ES376963A1 - The polymerization of ethylenically unsaturated monomers - Google Patents
The polymerization of ethylenically unsaturated monomersInfo
- Publication number
- ES376963A1 ES376963A1 ES376963A ES376963A ES376963A1 ES 376963 A1 ES376963 A1 ES 376963A1 ES 376963 A ES376963 A ES 376963A ES 376963 A ES376963 A ES 376963A ES 376963 A1 ES376963 A1 ES 376963A1
- Authority
- ES
- Spain
- Prior art keywords
- polymerization
- ethylenically unsaturated
- straight
- carbon atoms
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A process for the bulk or solution polymerization of an ethylenically unsaturated monomer (as defined herein), characterized by being carried out in the presence of a catalyst system consisting of an organic hydroperoxide activated by a sulfur compound of the general formula: **(See formula)** wherein R represents a straight or branched, substituted or simple alkyl group, or with 1 to 12 carbon atoms, or a cycloalkyl group; X represents the chemical equivalent of a metal of the first or second group of the Periodic System or aluminum or represents one of the groupings signified by R, in which case the polymerization is carried out in the additional presence of an alkali metal alcoholate in which the alkyl group has a straight or branched chain and contains from 1 to 6 carbon atoms, or of an alkali metal hydroxide, in solution of an alcohol (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT1347869 | 1969-02-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES376963A1 true ES376963A1 (en) | 1972-09-16 |
Family
ID=11144470
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES376963A Expired ES376963A1 (en) | 1969-02-28 | 1970-02-28 | The polymerization of ethylenically unsaturated monomers |
Country Status (7)
Country | Link |
---|---|
BE (1) | BE746675A (en) |
CA (1) | CA919835A (en) |
DE (1) | DE2009215A1 (en) |
ES (1) | ES376963A1 (en) |
FR (1) | FR2046133A5 (en) |
GB (1) | GB1299761A (en) |
NL (1) | NL160837C (en) |
-
1970
- 1970-02-23 NL NL7002492A patent/NL160837C/en not_active IP Right Cessation
- 1970-02-24 FR FR7006506A patent/FR2046133A5/fr not_active Expired
- 1970-02-25 CA CA075903A patent/CA919835A/en not_active Expired
- 1970-02-26 GB GB943570A patent/GB1299761A/en not_active Expired
- 1970-02-27 DE DE19702009215 patent/DE2009215A1/en not_active Withdrawn
- 1970-02-27 BE BE746675D patent/BE746675A/en unknown
- 1970-02-28 ES ES376963A patent/ES376963A1/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
NL160837C (en) | 1979-12-17 |
GB1299761A (en) | 1972-12-13 |
NL7002492A (en) | 1970-09-01 |
FR2046133A5 (en) | 1971-03-05 |
DE2009215A1 (en) | 1970-09-17 |
NL160837B (en) | 1979-07-16 |
BE746675A (en) | 1970-08-27 |
CA919835A (en) | 1973-01-23 |
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