ES334801A1 - Noved des-a-gonanes, and processes for their preparation - Google Patents

Noved des-a-gonanes, and processes for their preparation

Info

Publication number
ES334801A1
ES334801A1 ES334801A ES334801A ES334801A1 ES 334801 A1 ES334801 A1 ES 334801A1 ES 334801 A ES334801 A ES 334801A ES 334801 A ES334801 A ES 334801A ES 334801 A1 ES334801 A1 ES 334801A1
Authority
ES
Spain
Prior art keywords
des
gona
hydroxymethylene
gon
dien
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES334801A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Publication of ES334801A1 publication Critical patent/ES334801A1/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07JSTEROIDS
    • C07J73/00Steroids in which the cyclopenta[a]hydrophenanthrene skeleton has been modified by substitution of one or two carbon atoms by hetero atoms
    • C07J73/001Steroids in which the cyclopenta[a]hydrophenanthrene skeleton has been modified by substitution of one or two carbon atoms by hetero atoms by one hetero atom
    • C07J73/003Steroids in which the cyclopenta[a]hydrophenanthrene skeleton has been modified by substitution of one or two carbon atoms by hetero atoms by one hetero atom by oxygen as hetero atom

Abstract

Novel compounds having the formul[mu] where R represents an alkyl radical, and X represents a hydrogen atom, a saturated or unsaturated aliphatic hydrocarbon radical optionally containing an oxygen atom in the hydrocarbon chain, or an acyl group derived from an organic carboxylic acid are obtained by reacting a des-A-gon-9-en-5-one with a formylating agent to give a 10-hydroxymethylene - des - A - gon - 9(11) - en - 5 - one, reacting the latter with a dehydrogenating agent to form a 10-formyl-des-A-gona-9,11- dien-5-one, and selectively reducing the latter to form a 10-hydroxymethyl-des-A-gona-9,11- dien-5-one. Alternatively the 10-hydroxymethylene starting compound is obtained by condensing a 5-enamino-des-A-gona-5(10), 9(11)- diene with formylacetic mixed anhydride to give the corresponding iminium compound which is subjected to acid hydrolysis.
ES334801A 1965-12-23 1966-12-22 Noved des-a-gonanes, and processes for their preparation Expired ES334801A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR43565A FR1476631A (en) 1965-12-23 1965-12-23 New substituted tricyclic compounds and method of preparation

Publications (1)

Publication Number Publication Date
ES334801A1 true ES334801A1 (en) 1968-03-01

Family

ID=8596668

Family Applications (1)

Application Number Title Priority Date Filing Date
ES334801A Expired ES334801A1 (en) 1965-12-23 1966-12-22 Noved des-a-gonanes, and processes for their preparation

Country Status (12)

Country Link
JP (1) JPS4935618B1 (en)
AT (1) AT267775B (en)
BE (1) BE691403A (en)
CH (1) CH467738A (en)
DE (1) DE1593349A1 (en)
DK (1) DK135710B (en)
ES (1) ES334801A1 (en)
FR (1) FR1476631A (en)
GB (1) GB1146867A (en)
IL (2) IL35912A (en)
NL (2) NL6618080A (en)
SE (1) SE317969B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3526642A (en) * 1968-06-19 1970-09-01 Squibb & Sons Inc 2-oxa-5beta-cyanopregnane derivatives

Also Published As

Publication number Publication date
IL27130A (en) 1971-07-28
DK135710C (en) 1977-12-27
FR1476631A (en) 1967-04-14
SE317969B (en) 1969-12-01
JPS4935618B1 (en) 1974-09-25
GB1146867A (en) 1969-03-26
NL128001C (en)
NL6618080A (en) 1967-06-26
CH467738A (en) 1969-01-31
BE691403A (en) 1967-06-19
IL35912A (en) 1971-07-28
DE1593349A1 (en) 1970-07-23
DK135710B (en) 1977-06-13
AT267775B (en) 1969-01-10

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