups or amido-acid groups represented by the formulas HO-CO-CH = CH-COO-, HO-CO-CH = CH-CONH-, HO-CO-CH = C (CH3) -COO-, HO-CO-CH = C (CH3) -CONH-, (see formula); b) acrylic ester or acrylic amide groups represented by the formulas CH2 = CR4-COO- and CH2 = CR4-CONH, with R4 H or CH3; c) allyl, methallyl, vinyloxy, allyloxy, methyloxy, vinyl acetoxy, allyl acetoxy, or metalyl-acetoxy; A is absent when V is an allyl, metalyl, vinyl acetoxy, allyl acetoxy, or metalyl acetoxy group and is otherwise a group selected from the classes consisting of ethylene, propylene, hydroxypropylene, acetoxy, propylene, ixopropylene groups, and -O -CH2-CHR4- (O-CH2-CHR4) n-, where R4 is H or CH3 and where n is 0, 1, 2, 3 or 4; the quaternary nitrogen group N + .R1.R2.R3 is selected from the classes consisting of: a) aliphatic tertiary amines in which R1 is an alcoholic or benzyl group containing 1 to 7 carbon atoms, and R2 is a group alcohol or benzyl containing 1 to 7 carbon atoms or a group selected from the class consisting of R5-O-CO-CH2- and R5-NH-CO-CH2, -, where R5 H or an alcohol group containing from 1 to 4 carbon atoms; b) groups in which n, R1 and R2 together form part of a heterocyclic tertiary amine having the formula **(See formula)** and R3 is a lipophilic radical containing an aliphatic hydrocarbon chain of 7 to 28 carbon atoms; and X- is a radical selected from (a) the class consisting of F-, Cl-, Br-, I-, CH3SO4, C2HSO4-, CH3- or SO3-, or (b) an alcoholic sulfate in which the group alcohol contains 7 to 28 carbon atoms, an alcohol benzene sulphonate in which the alcohol group contains 7 to 12 carbon atoms, a phenoxy (or alcohol phenoxy) alcohol (or polyalcohilenoxi-alcoholilen) sulfate that has the formula R'' - C6H4O- (CH2-CHR'''- O) n-CH2-CHR''' SO4 where R'' is hydrogen or an alcohol group containing 1 to 12 carbon atoms, where R'''is hydrogen or a methyl group, and where n is zero or an integer; a dialkoxy sulphosuccinate in which the alcoholic groups contain 1 to 24 carbon atoms or an alcoholic phosphate in which the alcoholic group contains 1 to 18 carbon atoms, with the proviso that when X- falls within class (b), R3 It is a lipophilic radical that contains a hydrocarbon chain of 8 to 28 carbon atoms. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US86789969A | 1969-10-20 | 1969-10-20 | |
US86790069A | 1969-10-20 | 1969-10-20 | |
US4070570A | 1970-05-26 | 1970-05-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES384655A1 true ES384655A1 (en) | 1973-03-16 |
Family
ID=27365773
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES384655A Expired ES384655A1 (en) | 1969-10-20 | 1970-10-17 | Unsaturated quaternary ammonium compounds and copolymers containing them |
Country Status (9)
Country | Link |
---|---|
BE (1) | BE757751A (en) |
CH (1) | CH562262A5 (en) |
DE (1) | DE2051479C2 (en) |
DK (1) | DK154423C (en) |
ES (1) | ES384655A1 (en) |
FR (1) | FR2064443B1 (en) |
GB (1) | GB1298099A (en) |
NL (1) | NL166700C (en) |
NO (1) | NO139958C (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2116966B (en) * | 1982-02-26 | 1986-01-15 | British Petroleum Co Plc | N-oxyalkylated aqueous compositions of quaternary ammenium salt surfactants |
JPS61157505A (en) * | 1984-12-28 | 1986-07-17 | Kao Corp | Dispersion stabilizer for oily suspension polymerization |
JP2001509195A (en) | 1997-01-28 | 2001-07-10 | ステパン カンパニー | Improved emulsion polymerization process using ethylenically unsaturated amine salts of sulfonic, phosphoric and carboxylic acids |
US6242526B1 (en) * | 1997-01-28 | 2001-06-05 | Stepan Company | Antimicrobial polymer latexes derived from unsaturated quaternary ammonium compounds and antimicrobial coatings, sealants, adhesives and elastomers produced from such latexes |
US20020161108A1 (en) | 2000-03-09 | 2002-10-31 | Stepan Company, A Corporation Of The State Of Delaware | Emulsion polymerization process utilizing ethylenically unsaturated amine salts of sulfonic, phosphoric and carboxylic acids |
US7423167B2 (en) | 1997-01-28 | 2008-09-09 | Stepan Company | Ethylenically unsaturated amine salts of sulfonic, phosphoric and carboxylic acids |
IT1396300B1 (en) * | 2009-10-07 | 2012-11-16 | Bridgestone Corp | GUIDED AGENTS OF VULCANIZATION. |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1317895A (en) * | 1961-03-21 | 1963-05-08 | ||
GB1112912A (en) * | 1964-09-02 | 1968-05-08 | Rohm & Haas | Monomers with hydroxyl and quaternary ammonium functionality and polymers thereof |
GB1140520A (en) * | 1966-07-19 | 1969-01-22 | Shell Int Research | Novel cationic ester compounds, novel polymers and copolymers thereof, their preparation and use |
CA939668A (en) * | 1968-10-21 | 1974-01-08 | Kendall Company (The) | Quaternized monomeric emulsion stabilizers |
-
1970
- 1970-10-02 GB GB4699770A patent/GB1298099A/en not_active Expired
- 1970-10-17 ES ES384655A patent/ES384655A1/en not_active Expired
- 1970-10-19 NO NO394470A patent/NO139958C/en unknown
- 1970-10-20 NL NL7015362A patent/NL166700C/en not_active IP Right Cessation
- 1970-10-20 BE BE757751D patent/BE757751A/en not_active IP Right Cessation
- 1970-10-20 FR FR7037832A patent/FR2064443B1/fr not_active Expired
- 1970-10-20 CH CH1546870A patent/CH562262A5/xx not_active IP Right Cessation
- 1970-10-20 DE DE19702051479 patent/DE2051479C2/en not_active Expired
- 1970-10-20 DK DK532570A patent/DK154423C/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
FR2064443A1 (en) | 1971-07-23 |
GB1298099A (en) | 1972-11-29 |
CH562262A5 (en) | 1975-05-30 |
DK154423B (en) | 1988-11-14 |
BE757751A (en) | 1971-04-01 |
DE2051479A1 (en) | 1971-05-06 |
NO139958C (en) | 1979-06-13 |
NL7015362A (en) | 1971-04-22 |
NL166700C (en) | 1981-09-15 |
DE2051479C2 (en) | 1982-02-11 |
DK154423C (en) | 1989-04-17 |
NO139958B (en) | 1979-03-05 |
NL166700B (en) | 1981-04-15 |
FR2064443B1 (en) | 1974-07-12 |
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