ES370135A1 - Procedure for obtaining a perfectly stable and uniform white polymer of molecular weight. (Machine-translation by Google Translate, not legally binding) - Google Patents

Procedure for obtaining a perfectly stable and uniform white polymer of molecular weight. (Machine-translation by Google Translate, not legally binding)

Info

Publication number
ES370135A1
ES370135A1 ES370135A ES370135A ES370135A1 ES 370135 A1 ES370135 A1 ES 370135A1 ES 370135 A ES370135 A ES 370135A ES 370135 A ES370135 A ES 370135A ES 370135 A1 ES370135 A1 ES 370135A1
Authority
ES
Spain
Prior art keywords
acrylonitrile
translation
procedure
obtaining
molecular weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES370135A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
C T A IND DE TEXTILE Cie
Original Assignee
C T A IND DE TEXTILE Cie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by C T A IND DE TEXTILE Cie filed Critical C T A IND DE TEXTILE Cie
Publication of ES370135A1 publication Critical patent/ES370135A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/42—Nitriles
    • C08F20/44—Acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Polymers and copolymers containing at least a predominant amount of acrylonitrile units are prepared by a process which comprises polymerizing acrylonitrile optionally with at least one other ethylenic compound, in an aqueous medium, at a pH of 1À8-2À7, at a temperature of 30-70 C., in the presence of an alkali or alkaline earth metal chlorate, SO 2 or a compound capable of yielding SO 2 in the polymerization mixture, and an alkali or alkaline earth metal hypophosphite. In the examples a homopolymer of acrylonitrile, an acrylonitrile/ methylmethacrylate copolymer and terpolymers of acrylonitrile, methylmethacrylate and either potassium vinyloxybenzenesulphonate or sodium-methallylsulphonate are prepared utilizing potassium chlorate, S0 2 or sodium bisulphite, and sodium hypophosphite.
ES370135A 1968-08-01 1969-08-01 Procedure for obtaining a perfectly stable and uniform white polymer of molecular weight. (Machine-translation by Google Translate, not legally binding) Expired ES370135A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR161553 1968-08-01

Publications (1)

Publication Number Publication Date
ES370135A1 true ES370135A1 (en) 1971-06-16

Family

ID=8653336

Family Applications (1)

Application Number Title Priority Date Filing Date
ES370135A Expired ES370135A1 (en) 1968-08-01 1969-08-01 Procedure for obtaining a perfectly stable and uniform white polymer of molecular weight. (Machine-translation by Google Translate, not legally binding)

Country Status (7)

Country Link
BE (1) BE735945A (en)
BR (1) BR6911093D0 (en)
DE (1) DE1939040A1 (en)
ES (1) ES370135A1 (en)
FR (1) FR1596539A (en)
GB (1) GB1231745A (en)
NL (1) NL6911710A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6268450B1 (en) * 1998-05-11 2001-07-31 Solutia Inc. Acrylic fiber polymer precursor and fiber

Also Published As

Publication number Publication date
GB1231745A (en) 1971-05-12
BR6911093D0 (en) 1973-01-11
BE735945A (en) 1969-12-16
FR1596539A (en) 1970-06-22
NL6911710A (en) 1970-02-03
DE1939040A1 (en) 1970-02-05

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