ES381226A1 - Beneficiation of fluorspar ores - Google Patents
Beneficiation of fluorspar oresInfo
- Publication number
- ES381226A1 ES381226A1 ES381226A ES381226A ES381226A1 ES 381226 A1 ES381226 A1 ES 381226A1 ES 381226 A ES381226 A ES 381226A ES 381226 A ES381226 A ES 381226A ES 381226 A1 ES381226 A1 ES 381226A1
- Authority
- ES
- Spain
- Prior art keywords
- fluorspar
- soaps
- pulp
- feso
- fatty acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010436 fluorite Substances 0.000 title abstract 6
- 239000000344 soap Substances 0.000 abstract 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 3
- 239000011707 mineral Substances 0.000 abstract 3
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- 239000012141 concentrate Substances 0.000 abstract 2
- 230000000994 depressogenic effect Effects 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 abstract 2
- 244000007835 Cyamopsis tetragonoloba Species 0.000 abstract 1
- 235000017343 Quebracho blanco Nutrition 0.000 abstract 1
- 241000065615 Schinopsis balansae Species 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 238000009291 froth flotation Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 150000004671 saturated fatty acids Chemical class 0.000 abstract 1
- 235000003441 saturated fatty acids Nutrition 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 abstract 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/002—Inorganic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/018—Mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/06—Depressants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Abstract
A fluorspar concentrate having a fluorspar content of at least 97% by weight is produced by:-(1) preparing an aqueous pulp containing:-(a) crude fluorspar ore containing less than 0.1 part by wt iron, expressed as FeSO 4 , per 1000 parts ore and appreciable quantities of gangue minerals but being substantially free of metallic sulphides (b) a water-soluble ferrous salt in an amount such that the pulp contains 0.1 to 0.4 part by wt of dissolved iron, expressed as FeSO 4 , per 1000 parts ore (c) a collector for fluorspar comprising one or more saturated fatty acids or soaps thereof either alone or mixed with one or more unsaturated fatty acids or soaps thereof, in an amount up to 70% by wt of the mixture (d) at least one depressant for gangue minerals comprising an alkali metal silicate or metasilicate, or quebracho (2) heating the pulp at its boiling point while maintaining the pH at 7-10 (3) subjecting the pulp to froth flotation (4) recovering a fluorspar concentrate from the froth. The pulp may also contain guar as a depressant for clay slimes, barium sulphate and gangue minerals. The ferrous salt may be FeSO 4 . The soaps may be aluminium or alkali metal or alkaline earth metal soaps such as Na, K, Ca and Mg soaps. The fatty acids may be those containing 4-22 carbon atoms. NaOH may be used to control the pH.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US84807969A | 1969-08-06 | 1969-08-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES381226A1 true ES381226A1 (en) | 1972-12-01 |
Family
ID=25302286
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES381226A Expired ES381226A1 (en) | 1969-08-06 | 1970-06-27 | Beneficiation of fluorspar ores |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3536193A (en) |
| ES (1) | ES381226A1 (en) |
| GB (1) | GB1265790A (en) |
| ZA (1) | ZA704374B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4288315A (en) * | 1979-03-26 | 1981-09-08 | Allied Corporation | Benefication of fluorspar ores |
| CN107597447A (en) * | 2017-10-11 | 2018-01-19 | 江西理工大学 | A kind of preparation method and applications of fluorite flotation collecting agent |
| CN112604817A (en) * | 2020-11-27 | 2021-04-06 | 湖南柿竹园有色金属有限责任公司 | Recycling and ore dressing process for tailings containing high-silicon gangue and high-calcium associated fluorite |
| CN113731639B (en) * | 2021-08-25 | 2023-06-09 | 湖南有色黄沙坪矿业有限公司 | Flotation method for low-grade associated fluorite ore containing tungsten and molybdenum |
-
1969
- 1969-08-06 US US848079A patent/US3536193A/en not_active Expired - Lifetime
-
1970
- 1970-06-22 GB GB1265790D patent/GB1265790A/en not_active Expired
- 1970-06-25 ZA ZA704374A patent/ZA704374B/en unknown
- 1970-06-27 ES ES381226A patent/ES381226A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1265790A (en) | 1972-03-08 |
| ZA704374B (en) | 1971-03-31 |
| US3536193A (en) | 1970-10-27 |
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