ES328778A1 - Procedure for the preparation of cationic monoazoic colorants. (Machine-translation by Google Translate, not legally binding) - Google Patents
Procedure for the preparation of cationic monoazoic colorants. (Machine-translation by Google Translate, not legally binding)Info
- Publication number
- ES328778A1 ES328778A1 ES0328778A ES328778A ES328778A1 ES 328778 A1 ES328778 A1 ES 328778A1 ES 0328778 A ES0328778 A ES 0328778A ES 328778 A ES328778 A ES 328778A ES 328778 A1 ES328778 A1 ES 328778A1
- Authority
- ES
- Spain
- Prior art keywords
- unsubstituted
- formula
- radical
- acid
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 2
- 125000002091 cationic group Chemical group 0.000 title 1
- 239000003086 colorant Substances 0.000 title 1
- -1 indole compound Chemical class 0.000 abstract 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- 239000000975 dye Substances 0.000 abstract 3
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 150000005840 aryl radicals Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 150000007522 mineralic acids Chemical class 0.000 abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 2
- 150000007524 organic acids Chemical class 0.000 abstract 2
- JVVRJMXHNUAPHW-UHFFFAOYSA-N 1h-pyrazol-5-amine Chemical compound NC=1C=CNN=1 JVVRJMXHNUAPHW-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- SIKJAQJRHWYJAI-UHFFFAOYSA-N benzopyrrole Natural products C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 150000008049 diazo compounds Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 abstract 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 abstract 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical class [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B44/00—Azo dyes containing onium groups
- C09B44/10—Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system
- C09B44/14—1,2-Diazoles or hydrogenated 1,2-diazoles ; Pyrazolium; Indazolium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B41/00—Special methods of performing the coupling reaction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Process for the preparation of cationic monoazo dyes, characterized in that the diazo compound of a 5-aminopyrazole of the formula I ** (See formula) ** it is coupled with an indole compound that copulates in position 3, of formula II ** (See formula) ** to arrive at a monoazoic dye of the formula III ** (See formula) ** in whose formulas R 1 is hydrogen, an alkyl radical, an unsubstituted or substituted alkyl or aryl ring, but free from groups that dissociate acid in water, R2 means an alkyl radical, aryl, carpalcoxy or an N-substituted or unsubstituted carboxylic acid amide radical, R3 and R4 each denote hydrogen or an unsubstituted or substituted alkyl or aryl radical, free of acid-dissociating groups in water, and the benzene radical A may contain substituents which do not dissociate acid in water, and this monoazo dye is reacted with the ester suitable for reaction of an unsubstituted or substituted non-ionogenic alkanol with an inorganic or organic acid to arrive at a cycloammonium compound of the formula IV ** (See formula) ** in which R1 'means an unsubstituted or substituted alkyl, cycloalkyl or aryl radical, free of acid-dissociating groups in water, R2, R3, R4 and A have the significance indicated in formulas I, II and III, R5 means an unsubstituted or substituted non-ionogenic alkyl radical, and X ⊖ means the anion of an inorganic or organic acid. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH953665A CH439524A (en) | 1965-07-07 | 1965-07-07 | Process for the preparation of monoazo dyes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES328778A1 true ES328778A1 (en) | 1967-08-16 |
Family
ID=4353029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES0328778A Expired ES328778A1 (en) | 1965-07-07 | 1966-07-06 | Procedure for the preparation of cationic monoazoic colorants. (Machine-translation by Google Translate, not legally binding) |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE683733A (en) |
| CH (1) | CH439524A (en) |
| DE (1) | DE1644243C3 (en) |
| ES (1) | ES328778A1 (en) |
| GB (1) | GB1111014A (en) |
| NL (1) | NL6609459A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2508884C3 (en) | 1975-02-28 | 1978-12-14 | Bayer Ag, 5090 Leverkusen | Cationic mono and disazo dyes and their uses |
-
1965
- 1965-07-07 CH CH953665A patent/CH439524A/en unknown
-
1966
- 1966-07-06 GB GB3028366A patent/GB1111014A/en not_active Expired
- 1966-07-06 ES ES0328778A patent/ES328778A1/en not_active Expired
- 1966-07-06 NL NL6609459A patent/NL6609459A/xx unknown
- 1966-07-06 DE DE19661644243 patent/DE1644243C3/en not_active Expired
- 1966-07-06 BE BE683733D patent/BE683733A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH439524A (en) | 1967-07-15 |
| BE683733A (en) | 1967-01-06 |
| DE1644243A1 (en) | 1971-07-29 |
| DE1644243C3 (en) | 1974-08-22 |
| GB1111014A (en) | 1968-04-24 |
| DE1644243B2 (en) | 1974-01-24 |
| NL6609459A (en) | 1967-01-09 |
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