ES355565A1 - Improvements in or relating to the production of microporous articles of high polymers - Google Patents

Improvements in or relating to the production of microporous articles of high polymers

Info

Publication number
ES355565A1
ES355565A1 ES355565A ES355565A ES355565A1 ES 355565 A1 ES355565 A1 ES 355565A1 ES 355565 A ES355565 A ES 355565A ES 355565 A ES355565 A ES 355565A ES 355565 A1 ES355565 A1 ES 355565A1
Authority
ES
Spain
Prior art keywords
water
polymer
film
dms
dmf
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES355565A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Crylor SA
Original Assignee
Crylor SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Crylor SA filed Critical Crylor SA
Publication of ES355565A1 publication Critical patent/ES355565A1/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/40Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters
    • B01D71/42Polymers of nitriles, e.g. polyacrylonitrile
    • B01D71/421Polyacrylonitrile
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0095Drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/40Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters
    • B01D71/42Polymers of nitriles, e.g. polyacrylonitrile
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/54Polyureas; Polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/20Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 for porous or cellular articles, e.g. of foam plastics, coarse-pored
    • B29C67/202Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 for porous or cellular articles, e.g. of foam plastics, coarse-pored comprising elimination of a solid or a liquid ingredient
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • D06N3/0052Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by leaching out of a compound, e.g. water soluble salts, fibres or fillers; obtained by freezing or sublimation; obtained by eliminating drops of sublimable fluid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/04Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C08J2201/048Elimination of a frozen liquid phase
    • C08J2201/0484Elimination of a frozen liquid phase the liquid phase being aqueous
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/04Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C08J2201/05Elimination by evaporation or heat degradation of a liquid phase
    • C08J2201/0502Elimination by evaporation or heat degradation of a liquid phase the liquid phase being organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/04Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C08J2201/054Precipitating the polymer by adding a non-solvent or a different solvent
    • C08J2201/0542Precipitating the polymer by adding a non-solvent or a different solvent from an organic solvent-based polymer composition
    • C08J2201/0543Precipitating the polymer by adding a non-solvent or a different solvent from an organic solvent-based polymer composition the non-solvent being organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/04Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C08J2201/054Precipitating the polymer by adding a non-solvent or a different solvent
    • C08J2201/0545Precipitating the polymer by adding a non-solvent or a different solvent from an aqueous solvent-based polymer composition
    • C08J2201/0546Precipitating the polymer by adding a non-solvent or a different solvent from an aqueous solvent-based polymer composition the non-solvent being organic

Abstract

A microporous film, membrane or similar sheet is prepared by shaping, e.g. by casting or extruding, a thin film from a solution of a high polymer, e.g. acrylonitrile polymer, a segmented polyurethane or a polyvinyl alcohol polymer or a mixture of two or more polymers, which is insoluble in cold water, then coagulating and washing the film, freezing, without intermediate drying, the water impregnated film by rapid cooling to a temperature equal to or below -10 C., and drying the resulting material by slow and progressive heating in a vacuum. Suitable polymer solvents are dimethylformamide (DMF), dimethylsulphoxide (DMS) and water and suitable coagulating baths are a mixture of water-DMF, water-DMS, water, or an aqueous saturated salt solution, e.g. sodium sulphate depending upon the polymer.
ES355565A 1967-06-30 1968-06-28 Improvements in or relating to the production of microporous articles of high polymers Expired ES355565A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR112715 1967-06-30

Publications (1)

Publication Number Publication Date
ES355565A1 true ES355565A1 (en) 1969-12-16

Family

ID=8634260

Family Applications (1)

Application Number Title Priority Date Filing Date
ES355565A Expired ES355565A1 (en) 1967-06-30 1968-06-28 Improvements in or relating to the production of microporous articles of high polymers

Country Status (9)

Country Link
BE (1) BE717380A (en)
BR (1) BR6800115D0 (en)
CH (1) CH486525A (en)
DE (1) DE1779010C3 (en)
ES (1) ES355565A1 (en)
FR (1) FR1551885A (en)
GB (1) GB1212726A (en)
IL (1) IL30273A (en)
NL (1) NL142716B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD100484A1 (en) * 1971-12-24 1973-09-20
JPS5856378B2 (en) * 1976-09-08 1983-12-14 旭化成株式会社 Acrylonitrile polymer dry membrane and its manufacturing method
DE2918027C2 (en) * 1979-05-04 1986-05-28 Akzo Gmbh, 5600 Wuppertal Ultrafiltration membranes made from linear polyurethanes
CN101422669B (en) * 2008-11-26 2012-02-08 南昌大学 Preparation method of hydrophilicity macromolecule micropore filter material
CN113768081B (en) * 2021-09-14 2023-08-25 金腰燕(广州)食品有限公司 Method for removing nitrite in bird's nest

Also Published As

Publication number Publication date
NL142716B (en) 1974-07-15
CH486525A (en) 1970-02-28
IL30273A (en) 1972-10-29
DE1779010C3 (en) 1978-10-26
FR1551885A (en) 1969-01-03
BE717380A (en) 1968-12-30
IL30273A0 (en) 1968-08-22
DE1779010B2 (en) 1978-02-23
NL6808786A (en) 1968-12-31
DE1779010A1 (en) 1971-11-18
BR6800115D0 (en) 1973-01-04
GB1212726A (en) 1970-11-18

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