ES2860941T3 - Compositions comprising a triazole compound and a biopesticide - Google Patents

Abstract

Compositions comprising, 1) as component I the: compound I-3 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) propan -2-ol; and 2) as component II a biopesticide selected from: Bacillus amyloliquefaciens ssp. plantarum MBI 600 (II-27), Bacillus pumilus INR-7 (II-29), Bacillus subtilis FB17 (II-176).

Description

DESCRIPTION

Compositions comprising a triazole compound and a biopesticide

The present invention relates to compositions comprising,

1) as component I:

compound I-32- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) propan-2-ol;

and

2) as component II a biopesticide selected from:

Bacillus amyloliquefaciens ssp. plantarum MBI 600 (II-27),

Bacillus pumilus INR-7 (II-29),

Bacillus subtilis FB17 (II-176).

The compositions may further comprise a component III selected from biopesticides of groups L1) to L6)

L1) Microbial pesticides with fungicidal, bactericidal, viricidal and / or activating activity of plant defenses: Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus altitudinis, B. amyloliquefaciens, B. megaterium, B. mojavensis, B. mycoides, B. pumilus, B. simplex, B. solisalsi, B. subtilis, B. subtilis var. amyloliquefaciens, Candida oleophila, C. saitoana, Clavibactermichiganensis (bacteriophages), Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Dilophosphora alopecuri, Fusarium oxisporum, Clonostachys rosea f. catenulate (Gliocladium catenulatum also called), Gliocladium roseum, Lysobacter antibioticus, L. enzymogenes, Metschnikowia fructicola, Microdochium dimerum, Microsphaeropsis ochracea, Muscodor albus, Paenibacillus alvei, Paenibacillus polymyxa, Pantoea vagans, Penicillium Bilaiae, Phlebiopsis gigantea, Pseudomonas sp., Pseudomonas chloraphis, Pseudozyma flocculosa, Pichia anomala, Pythium oligandrum, Sphaerodes mycoparasitica, Streptomyces griseoviridis, S. lydicus, S. violaceusniger, Talaromyces flavus, Trichoderma asperellum, T. atroviride, T. fertile, T. harmatum gamsii, T. harmatum gamsii, , T. polysporum, T. stromaticum, T. virens, T. viride, Typhula phacorrhiza, Ulocladium oudemansii, Verticillium dahlia, zucchini yellow mosaic virus (avirulent strain);

L2) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or activating activity of plant defenses: chitosan (hydrolyzed), harpin protein, laminarin, Menhaden's fish oil, natamycin, coat protein of Plum pox virus, bicarbonate of potassium or sodium, Reynoutria sachalinensis extract, salicylic acid, tea tree oil;

L3) Microbial pesticides with insecticidal, acaricidal, molluscid and / or nematicidal activity: Agrobacterium radiobacter, Bacillus cereus, B. firmus, B. thuringiensis, B. thuringiensis ssp. aizawai, B. t. ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, B. t. ssp. tenebrionis, Beauveria bassiana, B. brongniartii, Burkholderia spp., Chromobacterium subtsugae, granulovirus Cydia pomonella (CpGV), Cryptophlebia leucotreta granulovirus (CrleGV), Flavobacterium spp., Helicoverpa armigera nucleopolyhedrovirus of (HearNPV), Heterorhabditis bacteriophora, Isaria fumosorosea, Lecanicillium longisporum, L. muscarium, Metarhizium anisopliae, Metarhizium anisopliae var. anisopliae, M. anisopliae var. acridum, Nomuraea rileyi, Paecilomyces lilacinus, Paenibacillus popilliae, Pasteuria spp., P. nishizawae, P. penetrans, P. ramosa, P. thornea, P. Usgae, Pseudomonas fluorescens, Spodoptera littoralis nucleopolyhedrovirus (SpliNPV), Steinernema carpocapsae, S. feltiae, S. kraussei, Streptomyces galbus, S. microflavus ;

L4) Biochemical pesticides with insecticidal, acaricidal, molluscid, pheromone and / or nematicidal activity: L-carvone, citral, (E, Z) -7,9-dodecadien-1-yl acetate, ethyl formate, (E, Z ) Ethyl -2,4-decadienoate (pear ester), (Z, Z, E) - 7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, laulilyl senecioate, cis-jasmone, 2- methyl 1-butanol, methyl eugenol, methyl jasmonate, (E, Z) -2,13-octadecadien-1-ol, (E, Z) -2,13-octadeca-dien-1-ol acetate, (E, Z) - 3,13-octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E, Z, Z) -3,8,11-tetradecatrienyl acetate , (Z, E) -9,12-tetradecadien-1-yl acetate, Z-7-tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11 -tetradecen-1-ol, Black Acacia extract, Grapefruit seed extract and pulp, Chenopodium ambrosiodes extract, Catnip oil, Neem oil, Quillay extract, Tagetes oil;

L5) Microbial pesticides with plant stress reducing activity, plant growth regulator, plant growth promoter and / or performance enhancer: Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium spp., B. elkanii, B. japonicum, B. liaoningense, B. lupini, Deiftia acidovorans, Glomus intraradices, Mesorhizobium spp., Rhizobium leguminosarum bv. phaseoli, RI bv. trifolii, R. I bv. viciae, R. tropici, Sinorhizobium meliloti,

L6) Biochemical pesticides with plant stress reducing activity, plant growth regulator and / or plant performance enhancer: abscisic acid, aluminum silicate (kaolin), 3-decen-2-one, formononetin, genistein , hesperetin, homobrasinolide, humates, jasmonic acid and its salts or derivatives thereof, lysophosphatidyl ethanolamine, naringenin, polymeric polyhydroxy acid, Ascophyllum nodosum extract (Norwegian algae, brown algae) and Ecklonia maxima extract (marine algae).

The invention further relates to the use of the compositions of the invention to control phytopathogenic fungi as detailed herein and preparations or compositions comprising them. Additionally, the invention also relates to seeds comprising the compositions. Additionally, the invention also relates to methods of controlling phytopathogenic fungi as detailed in this document, in which the fungi or the materials, plants, soil or seeds to be protected from fungal attack are treated with an amount effectiveness of a composition according to the invention. Additionally, the invention also relates to processes for the preparation of the compositions according to the invention.

Practical agricultural experience has shown that the repeated and exclusive application of a single active compound in the control of harmful fungi leads in many cases to a rapid selection of those fungal strains that have developed a natural or adapted resistance against the active compound in question. . Effective control of these fungi is then no longer possible with the active compound in question.

To reduce the risk of selection for resistant fungal strains, compositions of different active compounds are now conventionally used to combat harmful fungi. By combining active compounds that have different mechanisms of action, it is possible to ensure successful control over a relatively long period of time.

It is an object of the present invention to provide, with a view to effective resistance management and effective control of harmful phytopathogenic fungi, at the lowest possible application rates, compositions which, in a reduced total amount of applied active compounds, they have improved activity against harmful fungi (synergistic compositions) and a broadened spectrum of activity, in particular for certain indications. In accordance with the foregoing, it has been found that this objective is achieved by the compositions, defined herein, which comprise a compound I and a compound II. Furthermore, it has been found that the simultaneous, that is, joint or separate application of a compound I and a compound II or the successive application of a compound I and compound II allows better control of harmful fungi than is possible with the compounds. singles alone (synergistic compositions).

According to the present invention, the compositions may comprise in addition to a compound I and a biopesticide II, as component III an additional active compound. The compositions of the invention, in the form of use as fungicides, can also be present together with other active substances, for example, with herbicides, insecticides, growth regulators, fungicides or with fertilizers, as a premix or, where appropriate, not until immediately before use (tank mix).

In accordance with the foregoing, the compositions and uses defined at the beginning and in the following description have been found. In particular, the present invention relates to compositions comprising component I and component II and to compositions comprising component I, component II and component III, in which component III is selected from other active substances, for example , with herbicides, insecticides, growth regulators, fungicides or with fertilizers. In addition to the components I, II and III mentioned, the compositions according to the invention may also comprise additional components (for example, component IV or components IV and V).

In the compositions of the invention, the compounds I and / or the additional active compounds comprised in the respective composition may be present in different crystalline modifications, which may differ in biological activity.

Compounds I can be obtained by various routes analogous to known prior art procedures (cf. J. Agric. Food Chem. (2009) 57, 4854-4860; EP 0275955 A1; DE 4003180 A1; EP 0113640 A2; EP 0 126430 A2; US 4,940,720; EP 354183 A2). Additionally, the compounds of formula I or similar compounds of the triazole class, their preparation and use in crop protection are described in documents WO 2013/024076, WO 2013/024075, WO2013 / 024077, WO 2013/024080, WO 2013/024083, WO 2013/007767 and WO 2013/010862 which also describe certain compositions with other active compounds. Some of the compounds I are described in J. Agric. Food Chem. (2009) 57, 4854-4860, EP 0 126430 A2, US 4,940,720; EP 354183 A2 and EP 0113640 A2 DE 4003180 A1.

Due to the basic character of its nitrogen atoms, component I, that is, in particular compound I-3 or any group of compound I-3 detailed in this document, is capable of forming salts or adducts with inorganic or organic acids or with metal ions, in particular salts with inorganic acids.

Examples of inorganic acids are hydrohalic acids, such as hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogen iodide, carbonic acid, sulfuric acid, phosphoric acid, and nitric acid.

Suitable organic acids are, for example, formic acid and alkanoic acids, such as acetic acid, trifluoroacetic acid, trichloroacetic acid and propionic acid, and also glycolic acid, thiocyanic acid, lactic acid, succinic acid, citric acid, benzoic acid and others. arylcarboxylic acids, cinnamic acid, oxalic acid, alkylsulfonic acids (sulfonic acids that have straight or branched chain alkyl radicals of 1 to 20 carbon atoms), arylsulfonic acids or aryldisulfonic acids (aromatic radicals, such as phenyl and naphthyl, that carry one or two sulfonic acid groups), alkylphosphonic acids (phosphonic acids having straight or branched chain alkyl radicals with 1 to 20 carbon atoms), arylphosphonic acids or aryldiphosphonic acids (aromatic radicals, such as phenyl and naphthyl, which carry one or two phosphoric acid radicals), where the alkyl or aryl radicals may carry additional substituents, for example lo, p-toluenesulfonic acid, salicylic acid, paminosalicylic acid, 2-phenoxybenzoic acid, 2-acetoxybenzoic acid, etc. Suitable metal ions are in particular the ions of the elements of the second main group, in particular calcium and magnesium, of the third and fourth main group, in particular aluminum, tin and lead, and also of the elements of transition groups one to eight , in particular chromium, manganese, iron, cobalt, nickel, copper, zinc and others. Particular preference is given to the metal ions of the elements of the transition groups of the fourth period. Metals can be present in the various valencies that they can assume.

Components I comprise chiral centers and are generally obtained in the form of racemates. The R- and S- enantiomers of the compounds according to the invention can be separated and isolated in pure form by methods known to those skilled in the art, for example using chiral HPLC. Suitable for use as antimicrobial agents are both the enantiomers and the compositions thereof. This applies correspondingly to compositions. Additionally, components I may be present in different crystal modifications, which may differ in biological activity.

In particular, in each case, a racemic composition is present. Additionally, any other proportion of the (R) enantiomer and the (S) enantiomer may be present according to the present invention. This applies to all compositions detailed in this document.

According to the present invention, component I is compound I-3. Compound I-3 can be present as a racemic composition of the (R) enantiomer and the (S) enantiomer, but the (R) enantiomer and the (S) enantiomer can also be present in any other proportion, for example the pure enantiomer ( R) or the pure (S) enantiomer of I-3.

According to a specific embodiment, compound I-3 is provided and used as enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, more preferably at least 95%, still more preferably at least 98% and most preferably at least 99%.

According to a further specific embodiment, compound I-3 is provided and used as the (S) enantiomer with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80 %, preferably at least 90%, more preferably at least 95%, still more preferably at least 98% and most preferably at least 99%.

A pesticide is generally a chemical or biological agent (such as a pesticidal active ingredient, compound, composition, virus, bacterium, antimicrobial, or disinfectant) that through its effect deters, incapacitates, kills, or otherwise discourages pests. Target pests can include insects, plant pathogens, weeds, mollusks, birds, mammals, fish, nematodes (roundworms), and microbes that destroy property, cause nuisance, spread disease, or are disease vectors. The term "pesticide" also includes plant growth regulators that alter the expected growth, flowering or reproduction rate of plants; defoliants that cause leaves or other foliage to drop off a plant, usually to facilitate harvest; desiccants that promote drying of living tissues, such as unwanted plant canopies; plant activators that activate plant physiology for the defense of certain pests; protectants that reduce the unwanted herbicidal action of pesticides on crop plants; and plant growth promoters that affect plant physiology, for example, to increase plant growth, biomass, yield or any other quality parameter of the harvestable goods of a crop plant.

Biopesticides are generally created by cultivating and concentrating naturally occurring organisms and / or their metabolites, including bacteria and other microbes, fungi, viruses, nematodes, proteins, etc. They are often considered to be important components of integrated pest management (IPM) programs, and have received much practical attention as substitutes for synthetic phytosanitary chemicals (PPPs).

Biopesticides are divided into two main classes, microbial and biochemical pesticides:

(1) Microbial pesticides consist of bacteria, fungi, or viruses (and often include the metabolites produced by bacteria and fungi). Entomopathogenic nematodes are also classified as microbial pesticides, although they are multicellular.

(2) Biochemical pesticides are naturally occurring substances that control pests or provide other uses for crop protection as defined below, but are relatively non-toxic to mammals.

The user applies the composition according to the invention normally from a pre-dosing device, a backpack sprayer, a spray tank, a spray plane or an irrigation system. Usually, the agrochemical composition is prepared with water, buffer solution and / or additional auxiliaries up to the desired application concentration and thus the ready-to-use spray liquor or the agrochemical composition according to the invention is obtained. Typically 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of useful agricultural area.

According to one embodiment, the individual components of the composition according to the invention, such as parts of a kit or parts of a binary or ternary composition, can be mixed by the user himself in a spray tank or any other type of container used for applications. (eg seed treatment drums, seed pelletizing machinery, backpack sprayer) and additional auxiliaries can be added, if required.

When live microorganisms, such as microbial pesticides of groups L1), L3) and L5), are part of a kit, care must be taken that the choice and quantities of components (e.g. chemical pesticides) and of the additional auxiliaries do not influence the viability of the microbial pesticides in the composition mixed by the user. Especially for bactericides and solvents, the compatibility with the respective microbial pesticide must be taken into account. Consequently, an embodiment of the invention is a kit for the preparation of a usable pesticidal composition, the kit comprising a) a composition comprising component I as defined herein and at least one auxiliary; and b) a composition comprising component II as defined herein and at least one auxiliary; and optionally c) a composition comprising at least one auxiliary and optionally an additional active component III as defined herein.

Many of these biopesticides have been deposited with the deposition numbers mentioned in this document (the prefixes refer to the acronym of the respective culture collection), are mentioned in the literature, are registered and / or are commercially available: aluminum silicate ( Screen ™ Duo from Certis LLC, USA), Agrobacterium radiobacter K1026 (eg NoGall® from BASF Agricultural Specialties Pty Ltd, Australia), A. radiobacter K84 (Nature 280, 697-699, 1979; eg GallTroll ® AG Biochem, Inc., C, EE. U ^u.), Ampelomyces quisqualis M-10 (e.g., AQ 10® of Intrachem Bio GmbH & Co. KG, Germany), extract or filtering Ascophyllum nodosum (algae Norwegian , brown algae) (e.g. ORKA GOLD from BASF Agricultural Specialties (Pty) Ltd., South Africa; or Goemar® from Laboratoires Goemar, France), Aspergillus flavus NRRL 21882 isolated from a peanut in Georgia in 1991 by USDA, National Peanut Research Laboratory (for example, in Afla-Guard® from Syngenta, CH), c ompositions of Aureobasidium pullulans DSM 14940 and ^d S ^m 14941 (eg blastospores in BlossomProtect® from bio-ferm GmbH, Germany), Azospirillumamazonense SpY2 (DN: BR 11140; Proc. 9th Int. And 1 st Latin American PGPR meeting, Quimara, Medellín, Colombia 2012, p. 60, ISBN 978-958-46 0908-3), A. brasilense AZ39 (also called Az 39; INTA Az-39; Eur. J. Soil Biol 45 (1), 28-35, 2009), A. brasilense XOH (for example, AZOS de Xtreme Gardening, USA or RTI Reforestation Technologies International; USA), A. brasilense BR 11002 (Proc. 9th Int. and 1 st Latin American PGPR meeting, Quimara, Medellín, Colombia 2012 , p.

60, ISBN 978-958-46-0908-3J, A. brasilense Sp245 (BR 11005; for example, in GELFIX Grasses of BASF Agricultural Specialties Ltd., Brazil), A. brasilense Ab-V5 and Ab-V6 (for example , in AzoMax by Novozymes BioAg Produtos papra Agricultura Ltda., Quattro Barras, Brazil or SimbioseMaíz® by Simbiose-Agro, Cruz Alta, RS, Brazil; Plant Soil 331, 413-425, 2010), A. lipoferum BR 11646 (Sp31) (Proc. 9th Int. And 1 st Latin American PGPR meeting, Quimara, Medellín, Colombia 2012, p. 60), Bacillus altitudinis 41KF2b (DSM 21631; Int. J. Syst. Evol. Microbiol.

56 (7), 1465-1473, 2006), Bacillus amyloliquefaciens strains AP-136 (NRRL B-50614 and B-50330), AP-188 (NRRL B-50615 and B-50331), AP-218 (NRRL B -50618), AP-219 (NRRL B-50619 and B-50332), and AP-295 (NRRL B-50620 and B-50333) all known from US 8,445,255; B. amyloliquefaciens IT-45 (CNCM I-3800) (eg Rhizocell C from ITHEC, France), B. amyloliquefaciens IN937a (J. Microbiol. Biotechnol. 17 (2), 280-286, 2007; eg BioYield ® from Gustafson LLC, Tx, USA), B. amyloliquefaciens spp. plantarum D747 (US 20130236522 A1; FERM BP-8234; eg Double Nickel ™ 55 WDG or Double Nickel ™ LC from Certis LLC, USA), B. amyloliquefaciens spp. Plantarum FZB24 isolated from plant pathogen infested soil of a sugar beet field in Brandenburg, Germany (also called SB3615; DSM ID 96-2; J. Plant Dis. Prot. 105, 181-197, 1998; for example, Taegro® from Novozyme Biologicals, Inc., USA),), B. amyloliquefaciensspp. plantarum SB3615vPPI being a phage resistant variant of FZB24 (MRRL B-50349; US 2011/023045 A1; from Novozyme Biologicals, Inc., USA), B. amyloliquefaciens ssp. plantarum FZB42 isolated from plant pathogen infested soil of a sugar beet field in Brandenburg, Germany (J. Plant Dis. Prot. 105, 181-197, 1998; DSM 23117; for example, RhizoVital® 42 from AbiTEP GmbH, Berlin, Germany), B. amyloliquefaciens ssp. plantarum GB03 (also called GBO3; ATCC SD-1397; Phytopathol. 86 (11), S36, 1996; for example, Kodiak® or BioYield® from Gustafson, Inc., USA; or Companion® from Growth Products, Ltd ., White Plains, NY 10603, USA), B. amyloliquefaciens ssp. plantarum MBI600 also designated 1430 (NRRL B-50595; Int. J. Microbiol. Res. 3 (2) (2011), 120-130; US 2012/0149571 A1; for example, Integral®, Subtilex® NG from BASF Corp. , USA), B. amyloliquefaciens spp. Plantarum TJ1000 (also called 1BE; CA 2471555 A1; ATCC BAA-390; for example, QuickRoots ™ from TJ Technologies, Watertown, SD, USA), B. cereus CNCM I-1562 (US 6,406,690), B.

chitinosporus AQ746 isolated from roots in Saskatchewan, Canada (NRRL B-21618; US 5,733,544; AgraQuest now Bayer CropScience LP, USA), B. firmus CNCM I-1582 (WO 2009/126473, WO 2009/124707, US 6,406,690 ; for example, Votivo® from Bayer CropScience LP, USA), B. megaterium strains H491 (NRRL B-50769), m018 (NRRL B-50770) and J142 (NRRL B-50771) all known from US 2014 / 0051571 A1 from Marrone Biolnnovations, Inc., USA; B. mojavensis AP-209 (NRRL B-50616; US 8,445,255), B. mycoidesAQ726 (NRRL B-21664; US 5,906,818; from Bayer Crop Science, Germany), B. mycoides J strain (for example, BmJ WG from Certis , USA against potato virus Y), B. pumilus GB34 (ATCC 700814; e.g. YieldShield® from Gustafson LLC, TX, USA), B. pumilus GHA 180 isolated from apple rhizosphere in Mexico (IDAC 260707-01; for example, in PRO-MIX® BX from Premier Horticulture, 1, avenue Premier, Rivie're-du-Loup, Quebec, Canada G5R6C1), B. pumilus KFP9F (NRRL B-50754; WO 2014/029697; for example, BAC-UP or FUSION-P from BASF Agricultural Specialties (Pty) Ltd., South Africa), B. pumilus INR-7 also referred to as BU-F22 and BU-F33 (NRRL B-50185, NRRL B-50153; US 8,445,255), B. pumilus QST 2808 (NRRL B-30087; for example, Sonata® or Ballad® Plus from AgraQuest Inc., USA), B. solisalsi AP-217 (NRRL B-50617 ; US 8,445,255), B. subtilis CX-9060 (Federal Register 77 (7), 1633-1637; by Certis USA, LLC), B. subtilis FB17 also called ado UD 1022 or UD10-22 isolated from red beet roots in North America (ATCC PTA-11857; System. Appl. Microbiol. 27, 372-379, 2004; US 2010/0260735; WO 2011/109395); B. subtilis GB07 (Phytopathol. 86 (11), S36, 1996; Epic® from Gustafson, Inc., USA), B. subtilis QST-713 isolated from a California peach orchard in 1995 (NRRl B- 21661; for example, Rhapsody®, Serenade® MAX or Serenade® ASO from AgraQuest Inc., USA), B. thuringiensisssp. aizawai ABTS-1857 (also called ABG-6346; ATCC SD-1372; for example, XenTari® from BioFa AG, Münsingen, Germany), B. t. ssp. aizawai SAN 401 I, ABG-6305 (WO 2013/087709); Bacillus t. ssp. israelensis AM65-52 of serotype H-14 (ATCC SD-1276; eg VectoBac® from Valent BioSciences, IL, USA), Bacillus thuringiensis ssp. kurstaki SB4 (NRRL B-50753; for example, Beta Pro® from BASF Agricultural Specialties (Pty) Ltd., South Africa), B. t. ssp. kurstaki ABTS-351 identical to HD-1 (ATCC SD-1275; eg Dipel® DF from Valent BioSciences, IL, USA), B. t. ssp. kurstaki EG 2348 (NRRL B-18208; for example, Lepinox® or Rapax® from CBC (Europe) Srl, Italy), B. t. ssp. tenebrionis DSM 2803 of serotype H 8a, 8b (identical to NRRL B-15939; EP 0 585 215 B1; Mycogen Corp.), B. t. ssp. tenebrionis NB-125 (also referred to as SAN 418 I or ABG-6479; EP 0585215 B1; DsM 5526; former Novo-Nordisk production strain), B. t. ssp. tenebrionis NB-176 (or NB-176-1; an induced and gamma-irradiated high-yield strain mutant ⁿ B-125; EP 585215 B1; DSM 5480; for example, Novodor® from Valent BioSciences, Switzerland), Beauveria bassiana JW-1 (ATCC 74040; for example, Naturalis® from CBC (Europe) Srl, Italy), B. bassiana DSM 12256 (US 200020031495; for example, BioExpert® SC from Live Sytems Technology SA, Colombia), B. bassiana GHA (ATCC 74250; for example, BotaniGard® 22WGP from Laverlam Int. Corp., USA), B. bassiana PPRI 5339 (ARSEF 5339; NRRL 50757; for example, BroadBand® from BASF Agricultural Specialties (Pty) Ltd. , South Africa), B. brongniartii for bumblebee control (J. Appl. Microbiol. 100 (5), 1063-72, 2006; for example, Melocont® from Agrifutur, Agrianello, Italy), Bradyrhizobium sp. (eg Vault® from BASF Corp., USA), B. sp. (Arachis) CB1015 allegedly originally collected in India (IITA 1006, USDA 3446; from Australian Inoculants Research Group; http: // www.qaseeds.com.au/inoculant_applic.php). Strains of B. sp. (Arachis) deposited in SEMIA and known to FEMS Microbiol. Letters 303 (2), 123-131, 2010; Revista Brasileira de Ciencia do Solo 35 (3), 739-742, 2011, ISSN 0100 0683: SEMIA 6144, SEMIA 6462 (BR 3267) and SEMIA 6464 (BR 3262); B. sp. (Vigna) PNL01 (Bisson and Mason, April 29, 2010, Project report, Worcester Polytechnic Institute, Worcester, MA, USA: http: // www.wpi.edu/Pubs/E-project/Available/E- project-042810-163614 /; for example Vault® Peanut Liquid from BASF Corp., USA), B. elkanii SEMIA 587 (Appl. Environ. Microbiol. 73 (8), 2635, 2007; for example, GeLfIX 5 from BASF Agricultural Specialties Ltd., Brazil), B. elkanii SEMIA 5019 (= 29W; Appl. Environ. Microbiol. 73 (8), 2635, 2007; for example, GELFIX 5 from BASF Agricultural Specialties Ltd., Brazil), B. elkanii USDA 76, B. elkanii UsDA 94B. elkanii USdA 3254, B. elkanii U-1301 and U-1302 (for example, Nitragin® Optimize from Novozymes Bio As SA, Brazil, or Nlitrasec for soy from LAGE and Cia, Brazil), B. japonicum (for example, VAULT® from BASF Corp., USA), B. japonicum 532c isolated from the Wisconsin field (Nitragin 61A152; Can. J. Plant. Sci. 70, 661-666, 1990; for example, in Rhizoflo®, Histick®, Hicoat® Super from BASF Agricultural Specialties Ltd., Canada), B. japonicum E-109 variant of USDA 138 strain (INTA E109, SEMIA 5085; Eur. J. Soil Biol. 45, 28-35, 2009; Biol. Fertil Soils 47, 81-89, 2011), B. japonicum G49 (MSDJ G49; CR Acad. Agric. Fr. 73, 163-171, 1987); SeMiA-deposited B. japonicum strains known from Appl. Environ. Microbiol. 73 (8), 2635, 2007: SEMIA 566 isolated from North American inoculant in 1966 and used in Brazilian commercial inoculants from 1966 to 1978, SEMIA 586 originally isolated in Maryland, USA. USA, in 1961 but received from Australia in 1966 and used in inoculants from Brazil in 1977 (CB 1809, UsDA 136, Nitragin 61A136, RCR 3407), SEMIA 5079 a natural variant of SEMIA 566 used in commercial inoculants since 1992 (CPAC 15 ; for example, GELFIX 5 or ADHERE 60 from BASF Agricultural Specialties Ltd., Brazil), B. japonicum SEMIA 5080 a natural variant of SEMIA 586 used in commercial inoculants since 1992 (CPAC 7; for example, GELFIX 5 or ADHERE 60 from BASF Agricultural Specialties Ltd., Brazil); B. japonicum TA-11 (TA11 NOD +) (NRRL B-18466; US 5,021,076; Appl. Environ. Microbiol. 56, 2399-2403, 1990; eg VAULT® NP, ex BASF Corp., USA) , B. japonicum known USDA deposited strains from US 7,262,151 and Appl. Environ. Microbiol. 60, 940-94, 1994: USDA 3 isolated from Glycine max in Virginia (USA) in 1914, USDA 31 (= Nitragin 61A164) or Serogroup 31 isolated from Glycine max in Wisconsin (USA) in 1941, USDA 76 isolated from the plant passage of the UsDa 74 (Serogroup 76) strain that was isolated from G. maxin California (USA) in 1956, UsdA 110 (= IITA 2121, SeMIA 5032, RCR 3427, aRs I- 110 and Nitragin 61A89; Serogroup 110) isolated from G. max in Florida in 1959, USDA 121 isolated from G. max in Ohio (USA) in 1965 (Crop Science 26 (5), 911-916, 1986); B. japonicum WB74 (for example, Eco-Rhiz Soya of Plant Health Products (Pty) Ltd, South Africa; or soy inoculant from Stimuplant CC, South Africa), B. lupini LL13 isolated from nodules of Lupinus iuteus from French soils (deposited in InRa, France; http: // agriculture. Gouv.fr/IMG/pdf/ch20060216.pdf), B. lupinistrains from Australia and known from Palta JA, Berger JB (eds), Proceed.

12th International Lupine Conference, 14-18 Sept. 2008, Fremantle, Western Australia, International Lupine Association, Canterbury, New Zealand, 47-50, http://www.lupins.org/pdf/conference/2008/Aqronomy% 20and% 20Production / John% 20Howie are% 20and% 20G % 20OHara.pdf; Appl. Environ. Microbiol. 71, 7041-7052, 2005; Australian J. Exp. Aqricult. 36 (1), 63-70, 1996: strain WU425 isolated in Esperance, Western Australia from a non-Australian lequminase Ornithopus compressus, WSM471 isolated from Ornithopus pinnatus in Oyster Harbor, Western Australia, and WSM4024 isolated from lupins in Australia by CRS during a 2005 survey; Burkholderia sp. A396 (NRRL B-50319; WO 2013/032693; Marrone Bio Innovations, Inc., USA), Candida oleophila I-182 (NRRL Y-18846; Phytoparasitica 23 (3), 231-234, 1995; for example , Aspire® from Ecoqen Inc., USA;), C. oleophila O strain (NRRL Y-2317; Bioloqical Control 51, 403-408, 2009), Candida saitoana (for example, Biocure® [in composition with lysozyme] and BioCoat® from Micro Flo Company, USA (BASF SE) and Arysta), chitosan (eg Armour-Zen® from BotriZen Ltd., NZ), Clonostachys rosea f. catenulate (also called Gliocladium catenulatum) J1446 isolated from Finnish field soil (NJF seminar No 389: Pest, disease and weed manaqement in strawberry; Finland 8-9. Nov. 2006 in N ^j F Report 2 (10), 15-15 , 2006; DSM 9212; for example, Primastop® or Prestop® from Verdera Oy, Finland), Chromobacterium subtsugae PRAA4-1 isolated from the soil under an eastern hemlock ( Tsuga canadensis) in the mountainous Catoctin region of central Maryland (NRR ¹ B-30655; eg Grandevo® from Marrone Bio Innovations, USA), Coniothyrium minitans CON / M / 91-08 (WO 1996/021358; DSM 9660; eg Contans® WG, Intercept® WG from Prophyta Bioloqischer Pflanzenschutz GmbH, Germany), Cryphonectria parasitica (hypovirulent strains; Microbiol. Reviews 56 (4), 561-576, 1992; e.g. Endothia parasitica product from CNICM, France), Cryptococcus albidus (e.g. YIELD PLUS ® from Anchor Bio-Technoloqies, South Africa), Cryptophlebia leucotreta qranulovirus (CrleGv) (e.g. CRYPT EX from Adermatt Biocontrol, Switzerland), Cydia pomonella qranulovirus (CpGV) V03 (DSM GV-0006; eg Madex® Max from Andermatt Biocontrol, Switzerland), CpGV V22 (DSM GV-0014; eg Madex® Twin from Adermatt Biocontrol, Switzerland), Delftia acidovorans RAY209 (a Tc C PTA-4249; WO 2003/57861; for example, BioBoost® from Brett Younq, Winnipeq, Canada), Dilophosphora alopecuri (FarmNote 396, Feb. 2010, Department of Agriculture and Food, Government of Western Australia; for example, Twist Funqus from BASF Aqricultural Specialties Pty Ltd, Australia), Ecklonia maxima ( seaweed) extract (J. Ecoloqical Enqineerinq 14 (1), 48-52, 2013; for example, KELPAK SL from Kelp Products Ltd, South Africa), Flavobacterium sp. H492 (ATCC B-505584; WO 2013/138398; for example, MBI-302 from Marrone Bio Innovations, USA for soyean cyst nematode control), formononetin (US 5,002,603; for example, Myconate® from Plant Health Care plc, United Kingdom), Fusarium oxysporum Fo47 (non-pathoqenic strain isolated from a suppressive soil located at Cháteaurenard, France; Appl. Environ. Microbiol 68 (8), 4044-4060, 2002; Fusaclean® de Natural Plant Protection, NPP (société anonyme ) Route d'Artix F-64150 Noqueres, France), F. oxysporum 251 / 2RB (Prevention Today Vol. 2, n. 1-2, 47-62, 2006; for example, Biofox® C from SIAPA, Italy); Glomus intraradices (for example, Myc® 4000 from ITHEC, France), Glomus intraradices RTI-801 (for example, MYKOS from Xtreme Gardeninq, USA or RTI Reforestation Technoloqies International; USA), grapefruit seeds and extract pulp (eg BC-1000 from Chemie SA, Chile), harpin protein (alpha-beta) (Science 257, 85-88, 1992; eg Messenqer ™ or HARP-N-Tek from Plant Health Care plc, United Kingdom), Helicoverpa armigera nucleopolyhedrovirus (HearNPV) (J. Invertebrate Pathol. 107, 112-126, 2011; for example, Helicovex® from Adermatt Biocontrol, Switzerland), Heterorhabditis bacteriophora (for example, Nemasys® G from BASF Aqricultural Specialties Limited, UK), Isaria fumosorosea Apopka-97 (a Tc C 20874; Biocontrol Science Technol. 22 (7), 747-761, 2012; for example, PFR-97 ™ or PreFeRal® from Certis LLC, USA). ), /. fumosorosea FE 9901 (AR ^s EF 4490; Biocontrol Science Technol. 22 (7), 747-761, 2012; for example, blastospores in NoFly ™ WP from Natural Industries, Inc., Houston, TX, USA ^or U. or from Novozymes, EE U ^u), cis -jasmone (US 6,890,525;.. US 8,221,736; Plant Bioscience Limited, Norwich, UK), laminarin (for example in Laboratoires Vacciplant® Goemar, St. Malo, France or Stahler SA, Switzerland), Lecanicilliumlongisporum KV42 and KV71 (for example, Vertalec® from Koppert BV, The Netherlands), L. muscarium Ve6 (also called KV01; IMI 19-79, C ^a B ⁱ 268317, CBS 102071, A ^r S ^e F 5128 ; for example, Mycotal® from Koppert BV, Netherlands), Lysobacter antibioticus 13-1 (Bioloqical Control 45, 288-296, 2008), L. antibioticus HS124 (Curr. Microbiol. 59 (6), 608-615, 2009) , L. enzymogenes 3.1T8 (Microbiol. Res. 158, 107-115, 2003; Bioloqical Control 31 (2), 145-154, 2004); strains of Mesorhizobium spp. known from Soil Biol. Biochem.

36 (8), 1309-1317, 2004; Plant and Soil 348 (1-2), 231-243, 2011: M. sp. WSM1271 collected in Sardinia, Italy, from the host plant Biserrula pelecinus, M. sp. WSM 1497 collected in Mykonos, Greece, from Biserrula pelecinus, Mesorhizobium ciceri CC1192 collected in Israel from Cicer arietinum nodules (UPM 848, CECT 5549; Can. J. Microbiol. 48, 279-284, 2002; from Horticultural Research Station, Gosford, Australia), M. huakuii HN3015 isolated from Astralagus sinicus in a rice field in southern China (World J. Microbiol. Biotechn. 23 (6), 845-851, 2007, ISSN 0959-3993), M. loti CC829 isolated from L. ulginosus nodules in the USA (NZP 2012; commercial inoculant for Lotus pedunculatus and L. ulginosus in Australia), and M. loti SU343 isolated from host nodules in the USA (commercial inoculant for Lotus corniculatus in Australia); Metarhizium anisopliae FI-1045 (AGAL V10 / 0104285; WO 2012/018266; eg Biocane® from BASF Aqricultural Specialties Pty Ltd, Australia), M. anisopliae var. anisopliae F52 also called 275 or V275 (DSM 3884, ATCC 90448; for example, Met52® Novozymes Bioloqicals BioAq Group, Canada), M. anisopliae ICIPE 69 isolated from a soil sample obtained from the Democratic Republic of the Congo (DRC) and using the Galleria bait method in 1990 (eg Metathripol from ICIPE, Nairobe, Kenya), M. anisopliae var. acridum IMI 330189 isolated from Ornithacris cavroisi in Niqer (NRRL 50758; for example, Green Muscle® from BASF Aqricultural Specialties (Pty) Ltd., South Africa), M. a. var. acridum FI-985 isolated from a spiny qarqanta lanka, Austracris quttulosa (Walker), near Rockhampton, Queensland, Australia, in 1979 (ARSEF 324; Memoirs of the Entomoloqical Society of Canada 171, 287-300, 1997; for example, Green Guard® SC from BASF Aqricultural Specialties Pty Ltd, Australia), Metschnikowia fructicola 277 isolated from the surface of grape berries (cv. Superior) grown in central Israel (US 6,994,849; NRRL Y-30752; for example, Shemer® from Agrogreen, Israel, now distributed by Bayer CropSciences, Germany), Microdochium dimerum L13 (CNCM I-3141; for example, Antibot® from Agrauxine, France), Microsphaeropsis ochracea P130A isolated from apple leaves from an orchard abandoned, St-Joseph-du-Lac, Quebec, Canada in 1993 (ATCC 74412; Mycologia 94 (2), 297-301, 2002), Muscodor albus QST 20799 also called 620 originally isolated from the bark of a cinnamon tree in Honduras (NRRL 30547; for example, Muscudor ™ or QRD300 from AgraQuest, USA), Muscodor albus SA-13 (NRRL B-50774; US 2014/0086879 A1; for example, MBI-601-EP from Marrone Biolnnovations, Inc., USA), Neem oil (for example, Trilogy®, Triact® 70 EC from Certis LLC, USA), Nomuraea rileyistrains SA86101, GU87401, SR86151, CG128 and VA9101 (Braz. Arch. Biol Technol.

46 (1), 13-19, 2003; WO 2013/110594), Paecilomyces lilacinus 251 isolated from infected nematode eggs in the Philippines (AGAL 89/030550; WO1991 / 02051; Crop Protection 27, 352-361, 2008; e.g. BioAct® / MeloCon® from Prophyta, Germany) , P. lilacinus DSM 15169 (for example, Nemata® SC from Live Systems Technology SA, Colombia), P. lilacinus BCP2 (NRRL 50756; Acta Agriculturae Slovenica, 101-2, 263-275, 2013; for example, PL Gold de BASF Agricultural Specialties (Pty) Ltd., South Africa), Paenibacillus alvei NAS6G6 (WO 2014/029697; NRRL B-50755; for example, BAC-UP from BASF Agricultural Specialties (Pty) Ltd., South Africa in composition with Bacillus pumilus KFP9F) , P. polymyxa PKB1 (ATCC 202127; Can. J. Microbiol. 48 (2), 159-169, 2002), Pantoea agglomerans E325 (NRRL B-21856; Phytopathol. 101 (10), 1234-41, 2011; Trees 26, 227-238, 2012; Bloomtime Biological ™ from Northwest Agricultural Products, Inc., USA), Pantoea vagans (formerly agglomerans) C9-1 originally isolated in 1994 from stem tissue of apple for control of fire blight in apple (J. Bacteriol.

192 (24), 6486-6487, 2010; for example, BlightBan C9-1® from NuFrams America Inc., USA), Pasteuria sp. ATCC PTA-9643 (WO 2010/085795), Pasteuria sp. Ph3 isolated from turfgrass soil samples collected at the DeBary Golf Course in central Florida (ATCC Sd-5832; WO 2012/064527; for control of the Hoplolaimus galeatus nematode from Pasteuria Bioscience, Inc. now Syngenta Crop Protection, LLC, USA), Pasteuria sp. Pr3 isolated from soil samples collected in the southeastern United States (ATCC SD-5834; for control of the Rotylenchulus reniformis nematode potentially P. ramosa species; Naviva® ST from Syngenta Crop Protection, LLC, USA). ), P. nishizawae (WO 2010/80619), P. nishizawae Pn1 (Federal Register 76 (22), 5808, February 2, 2011; ATCC Sd-5833; for example, Clariva ™ PN from Syngenta Crop Protection, LLC, EE USA), P. penetrans (US 5,248,500; Del Monte Corp.), P. ramosa (WO 2010/080619), P. thornea (WO 2010/080619), P. usgae BL1 (ATCC SD-5835; J. Nematol. 42 (2): 87-90, 2010; ibid 43 (2), 101-109, 2011; for example, Econem ™ for the control of Belonolaimus longicaudatus from Pasteuria BioScience now Syngenta sold by Harell's LLC, Florida, USA. For use in lawns for the management of Belonolaimus longicaudatus), Penicillium bilaiae (also called P. bilaii) strains ATCC 18309 (= ATCC 74319), ATCC 20851 and / or ATCC 22348 (= ATCC 74318) originally isolated from the soil in the southern Alberta (Fertilizer Res. 39, 97-103, 1994; Dog. J. Plant Sci. 78 (1), 91-102, 1998; US 5,026,417, WO 1995/017806; for example, Jump Start®, Provide® from Novozymes Biologicals BioAg Group, Canada), P. bilaiae NRRL 50162 and nRrL 50169 (WO 2010/037228), Phlebiopsis gigantea (for example, RotStop® from Verdera Oy, Finland), Pichia anomala WRL-076 (NRRL Y-30842; Us 8,206,972), potassium bicarbonate (eg Amicarb® from Stahler SA, Switzerland), potassium silicate (eg Sil-MATRIX ™ from Certis LLC, USA), Pseudozyma flocculosa PF-A22 UL (eg, Sporodex® L from Plant Products Co. Ltd., Canada), Pseudomonas sp. Proradix (DSM 13134; WO 2001/40441, eg PRORADIX from Sourcon Padena GmbH & Co. KG, Hechinger Str. 262, 72072 Tübingen, Germany), P. chloraphis MA 342 (Microbiology Monographs 18, 21-43, 2011; eg Cerall® or Cedemon® from BioAgri AB, Uppsala, Sweden or Intrachem Bio Deutschland GmbH & Co. KG, Bad Camberg, Germany), P. fluorescens (eg in Bio Cure-B from T. Stanes & Company Limited , India; or in Blight-End from Agri Naturals, Mumbai, India), P. fluorescens A506 (Phytopathol 97 (2), 244-249, 2007; ATCC 31948; for example, BlightBan® from NuFarm Americas, Inc., Morrisville , NC, eE. USA), P. fluorescens ATCC 13525 from biovar I = biotype A; originally isolated from pre-filter tanks in England (DSM 50090; registered for use in Canada), P. fluorescens CHA0 (Mol. Plant Microbe Interact. 5 (1), 4-13, 1992), P. fluorescens CL 145a (J Invertebr. Pathol. 113 (1), 104-14, 2013; for example, Zequanox® from Marrone Biolnnovations, Davis, CA, USA), P. fluorescens NCIB 12089 (EP 0210734 A !; Victus® from Mauri Laboratories, 9 Moorebank Ave., Moorebank, NSW 2170, Australia), P. fluorescens Pf-5 isolated from the cotton root surface (ATCC BAA-477), P. putida ATCC 202153 (EMBRAPA 63/88 4 B; WO 2004/0245865), Pythium oligandrum DV 74 (US 2013/0035230; ATCC 38472; e.g. Poyversum® from Remeslo SSRO, Biopreparaty, Czech Rep. And from Gowan, USA), Reynoutria sachalinensis extract (EP 0307510 B1; eg Regalia® SC from Marrone Biolnnovations, Davis, CA, USA or Milsana® from BioFa AG, Germany), Rhizobium leguminosarum bv. phaseoli ( eg RHIZO-STICK from BASF Corp., USA), R. leguminosarum bv. phaseoliRG-B10 (USDA 9041; from Int. J. Syst. Bacteriol. 46 (1), 240 244, 1996; Int. J. Syst. Evol. Microbiol. 50, 159-170, 2000; for example, Nodulator® Dry Bean in Africa, HiStick NT Dry bean in the US, and Nodulator® Dry Bean in Canada from BASF Corp., USA, or BASF Agricultural Specialties Ltd., Canada), R. /. bv. trifolii CB782 Nodulaid® peat for Kenya white clover from BASF Agricultural Specialties Pty Ltd, Australia), RI bv. trifoliiCC275e (Nodulaid® Peat for White Clover from NZ from BASF Agricultural Specialties Pty Ltd, Australia), RI bv. trifolii CC283b (ICMP 4073b; Proc. New Zealand Grassland Assoc. 56, 101-105, 1994; Microbiol. 153, 3184-3195, 2007; Nodulaid® peat for Caucasian clover from BASF Agricultural Specialties Pty Ltd, Australia), RI bv. trifolii CC1099 (Inoculating Legumes: A Practical Guide, ed. Grain Research and Development Corporation, 2012, ISBN 978-1-921779-45-9; for example, Nodulaid® peat for sainfoin from BASF Agricultural Specialties Pty Ltd, Australia), RI bv. trifolii RP113-7 (Appl. Environ. Microbiol. 44 (5), 1096-1101, 1982; eg, Dormal® from BASF Corp., USA), RI bv. trifolii TA1 (Appl. Environ. Microbiol. 49 (1), 127-131, 1985; for example, Nodulaid® peat for white clover from BASF Agricultural Specialties Pty Ltd, Australia), RI bv. trifolii strain WSM1325 isolated in 1993 from the Greek island of Serifos (Stand. Genomic Sci. 2 (3), 347-356, 2010; Inoculating Legumes: A Practical Guide, ed. Grain Research and Development Corporation, 2012, ISBN 978-1 -921779-45-9; Nodulaid® peat for sub-clover and Nodulator® granules for sub-clover, both from BASF Agricultural Specialties Pty Ltd, Australia, for a wide range of annual clovers of Mediterranean origin), RI bv. Trifolii strain WSM2304 isolated from Trifolium polymorphum in Uruguay in 1998 (Stand. Genomic Sci. 2 (1), 66-76, 2010), RI bv. viciae P1NP3Cst is a streptomycin resistant mutant of P1NP3C isolated from pea root nodules in Breteniére, France (also referred to as 1435; New Phytol. 176, 680-690, 2007; ibid 179 (1), 224-235, 2008; by example, Nodulator® PL Peat Granule from BASF Corp., USA; or Nodulator® XL PL from BASF Agricultural Specialties Ltd., Canada), RI bv. viciae RG-P2 also called P2 isolated from pea root nodules in Sakatchewan, Canada (eg RhizUP peat for peas and lentils in Canada from BASF Agricultural Specialties Ltd., Canada), RI bv. viciae SU303 (eg Nodulaid® Group E from BASF Agricultural Specialties Pty Ltd, Australia), RI bv. viciae WSM1455 (for example, Nodulaid® Group F from BASF Agricultural Specialties Pty Ltd, Australia), R. tropici CC511 (Agronomy, NZ 36, 4-35, 2006; for example, Nodulaid® peat for common beans from BASF Agricultural Specialties Pty Ltd, Australia), R. tropici CIAT 899 isolated in Colombia (SEMIA 4077; Rev. Ciénc. Agron. 44 (4) Fortaleza Oct./Dec. 2013; for example, Nitrafix® FEIJÁO peat for beans from BASF Agricultural Specialties Ltd. , Brazil in composition with the strain SeMiA 4080), R. tropici H12 isolated in Planaltina, DF, Cerrados, Brazil (SEMIA 4088; Appl. Microbiol. Biotechnol. 93 (5), 2035-49, 2012; for example, Nitrafix® FEIJÁO from BASF Agricultural Specialties Ltd., Brazil), R. tropici PRF 81 isolated from Paraná, Brazil (SEMIA 4080; Soil Biology & Biochemistry 39, 867-876, 2007; BMC Microbiol. 12, 84, 2012; Nitrafix® peat ^f E ⁱ JÁO for beans from ^b A ^s F Agricultural Specialties Ltd., Brazil in composition with the strain SEMIA 4077), Sinorhizobium meliloti RCR2011 also called do 2011 or SU47 (MSDJ0848; Mol. Gen. Genomics 272, 1-17, 2004; for example Dormal® Alfalfa & Luzerne from BASF Corp., USA; Nitragin® Gold from Novozymes Biologicals BioAg Group, Canada), Sphaerodes mycoparasitica SMCD2220 also called SMCD2220-01 (IDAC 301008-01; WO 2011/022809), nucleopolyhedrovirus from Adermatt littoralis (SpliNPV) (for example, from LITTOVIR from Adermatt Biocontrol, Switzerland ), Steinernema carpocapsae (e.g. Millenium® from BASF Agricultural Specialties Limited, UK), S. feltiae (Nemashield® from BioWorks, Inc., USA; Nemasys® from BASF Agricultural Specialties Limited, UK), S Kraussei L137 (Nemasys® L from BASF Agricultural Specialties Limited, UK), Streptomyces galbus AQ6047 (NRRL 30232; WO 2012/135763; AgraQuest now Bayer CropScience LP, USA); S. galbus M1064 (NRRL 50334; WO 2012/135763; AgraQuest now Bayer CropScience LP, USA); S. griseoviridis K61 (Crop Protection 25, 468-475, 2006; for example, Mycostop® from Verdera Oy, Espoo, Finland), S. lydicus WYEC 108 (US 5,403,584; for example, Actinovate® from Natural Industries, Inc., USA), S. violaceusniger YCED-9 (US 5,968,503; e.g. DT-9® from Natural Industries, Inc., USA), Talaromyces flavus V117b isolated from soil (e.g. Protus® WG from Prophyta, Germany), Trichoderma asperellum SKT-1 isolated from the rhizosphere of Japanese grass (FERM P-16510; J. Gen. Plant Pathol. 71 (5), 351-356, 2005; for example, Eco-Hope® from Kumiai Chemical Industry Co., Ltd., Japan), T. asperellum ICC 012 isolated from a soil in central Italy found to suppress plant diseases (IMI 392716; for example, Tenet WP, Remdier WP, or Bioten WP from Isagro nC, USA, Bio-Tam ™ from AgraQuest, USA), T. asperellum TV1 formerly T. viride (MUCL 43093; for example, T. viride TV1 from Agribiotec srl, Italy or Xedavir from Xeda Italia, Italia), T. atroviride LC52 (for example, Sentinel® from Agrimm Technologies Ltd, NZ), T. atroviride CNCM I-1237 (for example, Esquive® WG from Agrauxine SA, France, for example, against pruning wound diseases in root pathogens of plants and vine), T. fertile JM41R (NrRl 50759; eg Trichoplus ™ from BASF Agricultural Specialties (Pty) Ltd., South Africa), T. gamsii ICC 080 (IMI 392151; eg Tenet Wp, Remdier WP, Bioten WP from Isagro NC, USA, Bio-Tam ™ from AgraQuest, USA) T. harzianum T-22 also called KRL-AG2 (ATCC 20847; Bio-Control 57, 687-696, 2012; for example Plantshield® from BioWorks Inc., USA or SabrEx ™ from Advanced Biological Marketing Inc., Van Wert, OH, USA), T. harzianum T-35 and T-315 (ATCC 20691; EP 0133878 B1; for example, Root Pro® from Mycontrol Ltd., Israel ), T. harzianum T-39 (CNCM I-952; EP 0466133 B2; for example, Trichodex® or Trichoderma 2000® from Mycontrol Ltd., Israel and Makhteshim Ltd., Israel), composition of T. harzianum and T. viride (for example, Trichopel® from Agrimm Technologies Ltd, NZ), composition of T. harzianum ICC012 and T. viride ICC080 (for example, Remdier® WP from Isagro Ricerca, Italy), T. polysporum IMI 206039 (ATCC 20476; for example , Binab® from BinAb Bio-Innovation AB, Sweden in composition with T. a troviride IMI 206040), T. stromaticum (for example, Tricovab® from CEPLAC, Brazil), T. virens GI-3 also called G1-3 or GL-3 (CA 2471555 A1; AtCc 58678; e.g. QuickRoots ™ from TJ Technologies, Watertown, SD, USA in composition with B. amyloliquefaciens TJ1000), T. virens GL-21 also called G1-21 isolated from a sclerotia of Sclerotinia minor (US 7,429,477; for example , Soilguard® 12G by Certis LLC, USA; EPA Registration Number: 70051-3 and EPA Establishment Number: 067250-IL-001), T. virens G-41 also called 041, # 41X or ABM 127 isolated from soil samples taken from Aphanomyces suppressor bean fields in Livingston County, New York (ATCC 20906; US 4,996,157; e.g. Rootshield® PLUS from BioWorks, Inc., USA), T. viride (J. Biological Control 23 (1), 31-36, 2009; for example, Trieco® from Ecosense Labs. (India) Pvt. Ltd., India; or Bio-Cure® F from T. Stanes & Co. Ltd. , India), and Ulocladium oudemansii HRU3 (Agronomy 3, 632-647, 2013; for example, Botry-Zen® from Botry-Zen Ltd, NZ).

(3) Strains can be obtained from culture collections and deposition centers (listed by their acronym = strain prefix in this document http://www.wfcc.info/ccinfo/collection/by_acronym/) such as strains with prefixes AGAL or NMI from: National Measurement Institute, 1/153 Bertie Street, Port Melbourne, Victoria, Australia 3207; ATCC: American Type Culture Collection, 10801 University Blvd., Manassas, VA 20110-2209, USA; BR: Embrapa Agrobiology Diazothrophic Microbial Culture Collection, POBox 74.505, Seropedica, Rio de Janeiro, 23.851-970, Brazil; CABI or IMI: CABI Europe - International Mycological Institute, Bakeham Lane, Egham, Surrey, TW209TYNRRL, UK; CB: The CB Rhizobium Collection, School of Environment and Agriculture, University of Western Sydney, Hawkesbury, Locked Bag 1797, South Penrith Distribution Center, NSW 1797, Australia; CBS: Centraalbureau voor Schimmelcultures, Fungal Biodiversity Center, Uppsalaan 8, PO Box 85167, 3508 AD Utrecht, The Netherlands; CC: Division of Plant Industry, CSIRO, Canberra, Australia; CNCM: Collection Nationale de Cultures de Microorganismos, Institute Pasteur, 25 rue du Docteur Roux, F-75724 PARIS Cedex 15; CPAC: Embrapa-Cerrados, CX.Postal 08223, Planaltina, DF, 73301-970, Brazil; DSM: Leibniz-Institut DSMZ-Deutsche Sammlung von Mikroorganismen und Zellkulturen GmbH, InhoffenstraBe 7 B, 38124 Braunschweig, Germany; IDAC: International Depositary Authority of Canada Collection, Canada; ICMP: Interntional Collection of Micro-organisms of Plants, Landcare Research, Private Bag 92170, Auckland Mail Center, Auckland 1142, New Zealand; IITA: IITA, PMB 5320, Ibadan, Nigeria; INTA: Agriculture Collection Laboratory of the Institute of Agricultural Microbiology and Zoology (IMYZA), National Institute of Agricultural Technology (INTA), Castelar, Argentina; MSDJ: Laboratoire de Microbiologie des Sols, INRA, Dijon, France; MUCL: Mycothéque de l'Université catholique de Louvain, Croix du Sud 2, box L7.05.06, 1348 Louvain-la-Neuve, Belgium; nCiMB or NICB: The National Collections of Industrial and Marine Bacteria Ltd., Torry Research Station, PO Box 31, 135 Abbey Road, Aberdeen, AB9 8DG, Scotland; Nitragin: Nitragin strain collection, The Nitragin Company, Milwaukee, Wisconsin, USA, NRRL or ARSEF (collection of entomopathogenic fungi): ARS Culture Collection of the National Center for Agricultural Utilization Research, Agricultural Research Service, US Department of Agriculture, 1815 North University Street, Peoria, Illinois 61604, USA; NZP: Department of Scientific and Industrial Research Culture Collection, Applied Biochemistry Division, Palmerston North, New Zealand; PPRI: ARCPlant Protection Research Institute, Private Bag X134, Queenswood Pretoria, Gauteng, 0121, South Africa; SEMIA: FEPAGRO-Fundagao Estadual de Pesquisa Agropecuária, Rua Gongalves Dias, 570, Bairro Menino Deus, Porto Alegre / RS, Brazil; SRDI: SARDI, Adelaide, South Australia; USdA: US Department of Agriculture, Agricultural Research Service, Soybean and Alfalfa Research Laboratory, BARC-West, 10300 Baltimore Boulevard, Building 011, Beltsville, MD 20705, USA (Beltsville Rhiz. Cult. Catalog: http: //pdf.usaid. gov / pdf_docs / PNAAW891.pdf); and WSM: Murdoch University, Perth, Westerm Australia. More strains can be found at: http://gcm.wfcc.info/; http: // www.landcareresearch.co.nz/resources/ collections / icmp. Jasmonic acid, its salts (jasmonates) or derivatives include, without limitation, potassium, sodium, lithium, ammonium, dimethylammonium, isopropylammonium, diolammonium and diethtriethanolammonium jasmonate; and also jasmonic acid methyl ester, jasmonic acid amide, jasmonic acid methylamide, jasmonic acid-L-amino acid conjugates (linked by amide) (for example, conjugated with L-isoleucine, L-valine, L-leucine or L -phenylalanine), 12-oxo-phytodienoic acid, coronatin, coronalon, coronafacoyl-L-serine, coronafacoyl-L-threonine, 1-oxo-indanoyl-isoleucine methyl esters, 1-oxo-indanoyl-leucine methyl esters, cisjasmone , linoleic acid or derivatives thereof and combinations of any of the above.

Bacillus amyloliquefaciens subsp. plantarum MBI600 with accession number NRRL B-50595 is deposited with the United States Department of Agriculture on Nov. 10, 2011 under the strain designation Bacillus subtilis 1430. It has also been deposited with The National Collections of Industrial and Marine Bacteria Ltd. (NCIB), Torry Research Station, PO Box 31, 135 Abbey Road, Aberdeen, AB9 8DG, Scotland, under accession number 1237 on December 22, 1986. Bacillus amyloliquefaciens MBI600 is known as plant growth promoting rice seed treatment from Int. J. Microbiol . Res. ISSN 0975-5276, 3 (2) (2011), 120-130 and is described in more detail, for example, in US 2012/0149571 A1. This MBI600 strain is commercially available as an Integral® liquid formulation product (Becker-Underwood Inc., USA). Metarhizium anisopliae IMI33 is commercially available from Becker Underwood as a Green Guard product. The acridium strain of M. anisopliae var IMI 330189 (NRRL-50758) is commercially available from Becker Underwood as a Green Muscle product.

According to one embodiment, the microbial pesticides selected from II-27, II-29 and II-176 encompass not only the isolated pure cultures of the respective microorganism as defined herein, but also their cell-free extract, suspensions in a broth of complete culture or as a supernatant containing a metabolite or a purified metabolite obtained from a complete culture broth of the microorganism or strain of microorganisms.

According to a further embodiment, the microbial pesticides selected from II-27, II-29 and II-176 encompass not only isolated pure cultures of the respective microorganism as defined herein, but also a cell-free extract of the same or at least a metabolite thereof, and / or a mutant of the respective microorganism having all the identifying characteristics thereof and also a cell-free extract or at least one metabolite of the mutant; "Whole broth culture" refers to a liquid culture that contains both cells and medium.

"Supernatant" refers to the liquid broth that remains when cells growing in the broth are removed by centrifugation, filtration, sedimentation, or other means well known in the art.

The term "metabolite" refers to any compound, substance or by-product produced by a microorganism (such as fungi and bacteria) that improves plant growth, plant water use efficiency, plant health, appearance of the plant or the population of beneficial microorganisms in the soil around the activity of the plant.

The term "mutant" refers to a microorganism obtained by direct mutant selection but also includes microorganisms that have been further mutagenized or otherwise manipulated (eg, by the introduction of a plasmid). In accordance with the foregoing, embodiments include mutants, variants, and / or derivatives of the respective microorganism, both naturally-occurring and artificially induced mutants. By For example, mutants can be induced by subjecting the microorganism to known mutagens, such as N-methylnitrosoguanidine, using conventional methods.

Humates are humic and fulvic acids extracted from a form of lignite and clay coal, known as leonardite. Humic acids are organic acids found in humus and other organic materials such as peat and certain soft coals. They have been shown to increase the efficiency of fertilizers in the absorption of phosphates and micronutrients by plants, as well as aiding in the development of plant root systems.

According to an embodiment of the invention, the biopesticide component II is selected from:

Microbial pesticides with fungicidal, bactericidal, virucidal and / or activator of plant defenses selected from: Bacillus amyloliquefaciens ssp. plantarum MBI 600 (11-27), B. pumilus INR-7 (II-29);

According to one embodiment of the compositions of the invention, the at least one biopesticide component II is Bacillus amyloliquefaciens ssp. plantarum MBI600. These compositions are particularly suitable for soybeans.

According to another embodiment of the compositions of the invention, the at least one biopesticide component II is B. pumilus INR-7 (also called BU-F22 (NRRL B-50153) and BU-F33 (NRRL B-50185; see document WO 2012/079073) These compositions are particularly suitable for soybeans and corn.

According to a further embodiment, the at least one biopesticide component II is B. subtilis strain FB17.

According to one embodiment of the compositions of the invention, the at least one biopesticide component II is selected from B. amyloliquefaciens ssp. plantarum MBI600, B. subtilis FB17. These compositions are particularly suitable for soybeans and corn, in particular for treating seeds.

The user applies the composition according to the invention normally from a pre-dosing device, a backpack sprayer, a spray tank, a spray plane or an irrigation system. Usually, the agrochemical composition is prepared with water, buffer solution and / or additional auxiliaries up to the desired application concentration and the ready-to-use spray liquor or the agrochemical composition according to the invention is thus obtained. Typically, 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of useful agricultural area.

According to one embodiment, the individual components of the composition according to the invention, such as parts of a kit or parts of a binary or ternary composition, can be mixed by the user himself in a spray tank or any other type of container used for applications. (eg seed treatment drums, seed pelletizing machinery, knapsack sprayer) and other auxiliaries can be added, if applicable. Accordingly, one embodiment of the invention is a kit for preparing a usable pesticidal composition, the kit comprising a) a composition comprising component I as defined herein and at least one auxiliary; and b) a composition comprising component II as defined herein and at least one auxiliary; and optionally c) a composition comprising component III as defined herein and at least one auxiliary.

The mixture of the compounds I or the compositions comprising them in the form of use as fungicides with other fungicides results in many cases in obtaining an expansion of the spectrum of fungicidal activity or in a prevention of the development of resistance to fungicides. Additionally, in many cases synergistic effects are obtained.

The compositions of the invention and their preferred uses are described in more detail below. In each case, according to the present invention, the use of the composition to control a particular phytopathogenic fungus is also intended to encompass the respective method of controlling the particular phytopathogenic fungi, wherein the fungi or the materials, plants, soil or seeds that are they will protect from fungal attack are treated with an effective amount of a composition as defined in that particular context.

According to another embodiment of the invention, the biopesticide component II is selected from

Bacillus amyloliquefaciens MBI 600 ssp. plantarum (11-27);

B. pumilus INR-7 (11-29);

According to yet another embodiment of the invention, the biopesticide component II is

Bacillus subtilis FB17 (II-176)

Particularly preferred two-component compositions are:

B-59 I-3 II-27;

B-61 I-3 II-29.

According to a specific aspect, they are binary compositions each containing only these two components as active compounds. Additionally, also each combination of said compositions represents embodiments of the present invention.

Another particularly preferred two-component composition is B2-309 comprising I-3 II 176. According to a specific aspect, this is the binary composition that only contains these two components as active compounds.

As detailed above, components I contain centers of chirality and therefore can be present as racemic compositions, as pure enantiomers or in the two enantiomers of a component I they can be present in any ratio (S) :( R) .

According to particular embodiments of the invention, the respective component I is present as the (S) -enantiomer. Specific two-component compositions comprising the (S) -enantiomer of the respective component I are

Bs-59 (S) -I-3 II-27;

Bs-61 (S) -I-3 II-29.

According to a specific aspect, they are binary compositions each containing only these two components as active compounds. Additionally, also each combination of said compositions represents embodiments of the present invention.

According to particular embodiments of the invention, the respective component I is present as the (R) enantiomer. Specific two-component compositions comprising the (R) -enantiomer of the respective component I are

Br-59 (R) -I-3 II-27;

Br-61 (R) -I-3 II-29.

According to a specific aspect, they are binary compositions each containing only these two components as active compounds. Additionally, also each combination of said individualized compositions in this table represents embodiments of the present invention.

According to a further aspect, the present invention relates to three-component compositions, that is, compositions comprising component I, that is, a compound I-3, a component II as detailed above and a component III.

According to one embodiment, component III is selected from groups L1 to L6 or any preferred subgroup thereof as detailed above.

According to a further embodiment, component III is selected from groups L1a to L6a or any preferred subgroup thereof:

L1a) Microbial pesticides with fungicidal, bactericidal, viricidal and / or activating activity of plant defenses: Ampelomyces quisqualis M-10 (L.1.1), Aspergillus flavus NRRL 21882 (L1.2), Aureobasidium pullulans DSM 14940 (L1. 3), A. pullulans DSM 14941 (L.1.4), Bacillus altitudinis 41KF2b (L.1.5), Bacillus amyloliquefaciens AP-136 (L.1.6), B. amyloliquefaciens AP-188 ( ^l .1.7), B. amyloliquefaciens AP -218 (L.1.8), B. amyloliquefaciens AP-219 (L.1.9), B. amyloliquefaciens AP-295 ( ^l .1.10), B. amyloliquefaciens IN937a (L.1.11), B. amyloliquefaciens IT-45 (l .1.12), B. amyloliquefaciens ssp. plantarum D747 (L.1.13), B. amyloliquefaciens ssp. plantarum FZB24 (L.1.14), B. amyloliquefaciens ssp. plantarum FZB42 (L.1.15), B. amyloliquefaciens ssp. plantarum GB03 (L.1.16), B. amyloliquefaciens ssp. plantarum MBI600 (NRRL B-50595) (L.1.17), B. amyloliquefaciens ssp. plantarum QST-713 (L.1.18), B. amyloliquefaciens ssp. plantarum TJ1000 (L.1.19), B. mojavensis AP-209 (L.1.20), B. mycoides AQ726 (L.1.21), B. mycoides strain J (L.1.22), B. pumilus INR-7 (L. 1.23), B. pumilus KFP9F (L.1.24), B. pumilus QST 2808 (L.1.25), B. pumilus GHA 180 (L.1.26), B. simplex ABU 288 (L.1.27), B. solisalsi AP -217 (L.1.28), B. subtilis CX-9060 (L.1.29), B. subtilis FB17 (L.1.30), B. subtilis GB07 (L.1.31) Candida oleophila I-82 (L.1.32), C. oleophila O (L.1.33), C. saitoana (L.1.34), Clavibacter michiganensis (bacteriophages) (L.1.35), Coniothyrium minitans CON / M / 91-08 (L.1.36), Cryphonectria parasitica (L. 1.37), Cryptococcus albidus (L.1.38), Dilophosphora alopecuri (L.1.39), Fusarium oxisporum (L.1.40), Clonostachys rosea f. catenulata J1446 (L.1.41), Gliocladium roseum 321U (l .1.42), Metschnikowia fructicola NRRL Y-30752 (L.1.43), Microdochium dimerum (L.1.44), Microsphaeropsis ochracea P130A (L.1.45), Muscodor albus QST 20799 (L.1.46), Muscodor albus SA-13 (L.1.47), Paenibacillus alvei NAS6G6 (L.1.48), Paenibacillus polymyxa PKB1 (L.1.49), Pantoea agglomerans E325 (L.1.90), Pantoea vagans C9-1 ( L.1.50), Penicillium bilaiaeATCC 22348 (L.1.51), P. bilaiae ATCC 20851 (L.1.52), Penicillium bilaiae ATCC 18309 (L.1.53), Phlebiopsis gigantea (L.1.54), Pichia anomala WRL-76 (L 1.55), Pseudomonas sp. Proradix (L.1.56), Pseudomonas chloraphis MA 342 (L.1.57), P. fluorescens A506 (L.1.58), P. fluorescens CL 145A (L.1.91), P. fluorescens NCIB 12089 (L.1.92), P. fluorescens Pf-5 (L.1.93), P. fluorescens WCS 374 (L.1.94), P. fluorescens ATCC 13525 (L.1.95), P. fluorescens CHAO (L.1.96) , P. putida ATCC 202153 (L.1.97), Pseudozyma flocculosa PF-A22 UL (L.1.59), Pythium oligandrum DV 74 (L.1.60), Sphaerodes mycoparasitica SMCD2220 (L.1.61), Streptomyces griseoviridis K61 (L.1.62 ), S. lydicus WYEC 108 (L.1.63), S. violaceusniger XL-2 (L.1.64), S. violaceusniger YCED-9 (L.1.65), Talaromyces flavus V117b (L.1.66), Trichoderma asperellum T34 ( l.1.67), T. asperellum SKT-1 (L.1.68), T. asperellum ICC 012 (L.1.69), T. atroviride LC52 (L.1.70), T. atroviride CNCM I-1237 (L.1.71) , T. fertile JM41R (L.1.72), T. gamsii ICC 080 (L.1.73), T. harmatum TH 382 (L.1.74), T. harzianum T-35 (L.1.75), T. harzianum T- 22 (L.1.76), T. harzianum T-39 (L.1.77); mixture of T. harzianum ICC012 and T. viride ICC080 (L.1.78); T. polysporum (L.1.79); T. stromaticum (L.1.80), T. virens GI-3 (L.1.81), T. virens G-41 (L.1.82), T. virens GL-21 (L.1.83), T. virens G- 41 (L.1.84), T. viride TV1 (L.1.85), Typhula phacorrhiza 94671 (L.1.86), Ulocladium oudemansii HRU3 (L.1.87), Verticillium dahlia (L.1.88), zucchini yellow mosaic virus ( avirulent strain) (L.1.89);

L2a) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or activator of plant defenses activity: chitosan (hydrolyzed) (L.2.1), harpin protein (L.2.2), laminarin (L.2.3), fish oil de Menhaden (L.2.4), natamycin (L.2.5), Plum pox virus coat protein (L.2.6), potassium bicarbonate (L.2.7), Reynoutria sachalinensis extract (L.2.8), salicylic acid ( L.2.9), potassium or sodium bicarbonate (L.2.10), tea tree oil (L.2.11);

L3a) Microbial pesticides with insecticidal, acaricidal, molluscid and / or nematicidal activity: Agrobacterium radiobacter K1026 (L.3.1), A. radiobacter K84 (L.3.2), Bacillus firmus I-1582 (L.3.3); strains of B. thuringiensis ssp. aizawai: ABTS-1857 (L.3.4), SAN 401 I (L.3.5), ABG-6305 (L.3.6) and ABG-6346 (L.3.7); B. t. ssp. israelensis AM65-52 (L.3.8), B. t. ssp. israelensis SUM-6218 (L.3.9), B. t. ssp. galleriae SDS-502 (L.3.10), B. t. ssp. kurstaki EG 2348 (l.3.11), B. t. ssp. kurstaki SB4 (L.3.12), B. t. ssp. kurstaki ABTS-351 (HD-1) (L.3.13), Beauveria bassiana ATCC 74040 (L.3.14), B. bassiana GHA (L.3.15), B. bassiana H123 (L.3.16), B. bassiana DSM 12256 (L.3.17), B. bassiana PPRI 5339 (L.3.18), B. brongniartii (L.3.19), Burkholderia sp. A396 (L.3.20), Chromobacterium subtsugae PRAA4-1 (L.3.21), Cydia pomonella granulosis virus V22 (L.3.22), Cydia pomonella granulosis virus V1 (L.3.23), Cryptophlebia leucotreta granulovirus (CrleGV) (L. 3.57), Flavobacterium sp. H492 (L.3.60), Helicoverpa armigera nucleopolyhedrovirus (HearNPV) (L.3.58), Isaria fumosorosea Apopka-97 (L.3.24), Lecanicillium longisporum KV42 (L.3.25), L. longisporum KV71 (L.3.26), L. muscarium KV01 (L.3.27), Metarhizium anisopliae FI-985 (L.3.28), M. anisopliae FI- 1045 (L.3.29), M. anisopliae F52 (L.3.30), M. anisopliae ICIPE 69 (L 3.31), M. anisopliae var. acridum IMI 330189 (L.3.32); Nomuraea rileyi strains: SA86101 (L.3.33), GU87401 (L.3.34), SR86151 (L.3.35), CG128 (L.3.36) and VA9101 (L.3.37); Paecilomyces fumosoroseus FE 9901 (L.3.38), P. lilacinus 251 (L.3.39), P. lilacinus DSM 15169 (L.3.40), P. lilacinus BCP2 (L.3.41), Paenibacillus popilliae Dutky-1940 (NRRL B- 2309 = ATCC 14706) (L.3.42), P. popilliae Dutky 1 (L.3.43), P. popilliae KLN 3 (L.3.56), Pasteuria sp. Ph3 (L.3.44), Pasteuria sp. ATCC PTA-9643 (L.3.45), Pasteuria sp. ATCC SD-5832 (L.3.46), P. nishizawae Pn1 (L.3.46), P. penetrans (L.3.47), P. ramosa (L.3.48), P. sp. Pr-3 (L.3.49), P. thornea (L.3.50), P. usgae (L.3.51), Pseudomonas fluorescens CL 145A (L.3.52), Spodoptera littoralis nucleopolyhedrovirus (SpliNPV) (L.3.59), Steinernema carpocapsae (L.3.53), S. feltiae (L.3.54), S. kraussei L137 (L.3.55);

L4a) Biochemical pesticides with insecticidal, acaricidal, molluscid, pheromone and / or nematicidal activity: L-carvone (L.4.1), citral (L.4.2), acetate (E, Z) -7,9-dodecadien-1-yl (L.4.3), ethyl formate (L.4.4), (E, Z) -2,4-ethyl decadienoate (pear ester) (L.4.5), (Z, Z, E) -7, 11,13-hexadecatrienal (L.4.6), heptyl butyrate (L.4.7), isopropyl myristate (L.4.8), cis-jasmone (L.4.9), lavanulyl senecioate (L.4.10), 2-methyl 1-butanol (L.4.11), methyl eugenol (L.4.12), methyl jasmonate (L.4.13), (E, Z) -2,13-octadecadien-1-ol (L.4.14), (E, Z) -2,13-octadecadien-1-ol acetate (l.4.15), (E, Z) -3,13-octadecadien-1-ol (L.4.16), R-1-octen-3-ol ( L.4.17), pentatermanone (L.4.18), potassium silicate (L.4.19), sorbitol actanoate (L.4.20), (E, Z, Z) -3,8,11-tetradecatrienyl acetate (L. 4.21), (Z, E) -9,12-tetradecadien-1-yl acetate (L.4.22), Z-7-tetradecen-2-one (L.4.23), Z-9-tetradecen-1 acetate -yl (L.4.24), Z-11-tetradecenal (L.4.25), Z-11-tetradecen-1 -ol (L.4.26), extract of A black cacia (L.4.27), grapefruit seed extract and pulp (L.4.28), Chenopodium ambrosiodes extract (L.4.29), catnip oil (L.4.30), Neem oil (L.4.31), Quillay extract (L.4.32), Tagetes oil (L.4.33);

L5a) Microbial pesticides with plant stress reducing activity, plant growth regulator, plant growth promoter and / or yield enhancer: Azospirillum amazonense BR 11140 (SpY2) (L.5.1), A. brasilense Ab -V5 (L.5.74), A. brasilense Ab-V6 (L.5.75), A. brasiiense AZ39 (L.5.2), A. brasilense xOh (L.5.3), A. brasilense Sp245 (BR 11005) (L .5.4), A. brasilense bR 11002 (L.5.5), A. lipoferum BR 11646 (Sp31) (L.5.6), A. irakense (L.5.7), A. halopraeferens (L.5.8), Bradyrhizobium sp. PNL01 (L.5.9), B. sp. (Arachis) CB1015 (L.5.10), B. sp. (Arachis) USDA 3446 (L.5.11), B. sp. (Arachis) SEMIA 6144 (L.5.12), B. sp. (Arachis) SEMIA 6462 (L.5.13), B. sp. (Arachis) SEMIA 6464 (L.5.14), B. sp. (Vigna) (L.5.15), B. elkanii SEMIA 587 (L.5.16), B. elkanii SEMIA 5019 (L.5.17), B. elkanii U-1301 (L.5.18), B. elkanii U-1302 ( L.5.19), B. elkanii USDA 74 (L.5.20), B. elkanii USDA 76 (L.5.21), B. elkanii USDA 94 (L.5.22), B. elkanii USDA 3254 (L.5.23), B . japonicum 532c (L.5.24), B. japonicum CPAC 15 (L.5.25), B. japonicum E-109 (L.5.26), B. japonicum G49 (L.5.27), B. japonicum TA-11 (L .5.28), B. japonicum USDA 3 (L.5.29), B. japonicum USDA 31 (L.5.30), B. japonicum USDA 76 (L.5.31), B. japonicum USDA 110 (L.5.32), B. japonicum uSDa 121 (L.5.33), B. japonicum UsDA 123 (L.5.34), B. japonicum USDA 136 (L.5.35), B. japonicum SEMIA 566 (L.5.36), B. japonicum SEMIA 5079 (L. 5.37), B. japonicum SEMIA 5080 (L.5.38), B. japonicum WB74 (L.5.39), B. liaoningense (L.5.40), B. lupini LL13 (L.5.41), B. lupini WU425 (L. 5.42), B. lupini WSM471 (L.5.43), B. lupini WSM4024 (L.5.44), Glomus intraradices RTI-801 (L.5.45), Mesorhizobium sp. WSM1271 (L.5.46), M. sp. WSM1497 (L.5.47), M. ciceri CC1192 (L.5.48), M. huakii (L.5.49), M. loti CC829 (L.5.50), M. loti SU343 (L.5.51), Rhizobium leguminosarum bv. Phaseoli RG-B10 (L.5.52), RI bv. trifolii RP113-7 (L.5.53), RI bv. trifolii 095 (L.5.57), RI bv. trifolii TA1 (L.5.58), RI bv. trifolii CC283b (L.5.59), RI bv. trifolii CC275e (L.5.60), RI bv. trifoliiCB782 (L.5.61), RI bv. trifolii CC1099 (L.5.62), RI bv. trifolii WSM1325 (L.5.63), RI bv. viciae SU303 (L.5.64), RI bv. viciae WSM1455 (L.5.65), RI bv. viciae P1NP3Cst (L.5.66), RI bv. viciae RG-P2 (L.5.67), R. tropici PRF 81 (L.5.68), R. tropici SEMIA 4077 (L.5.69), R. tropici CC511 (L.5.70), Sinorhizobium meliloti RCR2011 (L.5.71) , S. meliloti NRG185 (L.5.72), S. meliloti RRI128 (L.5.73);

L6a) Biochemical pesticides with activity to reduce plant stress, regulate plant growth and / or enhance plant yield: abscisic acid (L.6.1), aluminum silicate (kaolin) (L.6.2), 3 -decen-2-one (L.6.3), formononectin (L.6.4), genistein (L.6.5), hesperetin (L.6.6), homobrassinolide (L.6.7), humates (L.6.8), methyl jasmonate (L.6.9), cis-jasmone (L.6.10), lysophosphatidylethanlamine (L.6.11), naringenin (L.6.12), polymeric polyhydroxy acid (L.6.13), salicylic acid (L.6.14), Ascophyllum nodosum extract ( Norway seaweed, brown seaweed) (L.6.15) and Ecklonia maxima (seaweed) extract (L.6.16).

According to yet another embodiment, component III is selected from groups La to Lf or any preferred subgroup thereof:

La) Microbial pesticides with fungicidal, bactericidal, virucidal and / or activator of the defenses of plants selected from: Bacillus altudinis, Bacillus amyloliquefaciens, Bacillus amyloliquefaciens ssp. plantarum MBI 600 (II-27), B. amyloliquefaciens ssp. plantarum D747, B. megaterium, B. mojavensis (II-28), B. mycoides, B. pumilus iNr-7 (II-29), B. pumilus GHA 180, B. simplex (II-30), B. solisalsi (II-31), Bacillus subtilis, Burkholderia sp., Clavibacter michiganensis (bacteriophages) (II-32), Gliocladium roseum (II-33), Microsphaeropsis ochracea, Muscodor albus, Paenibacillus alvei, Paenibacillus polymyxa (II-34), Pantoea agglomerans (II-35), Pantoea vagans, Penicillium bilaiae, Pseudomonas sp., Pseudomonas chloraphis, P. fluorescens, Sphaerodes mycoparasitica (II-36), Streptomyces lydicus (II-37), S. violaceusniger (II-38), Trichoderma fertile JM41R (II-39), Typhula phacorrhiza (II-40), Verticillium dahlia (II-42), zucchini yellow mosaic virus (avirulent strain);

Lb) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or activating activity of plant defenses selected from: harpin protein, laminarin, jasmonic acid (II-43) or salts or derivatives thereof, laminarin, fish oil of Menhaden, Natamycin, Plum pox virus coat protein, sodium or potassium bicarbonate, salicylic acid, tea tree oil;

Lc) Microbial pesticides with insecticidal, acaricidal, molluscid and / or nematicidal activity selected from: Agrobacterium radiobacter, Bacillus cereus, Bacillus firmus (II-44), B. thuringiensis ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, Beauveria bassiana (II-45), Beauveria brongniartii, Burkholderia sp., Chromobacterium subtsugae, Cydia pomonella granulosis virus, Isaria fumosorosea, Lecanicillium longisporum, L. muscarium (formerly Verticillium lecanii), Metarhizium (II-46) M. anisopliae var. anisopliae, M. anisopliae var. acridum, Paecilomyces fumosoroseus, P. lilacinus, Paenibacillus popilliae, Pasteuria spp., P. nishizawae, P. reneformis, P. usagae, Pseudomonas fluorescens, Pseudomonas putida, Steinernema feltiae, Steinernema kraussei, Streptomcesbuslavces;

Ld) Biochemical pesticides with insecticidal, acaricidal, molluscid, pheromone and / or nematicidal activity selected from: L-carvone, citral, acetate (E, Z) -7,9-dodecadien-1-yl, ethyl formate, (E, Z) Ethyl -2,4-decadienoate (pear ester), (Z, Z, E) -7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, lanylyl senecioate, 2-methyl 1- butanol, methyl eugenol, methyl jasmonate, (E, Z) -2,13-octadecadien-1-ol, (E, Z) -2,13-octadecadien-1-ol acetate, (E, Z) -3, 13- octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E, Z, Z) -3,8,11-tetradecatrienyl acetate, (Z , E) -9,12-tetradecadien-1-yl, Z-7-tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11-tetradecen-1- ol, Black Acacia extract, Grapefruit seed extract and pulp, Chenopodium ambrosiodae extract, Catnip oil, Neem oil, Quillay extract (II-47), Tagetes oil;

Le) Microbial pesticides with plant stress reducing activity, plant growth regulator, plant growth promoter and / or performance enhancer selected from: Azospirillum amazonense, A. brasilense (II-48), A. lipoferum , A. irakense, A. halopraeferens, Bradyrhizobium sp. (II-49), B. japonicum (II-50), B. elkanii, B. lupini, B. liaoningense, Delftia acidovorans, Glomus intraradices, Mesorhizobium sp. (II-51), M. ciceri, M. huakii, M. loti, Paenibacillus alvei, Penicillium bilaiae (II-52), Rhizobium leguminosarum bv. phaseoli (II-53), R. I. trifolii, R. I. bv. viciae (II-54), R. tropici, Sinorhizobium meliloti (II-55);

Lf) Biochemical pesticides with plant stress reducing activity, plant growth regulator and / or plant performance enhancer selected from: abscisic acid, aluminum silicate (kaolin), 3-decen-2-one, homobrassinlide , humates, indole-3-acetic acid, lysophosphatidylethanlamine, polymeric polyhydroxy acid, Ascophyllum nodosum extract (Norwegian seaweed, brown seaweed) and Ecklonia maxima extract (seaweed).

According to yet another embodiment, component III is selected from groups La-1) to Lf-1) or any preferred subgroup thereof:

La-1) Microbial pesticides with fungicidal, bactericidal, viricidal and / or activating activity of plant defenses: Bacillus altitudinis 41KF2b, Bacillus amyloliquefaciens AP-136, B. amyloliquefaciens AP-188, B. amyloliquefaciens AP-218, B. amyloliquefaciens AP-219, B. amyloliquefaciens AP-295, B. amyloliquefaciens IN937a, B. amyloliquefaciens IT-45, B. amyloliquefaciens ssp. plantarum D747, B. amyloliquefaciens ssp. plantarum MBI600 (NRRL B-50595), B. amyloliquefaciens ssp. plantarum TJ1000, B. mojavensis AP-209, B. mycoides AQ726, B. mycoides strain J, B. pumilus INR-7, B. pumilus GHA 180, B. simplex ABU 288, B. solisalsi AP-217, B. subtilis CX-9060, B. subtilis FB17, B. subtilis GB07, Clavibacter michiganensis (bacteriophages), Gliocladium roseum 321U, Microsphaeropsis ochracea P130A, Muscodor albus QST 20799, Muscodor albus SA-13, Pamyen agillus alveiBibacillus6, Pamyen PKibacillus alveiB6Gglome6 E325, Pantoea vagans C9-1, Penicillium bilaiae ATCC 22348, P. bilaiae A ^t C ^c 20851, Penicillium bilaiae ATCC 18309, Phlebiopsis gigantea, Pichia anomala WRL-76, Pseudomonas sp. Proradix, Pseudomonas chloraphis MA 342, P. fluorescens A506, P. fluorescens CL 145A, P. fluorescens NCIB 12089, P. fluorescens Pf-5, P. fluorescens WCS 374, P. fluorescens ATCC 13525, P. fluorescens CHAO, P. putida ATCC 202153, Sphaerodes mycoparasitica SMCD2220, S. lydicus WYEC 108, S. violaceusniger XL-2, S. violaceusniger YCED-9, Trichoderma fertile JM41R, Typhula phacorrhiza 94671, Verticillium dahlia, zucchini yellow mosaic virus (strain);

Lb-1) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or activating activity of plant defenses: harpin protein, laminarin, Menhaden's fish oil, natamycin, coat protein of Plum pox virus, potassium bicarbonate, acid salicylic, sodium or potassium bicarbonate, tea tree oil;

Lc-1) Microbial pesticides with insecticidal, acaricidal, molluscid and / or nematicidal activity: Agrobacterium radiobacter K1026, A. radiobacter K84, Bacillus firmus I-1582; strains of B. thuringiensis ssp. aizawai: ABTS-1857, SAN 401 I, ABG-6305 and ABG-6346; B. t. ssp. israelensis AM65-52, B. t. ssp. israelensis SUM-6218, B. t. ssp. Galleriae SDS-502, B. t. ssp. kurstaki EG 2348, B. t. ssp. kurstaki SB4, B. t. ssp. kurstaki ABTS-351 (HD-1), Beauveria bassiana ATCC 74040, B. bassiana GHA, B. bassiana H123, B. bassiana Ds M 12256, B. bassiana Pp Ri 5339, B. brongniartii, Burkholderia sp. A396, Chromobacterium subtsugae PRAA4-1, Cydia pomonella granulosis virus V22, Cydia pomonella granulosis virus V1, Cryptophlebia leucotreta granulovirus (CrleGV), Flavobacterium sp. H492, Helicoverpa armigera nucleopolyhedrovirus (HearNPV), Isaria fumosorosea Apopka-97, Lecanicillium longisporum KV42, L. longisporum KV71, L. muscarium KV01, Metarhizium anisopliae FI-985, M. anisopliae F52, M. anisopliae, M. anisopliae FI-1045, M. anisopliae FI-1045, M. anisopliae FI-1045, anisopliae ICIPE 69, M. anisopliae var. acridum IMI 330189; Nomuraea rileyi strains: SA86101, GU87401, SR86151, CG128 and VA9101; Paecilomyces fumosoroseus FE 9901, P. lilacinus 251, P. lilacinus DSM 15169, P. lilacinus BCP2, Paenibacillus popilliae Dutky-1940 (NRRL B-2309 = ATCC 14706), P. popilliae Dutky 1, P. popilliae KLN 3, Pasteuria sp . Ph3, Pasteuria sp. ATCC PTA-9643, Pasteuria sp. ATCC SD-5832, P. nishizawae Pn1, P. penetrans, P. ramosa, P. sp. Pr-3, P. thornea, P. usgae, Pseudomonas fluorescens CL 145A, Spodoptera littoralis nucleopolyhedrovirus (SpliNPV), Steinernema carpocapsae, S. feltiae, S. kraussei L137;

Ld-1) Biochemical pesticides with insecticidal, acaricidal, molluscid, pheromone and / or nematicidal activity: L-carvone, citral, acetate (E, Z) -7,9-dodecadien-1-yl, ethyl formate, (E, Z) Ethyl -2,4-decadienoate (pear ester), (Z, Z, E) -7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, cis-jasmone, lavender lavender, 2 -methyl 1-butanol, methyl eugenol, methyl jasmonate, (E, Z) -2,13-octadecadien-1-ol, (E, Z) -2,13-octa-decadien-1-ol acetate, (E , Z) - 3,13-octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E, Z, Z) -3,8,11- acetate tetradecatrienyl, (Z, E) -9,12-tetradecadien-1-yl acetate, Z-7-tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z- 11-tetradecen-1-ol, Black Acacia extract, Grapefruit seed extract and pulp, Chenopodium ambrosiodes extract, Catnip oil, Neem oil, Quillay extract, Tagetes oil;

Le-1) Microbial pesticides with plant stress reducing activity, plant growth regulator, plant growth promoter and / or performance enhancer: Azospirillum amazonense BR 11140 (SpY2), A. brasilense Ab-V5, A. brasilense Ab-V6, A. brasilense AZ39, A. brasilense XOH, A. brasilense Sp245 (BR 11005), A. brasilense BR 11002, A. lipoferum BR 11646 (Sp31), A. irakense, A. halopraeferens, Bradyrhizobium sp. PNL01, B. sp. (Arachis) CB1015, B. sp. (Arachis) USDA 3446, B. sp. (Arachis) SE ^m I ^a 6144, B. sp. (Arachis) SEMIA 6462, B. sp. (Arachis) SEMIA 6464, B. sp. (Vigna), B. elkanii SEMIA 587, B. elkanii SEMIA 5019, B. elkanii U-1301, B. elkanii U-1302, B. elkanii USDA 74, B. elkanii USDA 76, B. elkanii USDA 94, B. elkanii USDA 3254, B. japonicum 532c, B. japonicum CPAC 15, B. japonicum E-109, B. japonicum G49, B. japonicum TA-11, B. japonicum USDA 3, B. japonicum USDA 31, B. japonicum USDA 76, B. japonicum USDA 110, B. japonicum USDA 121, B. japonicum USDA 123, B. japonicum U ^s D ^a 136, B. japonicum SEMIA 566, B. japonicum SEMIA 5079, B. japonicum SEMIA 5080, B. japonicum W ^b 74, B. liaoningense, B. lupini LL13, B. lupini WU425, B. lupini WSM471, B. lupini WSM4024, Glomus intraradices RTI-801, Mesorhizobium sp. WSM1271, M. sp. WSM1497, M. ciceri CC1192, M. huakii, M. loti CC829, M. loti SU343, Rhizobium leguminosarum bv. phaseoli RG-B10, RI bv. trifolii RP113-7, RI bv. trifolii 095, RI bv. trifolii TA1, RI bv. Trifolii CC283b, RI bv. trifolii CC275e, RI bv. trifolii CB782, RI bv. trifolii CC1099, RI bv. trifolii WSM1325, RI bv. viciae SU303, RI bv. viciae WSM1455, RI bv. viciae P1NP3Cst, RI bv. viciae RG-P2, R. tropici PRF 81, R. tropici SEMIA 4077, R. tropici CC511 (L.5.70), Sinorhizobium meliloti RCR2011, S. meliloti NRG185, S. meliloti RRI128;

Lf-1) Biochemical pesticides with plant stress reducing activity, plant growth regulator and / or plant performance enhancer: abscisic acid, aluminum silicate (kaolin), 3-decen-2-one, formononectin , genistein, hesperetin, homobrassinolide, humates, methyl jasmonate, cis-jasmone, lysophosphatidylethanlamine, naringenin, polymeric polyhydroxy acid, salicylic acid, Ascophyllum nodosum extract (Norwegian seaweed, brown seaweed) and Ecklonia maxima extract (seaweed).

According to yet another embodiment, component III is selected from the following compounds:

Bacillus altitudinis (II-72) Paenibacillus alvei (II-80)

Bacillus amyloliquefaciens (II-73) Paenibacillus polymyxa (II-34)

Bacillus amyloliquefaciens ssp. Plantarum (II-27) Paenibacillus popilliae (II-81)

Pasteuria nishizawae (II-82)

Bacillus firmus (II-44) Pasteuria usgae (II-83)

Bacillus megaterium (II-74) Penicillium bilaiae (II-52)

Bacillus mojavensis (II-28) Pseudomonas chloraphis (II-84)

Bacillus mycoides (II-75) Pseudomonas fluorescens (II-85)

Bacillus pumilus (II-29) Pseudomonas putida (II-86)

Bacillus simplex (II-30) abscisic acid (II-87)

Bacillus solisalsi (II-31) harpin protein (alpha-beta) (II-88)

Bacillus subtilis (II-76) jasmonic acid or salts or derivatives thereof (II-43) Burkholderia sp. (II-77)

Coniothyrium minitans (II-78) cis-jasmona (II-89)

Paecilomyces lilacinus (II-79) methyl jasmonate (II-90)

Other particularly preferred components III are selected from:

Bacillus altitudinis 41 KF2b (II-148) Bacillus subtilis CX-9060 (II-175)

Bacillus amyloliquefaciens AP-136 (II-149) Bacillus subtilis FB17 (II-176)

Bacillus subtilis GB07 (II-177)

Bacillus amyloliquefaciens AP-188 (II-150) Burkholderia sp. A396 (II-178)

Bacillus amyloliquefaciens AP-218 (II-151) Coniothyrium minitans CON / M / 91-08 (II-179) Paecilomyces lilacinus 251 (II-180) Bacillus amyloliquefaciens AP-219 (II-152) Paecilomyces lilacinus BCP2 (II-181)

Paenibacillus alvei NAS6G6 (II-182) Bacillus amyloliquefaciens AP-295 (II-153) Paenibacillus polymyxa PKB1 (II-183) Bacillus amyloliquefaciens ssp. plantarum D747 (II-154) Paenibacilllus popilliae 14F-D80 also called K14F-0080 (II-184) Paenibacilllus popilliae KLN 3 (II-185) Bacillus amyloliquefaciens ssp. plantarum FZB24 also Pasteuria nishizawae Pn1 (II-186)

called SB3615 (II-155)

Pasteuria sp, Ph3 (II-187)

Bacillus amyloliquefaciens ssp. plantarum FZB42 (II-156) Pasteuria sp. Pr3 (II-188)

Bacillus amyloliquefaciens ssp. plantarum GB03 also called Pasteuria sp. ATCC PTA-9643 (II-189) GBO3 formerly B. subtilis (II-157)

Bacillus amyloliquefaciens ssp. plantarum MBI600 also Pasteuria usgae BL1 (II-190) named 1430, formerly B.subtilis (II-158)

Bacillus amyloliquefaciens ssp. Plantarum QST-713, Penicillium bilaiae (also called P. bilaii) formerly B. subtilis (II-159) NRRL 50162 (II- 191)

Bacillus amyloliquefaciens ssp. plantarum TJ1000, also Penicillium bilaiae (also called P. bilaii) called 1BE (II-160) NRRL 50169 (II-192)

Bacillus firmus CNCM I-1582 (II-161) Penicillium bilaiae (also called P. bilaii)

ATCC 18309 (= ATCC 74319) (II-193) Bacillus megaterium H491 (II-162) Penicillium bilaiae (also called P. bilaii)

ATCC 20851 (II-194)

Bacillus megaterium J142 (II-163) Penicillium bilaiae (also called P. bilaii)

ATCC 22348 (= ATCC 74318) (II-195) Bacillus megaterium M018 (II-164) Pseudomonas fluorescens A506 (II-196)

Pseudomonas fluorescens ATCC 13525 (II-197)

Bacillus mojavensis AP-209 (II-165) Pseudomonas fluorescens CHAO (II-198) Bacillus mojavensis SR11 (II-166)

Bacillus mycoides AQ726 (II-167) Pseudomonas fluorescens CL 145A (II-199) Bacillus mycoides J also called BmJ (II-168) Pseudomonas fluorescens NCIB 12089 (II-200) Bacillus pumilus GB34 (II-169)

Bacillus pumilus GHA 180 (II-170) Pseudomonas fluorescens Pf-5 (II-201) Bacillus pumilus INR-7 also called BU F22 and BU-F33 Pseudomonas fluorescens WCS374 (II-202) (II-171)

Bacillus pumilus KFP9F (II-172)

Bacillus pumilus QST 2808 (II-173) Pseudomonas putida ATCC 202153 (II-203) Bacillus simplex ABU 288 (II-174)

According to the present invention, it may be preferred that the three-component compositions comprise in addition to component I and component II, a component III that is to say selected from a further active compound, preferably in a synergistically effective amount. In particular, according to this embodiment, component III is selected from the following compounds from groups A ')

A ') Respiratory inhibitors

- Inhibitors of complex III at the Qo site (for example, strobilurins): azoxystrobin, coumethoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, phenaminstrobin, phenoxy-strobin / fluphenoxystrobin, fluoxastrobin, kresoxystrobin, pyroxystrobin, methomoxystrobin, methyloxystrobin , pyraoxystrobin, trifloxystrobin, pyracistrobin, pyracistrobin, picoxystrobin, orystrobin, 2- [2- (2,5-dimethylphenoxymethyl) -phenyl] -3-methoxy-acrylic acid methyl ester and 2- (2- (3- (2, 6-dichlorophenyl) -1-methyl-allylideneaminoxymethyl) -phenyl) -2-methoxyimino-N-methylacetamide, pyribencarb, triclopyricarb / chlorodincarb, famoxadone, fenamidone;

- inhibitors of complex III at the Qi site: ciazofamide, amisulbrom, [(3S, 6S, 7R, 8R) -8-benzyl-3 - [(3-acetoxy-4-methoxypyridine-2-carbonyl) amino] -6- methyl-4,9-dioxo-1,5-dioxonan-7-yl] 2-methylpropanoate, [(3S, 6S, 7R, 8R) -8-benzyl- 3 [[3- (acetoxymethoxy) -4-methoxy- pyridine-2-carbonyl] amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl] 2-methylpropanoate, [(3S, 6S, 7R, 8R) -8-benzyl-3- [(3-isobutoxycarbonyloxy-4-methoxy-pyridine-2-carbonyl) amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl] 2-methylpropanoate, [(3S, 6S, 7R , 8R) -8-benzyl-3 - [[3- (1,3-benzodioxol-5-ylmethoxy) -4-methoxy-pyridine-2-carbonyl] amino] -6-methyl-4,9-dioxo-1 , 5-dioxonan-7-yl] 2-methylpropanoate; (3S, 6S, 7R, 8R) -3 - [[(3-hydroxy-4-methoxy-2-pyridinyl) carbonyl] amino] -6-methyl-4,9-dioxo-8- (phenylmethyl) -1, 5-dioxonan-7-yl 2-methylpropanoate;

- Complex II inhibitors (for example, carboxamides): benodanyl, benzovindiflupir, bixafen, boscalid, carboxin, fenfuram, fluopyram, flutolanil, fluxapyroxad, furametpyr, isofetamid, isopyrazam, mepronil, oxycarboxin, sedaxafluflufen, pentanthiflufen, penthoflufen, penthoflufen

N- (4'-trifluoromethylthiobiphenyl-2-yl) -3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N- (2- (1,3,3-trimethyl-butyl) -phenyl) -1 , 3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- (1,1,3-trimethylindan-4-yl) pyrazole-4-carboxamide, 3- (trifluoromethyl) -1-methyl-N- (1,1,3-trimethylindan-4-yl) pyrazole-4-carboxamide, 1,3-dimethyl-N- (1,1,3-trimethylindan-4-yl) pyrazole-4-carboxamide, 3- (trifluoromethyl) -1,5-dimethyl-N- (1,1,3-trimethylindan-4-yl) pyrazole-4-carboxamide, 1,3,5-trimethyl-N- ( 1,1,3-trimethylindan-4-yl) pyrazole-4-carboxamide, N- (7-fluoro-1,1,3-trimethyl-indan-4-yl) -1,3-dimethyl-pyrazol-4 -carboxamide, N- [2- (2,4-dichlorophenyl) -2-methoxy-1-methyl-ethyl] -3- (difluoromethyl) -1-methyl-pyrazole-4-carboxamide;

- other respiration inhibitors (eg complex I, uncouplers): diflumethorim, (5,8-difluoro-quinazolin-4-yl) - {2- [2-fluoro- 4- (4-trifluoromethylpyridin-2-yloxy ) -phenyl] -ethyl} -amine; nitrophenyl derivatives: binapacryl, dinobuton, dinocap, fluazinam; ferimzone; organometallic compounds: salts of fenthin, such as fenthin acetate, fenthin chloride, or fenthin hydroxide; Amethoctradine; and silthofam;

B ') Inhibitors of sterol biosynthesis (SBI fungicides)

- Demethylase C14 inhibitors (DMI fungicides): triazoles: azaconazole, bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, diniconazole-M, epoxiconazole, fenbuconazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, micconazole, imibconazole, hexaconazole, imibconazole, micconazole, imibconazole, , paclobutrazol, penconazole, propiconazole, prothioconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triticonazole, uniconazole, 1- [re / - (2S; 3R) -3- (2-chlorophenyl) -2- (2,4- Difluorophenyl) -oxyranylmethyl] -5-thiocyanate-1H- [1,2,4] triazole, 2- [re / - (2S; 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) -oxyranylmethyl] -2H- [1,2,4] triazol-3-thiol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (l, 2,4-triazol-1-yl ) pentan-2-ol, 1- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1-cyclopropyl-2- (1,2,4-triazol-1-yl) ethanol, 2- [ 4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1 - (1,2,4-triazol-1-yl) butan-2-ol, 2- [2-chloro-4- (4-chlorophenoxy ) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluorome tyl) phenyl] -3-methyl-1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1 - (1,2,4-triazol-1-yl) propan-2-ol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -3-methyl-1- (1,2,4- triazol-1-yl) butan-2- ol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) pentan-2- ol, 2- [4- (4-fluorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) propan-2-ol; imidazoles: imazalil, pefurazoate, prochloraz, triflumizole; pyrimidines, pyridines, and piperazines: fenarimol, nuarimol, pyrifenox, triforine, [3- (4-chloro-2-fluoro-phenyl) -5- (2,4-difluorophenyl) isoxazol-4-yl] - (3-pyridyl) methanol;

- Delta14-reductase inhibitors: aldimorph, dodemorph, dodemorph-acetate, fenpropimorph, tridemorph, fenpropidine, piperaline, spiroxamine;

- 3-keto reductase inhibitors: fenhexamid;

C ') Inhibitors of nucleic acid synthesis

- phenylamides or acylamino acid fungicides: benalaxyl, benalaxyl-M, kiralaxil, metalaxyl, metalaxyl-M (mephenoxam), ofurace, oxadixyl;

- others: hymexazole, octilinone, oxolinic acid, bupirimate, 5-fluorocytosine, 5-fluoro-2- (p-tolylmethoxy) pyrimidin-4-amine, 5- fluoro-2- (4-fluorophenylmethoxy) pyrimidin-4-amine;

D ') Inhibitors of cell division and the cytoskeleton

- tubulin inhibitors, such as benzimidazoles, thiophanates: benomyl, carbendazim, fuberidazole, thiabendazole, thiophanate-methyl; triazolopyrimidines: 5-chloro-7- (4-methylpiperidin-1-yl) -6- (2,4,6-trifluorophenyl) - [1,2,4] triazolo [1,5-a] pyrimidine;

- other inhibitors of cell division: dietofencarb, etaboxam, pencycuron, fluopicolide, zoxamide, metrafenone, pyrophenone

E ') Inhibitors of amino acid and protein synthesis

- inhibitors of methionine synthesis (anilino-pyrimidines): cyprodinil, mepanipyrim, pyrimethanil;

- protein synthesis inhibitors: blasticidin-S, kasugamycin, kasugamycin hydrochloride-hydrate, mildiomycin, streptomycin, oxytetracycline, polyoxin, validamycin A;

F ') Inhibitors of signal transduction

- MAP / histidine kinase inhibitors: fluoroimid, iprodione, procymidone, vinclozolin, fenpiclonil, fludioxonil;

- G protein inhibitors: quinoxyfen;

G ') Inhibitors of lipid and membrane synthesis

- Inhibitors of phospholipid biosynthesis: edifenfos, iprobenfos, pyrazofos, isoprothiolane;

- lipid peroxidation: dichloran, quintazene, technazene, tolclofos-methyl, biphenyl, chloroneb, etridiazole;

- phospholipid biosynthesis and cell wall deposition: dimetomorph, flumorph, mandipropamide, pyrimorph, benthiavalicarb, iprovalicarb, valifenalate and N- (1- (1- (4-cyanophenyl) ethanesulfonyl) -but-2-yl) carbamic acid - (4-fluorophenyl) ester;

- compounds that affect the permeability of the cell membrane and fatty acids: propamocarb, propamocarb hydrochloride

- fatty acid amide hydrolase inhibitors: oxathiapiproline, 2- {3- [2- (1 - {[3,5-bis (difluoromethyl-1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -1 , 3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} phenyl methanesulfonate, 2- {3- [2- (1 - {[3,5-bis (difluoromethyl) -1H-pi razol-1-yl] acetyl} piperidin-4-yl) -1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -3-chlorophenyl

methanesulfonate;

H ') Inhibitors with multisite action

- inorganic active substances: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur;

- thio- and dithiocarbamates: ferbam, mancozeb, maneb, metam, metiram, propineb, thiram, zineb, ziram;

- organochlorine compounds (e.g. phthalimides, sulfa drugs, chloronitriles): anilazine, chlorothalonil, captafol, captan, folpet, diclofluanide, dichlorophen, hexachlorobenzene, pentachlorphenol and its salts, phthalide, tolylfluanide, N- (4-chloro-2-nitro-2- phenyl) -N-ethyl-4-methyl-benzenesulfonamide;

- guanidines and others: guanidine, dodyne, dodyne free base, guazatine, guazatine-acetate, iminoctadine, iminoctadinetriacetate, iminoctadin-tris (albesylate), dithianone, 2,6-dimethyl-1H, 5H- [1,4] dithiino [2 , 3-c: 5,6-c '] dipyrrole-1,3,5,7 (2H, 6H) -tetraone;

I ') Inhibitors of cell wall synthesis

- inhibitors of glucan synthesis: validamycin, polyoxin B; melanin synthesis inhibitors: pyroquilon, tricyclazole, carpropamide, dicyclomet, phenoxanil;

J ') Plant defense inducers

- acibenzolar-S-methyl, probenazole, isothianil, thiadinil, prohexadione-calcium; phosphonates: fosetyl, fosetyl-aluminum, phosphorous acid and their salts;

K ') Unknown mode of action

- bronopol, quinomethionate, cyfluphenamide, cymoxanil, dazomet, debacarb, diclomezine, diphenzoquat, diphenzoquatmethylsulfate, diphenylamine, phenpyrazamine, flumethover, flusulfamide, flutianil, metasaulprocarb, nitrapyriproline, [2-oxrothal-tolpropropyl-3,5 difluoromethyl) -1H-pyrazol-1-yl] -1- [4- (4- {5- [2- (prop-2-yn-1-yloxy) phenyl] -4,5-dihydro-1,2- oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-1-yl] ethanone, 2- [3,5-bis (difluoromethyl) -1H-pyrazol-1-yl] -1- [ 4- (4- {5- [2-fluoro-6- (prop-2-yn-1 -yloxy) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} -1,3- thiazol-2-yl) piperidin-1-yl] ethanone, 2- [3,5-bis (difluoromethyl) -1 H-pyrazol-1-yl] -1- [4- (4- {5- [2- chloro-6- (prop-2-in- 1-yloxy) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-1-yl ] ethanone, oxine-copper, proquinazide, tebufloquine, tecloftalam, triazoxide, 2-butoxy-6-iodo-3-propylchromen-4-one, N- (cyclopropylmethoxyimino- (6-difluoro-methoxy-2,3-difluoro-phenyl ) -methyl) -2-phenyl acetamide, N '- (4- (4-chloro-3-trifluoromethylphenoxy) - 2,5-dimethyl-f enyl) -N-ethyl-N-methyl formamidine, N '- (4- (4-fluoro-3-trifluoromethyl-phenoxy) -2,5-dimethylphenyl) - N-ethyl-N-methyl formamidine, N' - ( 2-methyl-5-trifluoromethyl-4- (3-trimethylsilanyl-propoxy) -phenyl) - N-ethyl-N-methyl formamidine, N '- (5-difluoromethyl-2-methyl-4- (3-trimethylsilanyl-propoxy ) -phenyl) -Netyl- N-methyl formamidine, 6-tertbutyl-8-fluoro-2,3-dimethyl-quinolin-4-yl methoxy-acetic acid ester, 3- [5- (4-methylphenyl) - 2,3-dimethyl-isoxazolidin-3-yl] -pyridine, 3- [5- (4-chloro-phenyl) -2,3-dimethyl-isoxazolidin-3-yl] -pyridine (pyrisoxazole), acid amide N - (6-methoxy-pyridi n-3-yl) cyclopropanecarboxylic, 5-chloro-1- (4,6-dimethoxy-pyrimidin-2-yl) -2-methyl-1H-benzoimidazole, 2- (4-chloro -phenyl) -N- [4- (3,4-dimethoxy-phenyl) -isoxazol-5-yl] -2-prop-2-ynyloxy-acetamide, ethyl (Z) -3-amino-2-cyano-3 -phenyl-prop-2-enoate, tert-butyl N- [6 - [[(Z) - [(1-methyltetrazol-5-yl) -phenyl-methylene] amino] oxymethyl] -2-pyridyl] carbamate (picarbutrazox ), pentyl N- [6 - [[(Z) - [(1-methyltetrazol-5-yl) -phenyl-methylene] amino] oxymethyl] -2-pyridyl ] carbamate, 2- [2 - [(7,8-difluoro-2-methyl-3-quinolyl) oxy] -6-fluorophenyl] propan-2-ol, 2- [2-fluoro-6 - [(8- fluoro-2-methyl-3-quinolyl) oxy] phenyl] propan-2-ol, 3- (5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl) quinoline, 3 - (4,4-Difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline, 3- (4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1 -yl) quinoline, 9-fluoro-2,2-dimethyl-5- (3-quinolyl) -3H-1,4-benzoxazepine;

M ') Growth regulators

abscisic acid, amidochlor, anzimidol, 6-benzylaminopurine, brassinolide, butraline, chlormequat (chlormequat chloride), choline chloride, cyclanilide, daminozide, dicegulac, dimethypine, 2,6-dimethylpuridine, ethephon, flumetralin, fluruthiaphenuron, flumetraline, fluruthiacetylidol, Gibberellic acid, inabenfide, indole-3-acetic acid, maleic hydrazide, mefluidide, mepiquat (mepiquat chloride), naphthalene acetic acid, N-6-benzyladenine, paclobutrazol, prohexadione (prohexadione-calcium), prohydrojasmon, thidiazuron, triapentenol, tributyl phosphorotritioate, 2,3-benzyladenine, triiodoinethyl acid, and triiodoxathyl acid uniconazole;

N ') Herbicides

- acetamides: acetochlor, alachlor, butachlor, dimethachlor, dimethenamide, flufenacet, mefenacet, metolachlor, metazachlor, napropamide, naproanilide, petoxamide, prethylachlor, propachlor, thenylchlor;

- amino acid derivatives: bilanaphos, glyphosate, glufosinate, sulphosate;

- aryloxyphenoxypropionates: clodinafop, cyyhalofop-butyl, fenoxaprop, fluazifop, haloxyfop, metamifop, propaquizafop, quizalofop, quizalofop-P-tefuryl;

- Bipyridyls: diquat, paraquat;

- (thio) carbamates: asulam, butylate, carbetamide, desmedipham, dimepiperate, eptam (EPTC), esprocarb, molinate, orbencarb, phenmedipham, prosulfocarb, pyributicarb, thiobencarb, triallate;

- cyclohexanediones: butroxydim, clethodim, cycloxydim, profoxydim, sethoxydim, tepraloxydim, tralkoxydim;

- dinitroanilines: benfluralin, ethalfluralin, oryzalin, pendimethalin, prodiamine, trifluralin;

- diphenyl ethers: acifluorfen, aclonifene, bifenox, diclofop, ethoxyphene, fomesaphene, lactophene, oxyfluorfen;

- hydroxybenzonitriles: bomoxynil, dichlobenyl, ioxynyl;

- imidazolinones: imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr;

- phenoxyacetic acids: clomeprop, 2,4-dichlorophenoxyacetic acid (2,4-D), 2,4-DB, dichlorprop, MCPA, MCPAthioethyl, MCPB, Mecoprop;

- pyrazines: chloridazon, flufenpyr-ethyl, flutiacet, norflurazon, pyridate;

- pyridines: aminopyralid, clopyralid, diflufenican, dithiopyr, fluridone, fluroxypyr, picloram, picolinafen, thiazopyr;

- sulfonyl ureas: amidosulfuron, azimsulfuron, bensulfuron, chlorimuron-ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, foramsulfuron, halosulfuron, mesurulfuron-methuronsulfuron, yodosulftsulfuron, methurysulfuron, methurysulfuron, methylsulfuronzos-sulfuron, prosulfuron, pyrazosulfuron, rimsulfuron, sulfometuron, sulfosulfuron, thifensulfuron, triasulfuron, tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron, 1 - ((2-chloro-6-propyl-imidazo [1,2-b] pyridazin-3-yl) - 3- (4,6-dimethoxy-pyrimidin-2-yl) urea; - triazines: amethrin, atrazine, cyanazine, dimetamethrin, etiozine, hexazinone, metamitron, metribuzine, promethrin, simazine, terbutylazine, terbutryn, triaziflam;

- ureas: chlorotoluron, daimuron, diuron, fluometuron, isoproturon, linuron, metabenzthiazuron, tebutiuron, trifludimoxazine;

- other inhibitors of acetolactate synthase: bispyribac-sodium, chloraINSlam-methyl, diclosulam, florasulam, flucarbazone, flumetsulam, metosulam, ortho-sulfamuron, penoxsulam, propoxycarbazone, pyribambenz-propyl, pyrimythribenzothyl, pyrimobacimidelide, pyrimynthinzoan-methyl, pyrimbacymium-sulfur pyroxasulfone, pyroxsulam;

- others: amicarbazone, aminotriazole, anilofos, beflubutamide, benazoline, bencarbazone, benfluresate, benzophenap, bentazone, benzobicyclone, bicyclopyrone, bromacil, bromobutide, butafenacil, butamifos, cafenstrole, cinnamon-sulphonazide, cinnamon-etherzonazone, cinnamon-sulphonazide, cinnamon-sulphonathyl, cinnamon-sulfide-emethyl , dicamba, difenzoquat, diflufenzopyr, Drechslera monoceras, endothal, etofumesate, ethobenzanid, phenoxasulfone, fentrazamide, flumyclorac-pentyl, flumioxazine, flupoxam, flurochloridone, flurtamone, indanophane, isoxamethyl, propylene glycine, isoxapanyl, propionic acid Methyl arsonic acid, naptalam, oxadiargyl, oxadiazone, oxazicyclomephone, pentoxazone, pinoxaden, pyraclonil, pyraflufen-ethyl, pyrazulfotole, pyrazoxyphene, pyrazolinate, quinoclamine, saflufenacil, sulcotrione, sulfentrazothrone, tetrabazyl ester, topoline, ethyl ester (3- [2-chloro-4-fluoro-5- (3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-2H-pyrimidine- 1-yl) -phenoxy] -pyridin-2-yloxy) -acetic, 6-amino-5-chloro-2-cyclopropyl-pyrimidine-4-carboxylic acid methyl ester, 6-chloro-3- (2-cyclopropyl acid -6-methyl-phenoxy) -pyridazin-4-ol, 4-amino-3-chloro-6- (4-chlorophenyl) -5-fluoro-pyridine-2-carboxylic acid, 4-amino-3- methyl ester chloro-6- (4-chloro-2-fluoro-3-methoxy-phenyl) -pyridine-2-carboxylic acid, and 4-amino-3-chloro-6- (4-chloro-3-dimethylamino- 2-fluoro-phenyl) -pyridine-2-carboxylic;

O ') Insecticides

- organo (thio) phosphates: acefate, azamethiphos, azinphos-methyl, chlorpyrifos, chlorpyrifos-methyl, chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoate, disulfoton, ethion, fenitrothion, fenthion, isoxathion, malathion, methamidophos, methidathion methyl parathion, mevinphos, monochotophos, oxydemeton-methyl, paraoxon, parathion, phentoate, fosalone, phosmet, phosphamidon, phorate, phoxim, pyrimiphos-methyl, profhenophos, protiophos, sulprofos, tetrachlorvinphos, terbufos, triazophos, trichlorphon;

- carbamates: alanicarb, aldicarb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, fenoxycarb, furathiocarb, methiocarb, methomyl, oxamyl, pirimicarb, propoxur, thiodicarb, triazamate;

- pyrethroids: allethrin, bifenthrin, cyfluthrin, cyhalothrin, cyyphenothrin, cypermethrin, alphacypermethrin, betacypermethrin, zeta-cypermethrin, deltamethrin, sphenvalerate, etofenprox, phenpropathrin, fenvalerate, imipmethrin, and pyrmethrin-cyprine II silafluofen, tau-fluvalinate, tefluthrin, tetramethrin, tralomethrin, transfluthrin, profluthrin, dimefluthrin;

- insect growth regulators: a) chitin synthesis inhibitors: benzoylureas: chlorfluazuron, cyramazin, diflubenzuron, flucicloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron; buprofezine, diofenolan, hexythiazox, ethoxazole, clofentazine; b) ecdysone antagonists: halofenozide, methoxyphenozide, tebufenozide, azadirachtin; c) juvenoids: pyriproxyphene, methoprene, phenoxycarb; d) lipid biosynthesis inhibitors: spirodiclofen, spiromesifene, spirotetramat;

- Nicotinic receptor agonist / antagonist compounds: clothianidin, dinotefuran, flupiradifuron, imidacloprid, thiamethoxam, nitenpyram, acetamiprid, thiacloprid, 1 -2-chloro-ti-azol-5-ylmethyl) -2-nitrimino-3,5-dimethyl- [1,3,5] triazinane;

- GABA antagonist compounds: endosulfan, ethiprole, fipronil, vaniliprole, pyrafluprole, pyriprole, 5-amino-1- (2,6-dichloro-4-methyl-phenyl) -4-sulfinamoyl-1H-pyrazole-3 acid amide -carbothioic;

- Macrocyclic lactone insecticides: abamectin, emamectin, milbemectin, lepimectin, spinosad, spinetoram; - Acaricides of the mitochondrial electron transport inhibitor (METI) I: fenazaquin, piridaben, tebufenpyrad, tolfenpyrad, flufenerim;

- METI II and III compounds: acequinocyl, fluacyprim, hydramethylnon;

- Decouplers: chlorfenapir;

- inhibitors of oxidative phosphorylation: cyhexatin, diafentiuron, fenbutatin oxide, propargite;

- molt-disrupting compounds: cryomazine;

- mixed function oxidase inhibitors: piperonyl butoxide;

- sodium channel blockers: indoxacarb, metaflumizone;

- Ryanodine receptor inhibitors: chlorantraniliprole, cyanthraniliprole, flubendiamide, N- [4,6-dichloro-2 - [(diethylambda-4-sulfanilidene) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) - 5- (trifluoromethyl) pyrazole-3-carboxamide; N- [4-chloro-2 - [(diethyl-lambda-4-sulfanylidene) -carbamoyl] -6-methyl-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole-3 -carboxamide; N- [4-chloro-2 - [(di-2-propyl-lambda-4-sulfanylidene) carbamoyl] -6-methylphenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole- 3-carboxamide; N- [4,6-dichloro-2 - [(di-2-propyl-lambda- 4-sulfanylidene) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole- 3-carboxamide; N- [4,6-dichloro-2 - [(diethyl-lambda-4-sulfanylidene) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (difluoromethyl) pyrazole-3-carboxamide; N- [4,6-dibromo-2 - [(di-2-propyl-lambda-4-sulfanylidene) carbamoyl] -phenyl] -2- (3- chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole -3-carboxamide; N- [4-chloro-2 - [(di-2-propyl-lambda-4-sulfanylidene) carbamoyl] -6-cyano-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole-3-carboxamide; N- [4,6-dibromo-2 - [(diethyl-lambda-4-sulfanylidene) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole-3-carboxamide;

- others: benclotiaz, bifenazate, cartap, flonicamid, piridalil, pymetrozine, sulfur, thiocylam, cenopyraphene, flupirazophos, cyflumetofen, amidoflumet, imiciafos, bistrifluron, pirifluquinazon and acid ester 1,1 '- [(4S, 4SaR, 4SaR , 6aS, 12R, 12aS, 12bS) -4 - [[(2-cyclopropyl-acetyl) oxy] methyl] -1,3,4,4a, 5,6,6a, 12,12a, 12bdecahydro-12-hydroxy- 4,6a, 12b-trimethyl-11-oxo-9- (3-pyridinyl) -2H, 11H-naphtho [2,1-b] pyrano [3,4-e] pyran-3,6-diyl] cyclopropane- acetic. Compounds of groups A '), B'), C '), D'), E '), F'), G '), H'), I '), J'), K '), M '), N') and O '), their preparation and their biological activity, eg against noxious fungi, pests or weeds are known. Compounds II with fungicidal activity described by common names, their preparation and their activity against harmful fungi are known (cf .: http://www.alanwood.net/pesticides/); these substances are commercially available.

The compounds described by IUPAC nomenclature, their preparation and their fungicidal activity are also known (Can. J. Plant Sci. 48 (6), 587-94, 1968; EP-A 141 317; EP-A 152031; EP-A 226917 ; EP-A 243970; EP-A 256503; EP-A 428941; EP-A 532022; EP-A 1028125; EP-A 1035122; EP-A 1201 648; EP-A 1122244, JP 2002316902; DE 19650197; DE 10021412 ; DE 102005009458; US 3,296,272; US 3,325,503; WO 98/46608; WO 99/14187; WO 99/24413; WO 99/27783; WO 00/29404; WO 00/46148; WO 00/65913; WO 01/54501; WO 01/56358; WO 02/22583; WO 02/40431; WO 03/10149; WO 03/11853; WO 03/14103; WO 03/16286; WO 03/53145; WO 03/61388; WO 03/66609; WO 03/74491; WO 04/49804; WO 04/83193; WO 05/120234; WO 05/123689; WO 05/123690; WO 05/63721; WO 05/87772; WO 05/87773; WO 06/15866; WO 06/87325; WO 06/87343; WO 07/82098; WO 07/90624, WO 11/028657, WO2012 / 168188, WO 2007/006670, WO 11/77514; WO13 / 047749, WO 10/069882, WO 13/047441, WO 03/16303, WO 09/90181, WO 13/007767, WO 13/010862, WO 13/024009 and WO 13/024010).

According to one embodiment, component III is selected from the following compounds:

Azoxystrobin (C-1) Ethaboxam (C-13)

Trifloxystrobin (C-2) DMM (C-14)

Picoxystrobin (C-3) Cyproconazole (C-15)

Pyraclostrobin (C-4) Difenoconazole (C-16)

Sedaxane (C-5) Prothioconazole (C-17)

Pentiopyrad (C-6) Flutriafol (C-18)

Penflufen (C-7) Thiabendazole (C-19)

Fluopi ram (C-8) Ipconazole (C-20)

Fluxapyroxad (C-9) Tebuconazole (C-21)

Boscalid (C-10) Triadimenol (C-50)

Oxathiapiproline (C-49) Prochloraz (C-22)

Metalaxyl (C-11) Fluquinconazole (C-23)

Metalaxyl-M (C-12) Triticonazole (C-24)

Fludioxinil (C-25) Sulfoxaflor (C-51)

Carboxin (C-26) Metiocarb (C-52)

Silthiofam (C-27) Tefluthrin (C-40)

Ziram (C-28) Bifenthrin (C-41)

Thiram (C-29) Cypermethrin (C-53)

Carbendazim (C-30) Alphacypermethrin (C-42)

Thiophanate-methyl (C-31) Spinosad (C-43)

Valifenalate (C-32) Cyantraniliprole (C-44)

Insecticides / Nematic Chlorantraniliprole (C-45)

Fipronil (C-33) Thiodicarb (C-54)

-Clotianidin (C-34) Triflumezopyrim (Mesoionic) (C-55)

Thiamethoxam (C-35) Acefate (C-46)

Acetamiprid (C-36) Chlorpyrifos (C-47)

Dinotefuran (C-37) Flupiradifurone (C-56)

Imidacloprid (C-38) Abamectin (C-48)

Thiacloprid (C-39)

Consequently, particularly preferred three-component compositions are compiled in Table T1b, in which each row corresponds to an embodiment of the compositions according to the invention, that is, a specific individualized composition. According to a specific aspect, they are ternary compositions each containing only these three components as active compounds. Additionally, also each Combination of the individualized compositions in this table represents the embodiments of the present invention.

In these three-component compositions, component I is compound I-3, component II is selected from:

Bacillus amyloliquefaciens ssp. Plantarum (II-27)

Bacillus pumilus (II-29)

and component III is selected from:

Azoxystrobin (C-1) DMM (014} Trifloxystrobin (0 2) Clproconazole {015} Picoxystrobin (C-3) Difenoconazole (C-16) Pyraclostrobin (C-4J Prothioconazole (01 7) Sedaxane (05) Flutriafol (018)

Pentiopyrad (0 6) Tlabendazole {019) Penflufen (C-7) Ipconazole {0 20} Fluopyram (0 8) Tebuconazole {0 21} Fluxapyroxad (0 9) Triadimenol (C-50) Boscalid (010} Prochloraz (0 22) Oxathiapiproline (049) Fluqulnconazo I (023) Axial metal (0 11} Triticonazole (0 24) Metalaxll-M (01 2) Fludioxinil (0 25) Ethaboxam (0 13} Carboxin ^{(0 26)}

Sllthiofam (027) Metiocarb (052)

Ziram (028) Tefluthrin (C-40)

Thiram (029) Bif erythrine (0 41) Carbendazim (0 30) Cypermethrin (053)

Tlofanato-metll (031) Alphaclpermethrin <042) Valifenalate (032) Splnosad (C-43)

I n sectl c I d a s / N em ati c Ciantraniliprole (0 44)

Fipronil (033) Chlora ntranyliprole (C-45) Clothianidin (034) Thiodicarb (054)

Tlamethoxam (035) Triflumezopyrim (Mesoionic) (055) Acetamlprid (0 36} Acetate (046)

Dlnotefuran (037) Chlorophos (C-47)

Imidacloprid (038) Flupiradifuron (0 56)

Thiacloprid (039) Abamectin (C-48)

Sulfoxaflor {0 51}

Table T1b: Three-component compositions comprising compound I-3, component II, and component III. in particular ternary compositions containing compounds 1-3, and III as only Active Ingredients.

According to another embodiment of the invention, component III is selected from the following compounds: and component III is selected from:

Azoxystrobin (C-1) Tebuconazole (C-21) Trifloxystrobin (C-2) Triadimenol (C-50) Picoxystrobin (C-3) Prochloraz (C-22) Pyraclostrobin (C-4) Fluquinconazole (C-23) Sedaxane ( C-5) Triticonazole (C-24) Pentiopyrad (C-6) Fludioxinil (C-25) Penflufen (C-7) Carboxin (C-26) Fluopyram (C-8) Silthiofam (C-27) Fluxapiroxad (C- 9) Ziram (C-28) Boscalid (C-10) Tiram (C-29) Oxatiapiproline (C-49) Carbendazim (C-30) Metalaxyl (C-11) Thiophanate-methyl (C-31) Metalaxyl-M ( C-12) Valifenalate (C-32) Etaboxam (C-13) Insecticides / Nematic

DMM (C-14) Fipronil (C-33) Cyproconazole (C-15) Clothianidin (C-34) Difenoconazole (C-16) Thiamethoxam (C-35) Prothioconazole (C-17) Acetamiprid (C-36)

Flutriafol (C-18) Dinotefuran (C-37)

Thiabendazole (C-19) Imidacloprid (C-38)

Ipconazole (C-20) Thiacloprid (C-39)

Sulfoxaflor (C-51) Chlorantraniliprole (C-45)

Methiocarb (C-52) Thiodicarb (C-54)

Tefluthrin (C-40) Triflumezopyrim (Mesoionic) (C-55)

Bifenthrin (C-41) Acefate (C-46)

Cypermethrin (C-53) Chlorpyrifos (C-47)

Alphacypermethrin (C-42) Flupiradifuron (C-56)

Spinosad (C-43) Abamectin (C-48)

Cyantraniliprole (C-44)

Consequently, other particularly preferred three-component compositions are compiled in Table T1c, in which each row corresponds to an embodiment of the compositions according to the invention, that is, a specific individualized composition. According to a specific aspect, they are ternary compositions each containing only these three components as active compounds. Additionally, also all combinations of the individualized compositions in this table represent embodiments of the present invention.

In these three-component compositions, Component I is Compound I-3, Component II is Bacillus subtilis FB17 (II-176)

and component III is selected from:

Azoxystrobin (C-1) Fludioxinil (C-25)

Trifloxystrobin (C-2) Carboxin (C-26)

Picoxystrobin (C-3) Silthiofam (C-27)

Pyraclostrobin (C-4) Ziram (C-28)

Sedaxane (C-5) Thiram (C-29)

Pentiopyrad (C-6) Carbendazim (C-30)

Penflufen (C-7) Thiophanate-methyl (C-31)

Fluopyram (C-8) Valifenalate (C-32)

Fluxapyroxad (C-9) Insecticides / Nematic

Boscalid (C-10) Fipronil (C-33)

Oxathiapiproline (C-49) Clothianidin (C-34)

Metalaxyl (C-11) Thiamethoxam (C-35)

Metalaxyl-M (C-12) Acetamiprid (C-36)

Etaboxam (C-13) Dinotefuran (C-37)

DMM (C-14) Imidacloprid (C-38)

Cyproconazole (C-15) Thiacloprid (C-39)

Difenoconazole (C-16) Sulfoxaflor (C-51)

Prothioconazole (C-17) Methiocarb (C-52) Flutriafol (C-18) Tefluthrin (C-40) Thiabendazole (C-19) Bifenthrin (C-41) Ipconazole (C-20) Cypermethrin (C-53) Tebuconazole ( C-21) Alphacypermethrin (C-42) Triadimenol (C-50) Spinosad (C-43) Prochloraz (C-22) Cyantraniliprole (C-44) Fluquinconazole (C-23) Chlorantraniliprole (C-45) Triticonazole (C- 24) Thiodicarb (C-54) Triflumezopyrim (Mesoionic) (C-55) Flupiradifuron (C-56) Acefate (C-46) Abamectin (C-48) Chlorpyrifos (C-47)

Table T1c: Three-component compositions comprising compound I-3, a component II and a component IIL in particular ternary compositions containing compounds I-3, I and III as the only active ingredients.

Table T1c Continuation:

According to a further aspect, the present invention relates to four-component compositions, that is, compositions comprising component I, that is, compound I-3, component II as defined herein, component III as defined herein. defined in this document and a component IV.

A further aspect of the invention are compositions comprising more than four active ingredients, such as, in particular, five-component compositions. In addition to the four components I, II, III and IV detailed above, these compositions of the invention comprise a component V.

Compositions comprising component I and component II biochemical pesticide selected from groups L2), L4) and L6) as defined herein can be prepared as compositions comprising in addition to the active ingredients at least one inert ingredient (auxiliary ) by the usual means, for example, by the means given for the compositions of compounds I as detailed below. With regard to the usual ingredients of such compositions, reference is made to the explanations given for the compositions containing the compounds I.

According to one embodiment, the microbial pesticides selected from groups L1), L3) and L5) encompass not only the isolated pure cultures of the respective microorganism as defined herein, but also their cell-free extract, suspensions in a broth of complete culture or as a supernatant containing a metabolite or a purified metabolite obtained from a complete culture broth of the microorganism or strain of microorganisms.

According to a further embodiment, the microbial pesticides selected from groups L1), L3 and L5) encompass not only isolated pure cultures of the respective microorganism as defined herein, but also a cell-free extract thereof or in at least one metabolite thereof, and / or a mutant of the respective microorganism having all the identifying characteristics thereof and also a cell-free extract or at least one metabolite of the mutant.

"Whole broth culture" refers to a liquid culture that contains both cells and medium. In particular, as used herein, "complete culture broth" refers to a liquid culture of a microorganism containing vegetative cells and / or spores suspended in the culture medium and optionally metabolites produced by the respective microorganism.

As used herein, "culture medium" refers to a medium that can be obtained by cultivating the microorganism in such medium, preferably a liquid broth, and that remains when cells growing in the medium are removed, for example, the supernatant that remains when cells growing in a liquid broth are removed by centrifugation, filtration, sedimentation, or other means well known in the art; comprising for example metabolites produced by the respective microorganism and secreted into the culture medium. The "culture medium" sometimes also referred to as "supernatant" can be obtained for example, by centrifugation at temperatures of about 2 to 30 ° C (more preferably at temperatures of 4 to 20 ° C) for about 10 to 60 min (more preferably about 15 to 30 min) at about 5,000 to 20,000 xg (more preferably at about 15,000 xg).

As used herein, "supernatant" refers to the liquid broth that remains when cells growing in the broth are removed by centrifugation, filtration, sedimentation, or other means well known in the art.

The term "cell-free extract" refers to an extract from the vegetative cells, spores and / or the complete culture broth of a microorganism comprising cellular metabolites produced by the respective microorganism obtainable by art-known cell disruption methods such as solvent-based (eg organic solvents such as alcohols sometimes in combination with appropriate salts), temperature-based, application of shear forces, cell disruption with an ultrasonicator. The desired extract can be concentrated by conventional concentration techniques such as drying, evaporation, centrifugation or the like. Certain washing steps using organic solvents and / or water-based media can also be applied to the crude extract preferably before use.

The term "metabolite" refers to any compound, substance or by-product produced by a microorganism (such as fungi and bacteria) that improves plant growth, plant water use efficiency, plant health, appearance of the plant or the population of beneficial microorganisms in the soil around the activity of the plant. In particular, as used herein, the term "metabolite" refers to any component, compound, substance, or by-product (including, but not limited to, small molecule secondary metabolites, polyketides, fatty acid synthase products, non-peptides). ribosomes, ribosomal peptides, proteins and enzymes) produced by a microorganism (such as fungi and bacteria, in particular the strains of the invention) that have some beneficial effect as described in this document, such as pesticidal activity or growth enhancement of plants, plant water use efficiency, plant health, plant emergence, or beneficial soil microorganism population around plant activity in this document.

As used herein, "isolated" refers to a pure microbial culture separated from its natural origin, said isolate obtained by cultivating a single microbial colony. An isolate is a pure culture derived from a heterogeneous wild population of microorganisms

The term "mutant" refers to a microorganism obtained by direct mutant selection but also includes microorganisms that have been further mutagenized or otherwise manipulated (eg, by the introduction of a plasmid). In accordance with the foregoing, embodiments include mutants, variants, and / or derivatives of the respective microorganism, both naturally-occurring and artificially induced mutants. For example, mutants can be induced by subjecting the microorganism to known mutagens, such as N-methylnitrosoguanidine, using conventional methods.

Compositions comprising cell-free extracts and / or microbial pesticide metabolites selected from groups L1), L3) and L5) as defined herein can be prepared as compositions comprising in addition to the active ingredients at least one inert ingredient by customary means, for example, by the means given for the compositions of the compounds I. With respect to the usual ingredients of such compositions, reference is made to the explanations given for the compositions containing the compounds I.

Compositions comprising at least one compound I and cells, spores and / or whole broth culture of at least one microbial pesticide selected from groups L1), L3) and L5) as defined herein, can be prepared as compositions which comprise in addition to the active ingredients at least one inert (auxiliary) ingredient by the usual means (see, for example, HD Burges: Formulation of Mycobial Biopestcides, Springer, 1998), for example, by the means given for the compositions of the Compounds I. Typical appropriate types of such compositions are suspensions, powders, sprays, pastes, granules, presses, capsules, and compositions thereof. Examples of composition types are suspensions (eg SC, ^or D, FS), capsules (eg CS, ZC), pastes, lozenges, wettable powders or powders (eg WP, Sp, WS, DP, DS ), pressed (eg BR, TB, DT), granules (eg WG, Sg, GR, FG, gG, MG), insecticidal articles (eg IN), as well as gel formulations for the treatment of plant propagation materials such as seeds (eg GF). In this document, it should be taken into account that each type of formulation or choice of auxiliary should not influence the viability of the microorganism during the storage of the composition and when it is finally applied to the soil, plant or plant propagation material. Appropriate formulations for example are mentioned in WO 2008/002371, US 6955,912, US 5,422,107.

Examples of suitable auxiliaries are, in addition to those mentioned hereinabove, stabilizers or nutrients and UV protectors. Examples of suitable auxiliaries are those mentioned above in this document, in which care must be taken that the choice and amounts of such auxiliaries do not influence the viability of microbial pesticides in the composition. Especially for bactericides and solvents, the compatibility with the respective microorganism of the respective microbial pesticide must be taken into account. Furthermore, microbial pesticide compositions may further contain stabilizers or nutrients and UV protectants.

Suitable stabilizers or nutrients are, for example, alpha-tocopherol, trehalose, glutamate, potassium sorbate, various sugars such as glucose, sucrose, lactose, and maltodextrin (H.D. Burges: Formulation of Micobial Biopestcides, Springer, 1998). Suitable UV protectors are, for example, inorganic compounds such as titanium dioxide, zinc oxide and iron oxide pigments or organic compounds such as benzophenones, benzotriazoles and phenyltriazines. The compositions, in addition to the auxiliaries mentioned for the compositions comprising the compounds I of the present invention, may optionally comprise from 0.1 to 80% of stabilizers or nutrients and from 0.1 to 10% of UV protectors.

According to the invention, the solid material (dry matter) of biopesticides (with the exception of oils such as Neem oil, Tagetes oil, etc.) are considered active components (for example, obtained after drying or evaporation extraction medium or suspension medium in the case of liquid formulations of microbial pesticides).

In accordance with the present invention, the weight ratios and percentages used herein for the biological extract such as the Quillay extract are based on the total weight of the dry content (solid material) of the respective extract or extracts.

The total weight ratios of compositions comprising at least one microbial pesticide in the form of viable microbial cells, including latent forms, can be determined using the amount of CFU of the respective microorganism to calculate the total weight of the respective active component with the following equation that 1 x 1010 CFU equals one gram of total weight of the respective active component. The colony forming unit is a measure of viable microbial cells, particularly fungal and bacterial cells. Furthermore, in this document "CFU" can also be understood as the number of individual (juvenile) nematodes in the case of nematode biopesticides (entomopathogens), such as Steinernema feltiae.

In binary compositions and compositions according to the invention the weight ratio of component I and component II generally depends on the properties of the active components used, usually it is in the range from 1: 100 to 100: 1, regularly in the range from 1:50 to 50: 1, preferably in the range from 1:20 to 20: 1, more preferably in the range from 1:10 to 10: 1, even more preferably in the range from 1: 4 to 4: 1 and in particular in the range from 1: 2 to 2: 1.

According to other embodiments of the compositions and binary compositions, the weight ratio of component I and component II is usually in the range from 1000: 1 to 1: 1, often in the range from 100: 1 to 1: 1, regularly in the range from 50: 1 to 1: 1, preferably in the range from 20: 1 to 1: 1, more preferably in the range from 10: 1 to 1: 1, even more preferably in the range from 4: 1 to 1: 1 and in particular in the range from 2: 1 to 1: 1.

According to other embodiments of the compositions and binary compositions, the weight ratio of component I and component II is usually in the range from 1: 1 to 1: 1000, often in the range from 1: 1 to 1: 100, regularly in the range from 1: 1 to 1:50, preferably in the range from 1: 1 to 1:20, more preferably in the range from 1: 1 to 1:10, even more preferably in the range from 1: 1 to 1: 4 and in particular in the range from 1: 1 to 1: 2.

According to other embodiments of the compositions and compositions, the weight ratio of component I and component II generally depends on the properties of the active components used, usually it is in the range from 1: 10,000 to 10,000: 1, regularly in the range from 1: 100 to 10,000: 1, preferably in the range from 1: 100 to 5,000: 1, more preferably in the range from 1: 1 to 1,000: 1, even more preferably in the range from 1: 1 to 500: 1 and in particular in the range from 10: 1 to 300: 1.

According to other embodiments of the compositions and compositions, the weight ratio of Component I and Component II is usually in the range from 20,000: 1 to 1:10, often in the range from 10,000: 1 to 1: 1, regularly in the the range from 5,000: 1 to 5: 1, preferably in the range from 5,000: 1 to 10: 1, more preferably in the range from 2,000: 1 to 30: 1, even more preferably in the range from 2,000: 1 to 100 : 1 and in particular in the range from 1,000: 1 to 100: 1.

According to other embodiments of the compositions and compositions, the weight ratio of component I and component II is usually in the range from 1: 20,000 to 10: 1, often in the range from 1: 10,000 to 1: 1, usually in the the range from 1: 5,000 to 1: 5, preferably in the range from 1: 5,000 to 1:10, more preferably in the range from 1: 2,000 to 1:30, even more preferably in the range from 1: 2,000 to 1 : 100 and in particular in the range from 1: 1,000 to 1: 100.

In ternary compositions, that is, compositions according to the invention comprising component I and component II and a component III, the weight ratio of component I and component II depends on the properties of the active substances used, usually it is in the range from 1: 100 to 100: 1, regularly in the range from 1:50 to 50: 1, preferably in the range from 1:20 to 20: 1, more preferably in the range from 1:10 to 10: 1 and in particular in the range from 1: 4 to 4: 1, and the weight ratio of component I and component III is usually in the range from 1: 100 to 100: 1, regularly in the range from 1:50 to 50 : 1, preferably in the range from 1:20 to 20: 1, more preferably in the range from 1:10 to 10: 1 and in particular in the range from 1: 4 to 4: 1.

If desired, other active components are added in a ratio of 20: 1 to 1:20 to component I.

These proportions are also appropriate for compositions of the invention applied by seed treatment.

For microbial pesticides II selected from groups L1), L3) and L5), the ratios by weight and / or percentages refer to the total weight of a preparation of the respective biopesticide II with at least 1 x 106 CFU / g ("units colony forming by total weight in grams "), preferably with at least 1 x 108 CFU / g, even more preferably from 1 x 108 to 1 x 1012 CFU / g of dry matter. The colony forming unit is a measure of viable microbial cells, particularly fungal and bacterial cells. Furthermore, in this document CFU can also be understood as the number of individual (juvenile) nematodes in the case of nematode biopesticides (entomopathogens), such as Steinernema feeliae.

In this document, the microbial pesticides II selected from groups L1), L3) and L5) can be supplied in any physiological state such as active or inactive. Said inactive active component can be supplied, for example, frozen, dried or lyophilized or partially dried (procedures for producing these partially dried organisms are given in WO2008 / 002371) or in the form of spores.

Microbial pesticides II selected from groups L1), L3) and L5) used as an organism in an active state can be administered in a culture medium without additives or additional materials or in combination with appropriate nutritional compositions.

According to a further embodiment, the microbial pesticides II selected from groups L1), L3) and L5) are administered and formulated in an inactive stage, more preferably in the form of spores.

The total weight ratios of the compositions in which component 3) is selected from the groups L1), L3) and L5) can be determined based on the total weight of the solid material (dry matter) of component 1) and using the amount of CFU of component 2) to calculate the total weight of component 2) with the following equation that 1 x 109 CFU equals one gram of the total weight of component 2).

According to one embodiment, the compositions, in which component 3) is selected from the groups L1), L3) and L5), comprise between 0.01 and 90% (w / w) of dry matter (solid material) of component 1) and from 1 x 105 CFU to 1 x 1012 CFU of component 2) per gram of total weight of the composition.

According to another embodiment, the compositions, in which component 3) is selected from the groups L1), L3) and L5), comprise between 5 and 70% (w / w) of dry matter (solid material) of component 1) and from 1 x 106 CFU to 1 x 1010 CFU of component 2) per gram of total weight of the composition.

According to another embodiment, the compositions, in which component 3) is selected from the groups L1), L3) and L5), comprise between 25 and 70% (w / w) of dry matter (solid material) of the component 1) and from 1 x 107 CFU to 1 x 109 CFU of component 2) per gram of total weight of the composition.

In the case of compositions comprising microbial pesticides II selected from groups L1), L3) and L5), the application rates preferably range between about 1 x 106 and 5 x 1015 (or more) CFU / ha. Preferably, the spore concentration is from about 1x107 to about 1x1011 CFU / ha. In the case of nematodes (entomopathogens) such as microbial pesticides (e.g. Steinernema feeliae), application rates preferably range from 1 x 105 to 1 x 1012 (or more), more preferably from 1 x 108 to 1 x 1011, even more preferably from 5x108 to 1x1010 individuals (eg, in the form of eggs, juveniles or any other living state, preferably in an infectious juvenile state) per ha.

In the case of compositions comprising microbial pesticides II selected from groups L1), L3) and L5), application rates with respect to plant propagation material preferably range from about 1 x 106 to 1 x 1012 (or more ) CFU / seeds. Preferably, the concentration is from about 1 x 106 to about 1 x 1011 CFU / seed. In the case of microbial pesticides III selected from groups L1), L3) and L5), application rates with respect to plant propagation material also preferably range from about 1 x 107 to 1 x 1014 (or more) CFU per 100 kg of seed, preferably 1 x 109 to about 1 x 1011 CFU per 100 kg of seed.

In the case of compositions comprising microbial pesticides II selected from groups L1), L3) and L5), the microorganisms used according to the invention can be cultured continuously or discontinuously in the batch process or in the batch or batch feeding process. repeated discontinuous feeding. A review of known culture methods can be found in Chmiel's textbook (Bioprozesstechnik 1. Einführung in die Bioverfahrenstechnik (Gustav Fischer Verlag, Stuttgart, 1991)) or in Storhas's textbook (Bioreaktoren und periphere Einrichtungen (Vieweg Verlag, Braunschweig / Wiesbaden, 1994)). The culture medium to be used must meet the requirements of the particular strains in an appropriate manner. Descriptions of culture media for various microorganisms are given in the manual "Manual of Methods for General Bacteriology" of the American Society for Bacteriology (Washington DC, USA, 1981). These culture media can be used according to the invention generally comprise one or more carbon sources, nitrogen sources, inorganic salts, vitamins and / or trace elements. The preferred sources of carbon are sugars, such as mono, di, or polysaccharides. Very good sources of carbon are, for example, glucose, fructose, mannose, galactose, ribose, sorbose, ribulose, lactose, maltose, sucrose, raffinose, starch or cellulose. Sugars can also be added to the media through complex compounds, such as molasses or other by-products of sugar refining. It may also be advantageous to add compositions from various carbon sources. Other possible sources of carbon are oils and fats such as soybean oil, sunflower oil, peanut oil and coconut oil, fatty acids such as palmitic acid, stearic acid or linoleic acid, alcohols such as glycerol, methanol or ethanol and acids organic such as acetic acid or lactic acid. Nitrogen sources are usually organic or inorganic nitrogen compounds or materials containing these compounds. Examples of nitrogen sources include ammonia gas or ammonium salts, such as ammonium sulfate, ammonium chloride, ammonium phosphate, ammonium carbonate or ammonium nitrate, nitrates, urea, amino acids, or complex nitrogen sources, such as liquor of maceration of corn, soy flour, soy protein, yeast extract, meat extract and others. Nitrogen sources can be used separately or as a composition. Inorganic salt compounds that may be present in the media include the chloride, phosphate or sulfate salts of calcium, magnesium, sodium, cobalt, molybdenum, potassium, manganese, zinc, copper and iron. As sulfur sources, inorganic sulfur-containing compounds can be used, for example sulfates, sulfites, dithionites, tetrathionates, thiosulfates, sulfides, but also organic sulfur compounds, such as mercaptans and thiols. As sources of phosphorus, phosphoric acid, potassium dihydrogen phosphate or dipotassium hydrogen phosphate or the corresponding sodium-containing salts can be used. Chelating agents can be added to the medium to keep the metal ions in solution. Especially suitable chelating agents include dihydroxyphenols, such as catechol or protocatechuate, or organic acids, such as citric acid. The culture media used also they may contain other growth factors, such as vitamins or growth promoters, including for example biotin, riboflavin, thiamine, folic acid, nicotinic acid, pantothenate and pyridoxine. Growth factors and salts often come from complex components of the medium, such as yeast extract, molasses, corn steep liquor, and the like. In addition, appropriate precursors can be added to the culture medium. The precise composition of the compounds in the medium is highly dependent on the particular experiment and must be decided individually for each specific case. Information on media optimization can be found in the textbook "Applied Microbiol. Physiology, A Practical Approach" (Publ. PM Rhodes, PF Stanbury, IRL Press (1997) eg 53-73, ISBN 0 19963577 3). Culture media can also be obtained from commercial suppliers, such as Standard 1 (Merck) or BHI (Brain Heart Infusion, DIFCO), etc. All components of the medium are sterilized, either by heating (20 min at 2.0 bar and 121 ° C) or by sterile filtration. The components can be sterilized either together or, if necessary, separately. All components of the medium can be present at the start of growth or optionally can be added continuously or by batch feeding. The temperature of the culture of the respective microorganism is usually between 15 ° C and 45 ° C, preferably 25 ° C to 40 ° C and can be kept constant or can be varied during the experiment. The pH value of the medium should be in the range from 5 to 8.5, preferably around 7.0. The pH value for growth can be controlled during growth by adding basic compounds such as sodium hydroxide, potassium hydroxide, ammonia or ammonia water or acidic compounds such as phosphoric acid or sulfuric acid. Anti-foaming agents, for example, polyglycol fatty acid esters can be used to control foaming. To maintain the stability of the plasmids, appropriate substances with selective action, eg antibiotics, can be added to the medium. Oxygen-containing gas or oxygen compositions, eg ambient air, are fed to the culture to maintain aerobic conditions. The culture temperature is normally from 20 ° C to 45 ° C. Cultivation is continued until a maximum of the desired product has been formed. This is normally accomplished within 10 hours to 160 hours. To obtain cell-free extracts, the cells can optionally be disrupted by high-frequency ultrasound, by high pressure, for example, in a French pressure cell, by osmolysis, by the action of detergents, lytic enzymes or organic solvents, by means of homogenizers or by a combination of several of the listed methods. The methodology of the present invention may further include a step of recovering individual compositions such as cell-free extracts, supernatants, metabolites, or the like. The term "recovery" includes extraction, harvesting, isolation or purification of an extract, supernatant or metabolite, for example, from whole culture broth. Recovery can be carried out according to any conventional isolation or purification method known in the art, including, but not limited to, treatment with a conventional resin (eg, anion or cation exchange resin, nonionic adsorption resin, etc. ), treatment with a conventional adsorbent (for example, activated carbon, silicic acid, silica gel, cellulose, alumina, etc.), alteration of the pH, solvent extraction (for example, with a conventional solvent such as an alcohol, acetate ethyl, hexane, and the like), distillation, dialysis, filtration, concentration, crystallization, recrystallization, pH adjustment, lyophilization, and the like. For example, the agent can be recovered from culture media by first killing microorganisms. The remaining broth is then passed through or over a cation exchange resin to remove unwanted cations and then through or over an anion exchange resin to remove unwanted inorganic anions and organic acids.

The compositions according to the invention are suitable as fungicides. They are distinguished by outstanding efficacy against a broad spectrum of phytopathogenic fungi, including soil fungi, which are derived especially from the classes Plasmodiophoromycetes, Peronosporomycetes (syn. Oomycetes), Chytridiomycetes, Zigomycetes, Ascomycetes, Basidiomycetes, and Deuteromycetes (sin. Fungomycetes (syn. Fungomycetes). imperfecti). Some are systemically effective and can be used in crop protection such as foliar fungicides, seed compost fungicides, and soil fungicides. In addition, they are suitable for controlling harmful fungi that, but are not limited to, are found in wood or plant roots.

The compositions according to the invention are particularly important in the control of a multitude of phytopathogenic fungi in various cultivated plants, such as cereals, for example wheat, rye, barley, triticale, oats or rice; beets, for example sugar beets or fodder beets; fruits, such as pips, stone fruits or berries, for example apples, pears, plums, peaches, almonds, cherries, strawberries, raspberries, blackberries or currants; legume plants, such as lentils, peas, alfalfa, or soybeans; oil plants, such as rapeseed, mustard, olives, sunflowers, coconut, cocoa beans, castor plants, oil palm, ground nuts, or soybeans; cucurbits, such as pumpkins, cucumbers, or melons; fiber plants, such as cotton, linen, hemp or jute; citrus fruits, such as oranges, lemons, grapefruits, or tangerines; vegetables, such as spinach, lettuce, asparagus, cabbage, carrots, onions, tomatoes, potatoes, cucurbits or paprika; lauraceae plants, such as avocados, cinnamon, or camphor; power plants and raw materials, such as corn, soybeans, rapeseed, sugar cane or oil palm; corn; tobacco; walnuts; coffee; tea; bananas; vines (vines of table grapes and grape juice); hop; grass; sweet leaf (also called Stevia); natural rubber plants or ornamental and forest plants, such as flowers, shrubs, broad-leaved or evergreen trees, for example conifers and on the propagation material of the plant, such as seeds, and the growing material of these plants.

Preferably, the compositions of the invention are used to control a multitude of fungi in field crops, such as potatoes, sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rapeseed, legumes, sunflowers, coffee or sugar cane; fruits; vines; ornamental; or vegetables, such as cucumbers, tomatoes, beans, or squash.

The term "plant propagation material" should be understood to indicate all generative parts of the plant, such as seeds and vegetative plant material, such as cuttings and tubers (eg potatoes), that can be used for multiplication. of the plant. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, shoots, and other parts of plants, including seedlings and young plants, that will be transplanted after germination or after emerging from the ground. These young plants can also be protected before transplantation by a total or partial treatment by immersion or pouring.

Preferably, the treatment of plant propagation materials with the components of the compositions of the invention and the compositions of the invention, respectively, is used to control a multitude of fungi in cereals, such as wheat, rye, barley and oats; rice, corn, cotton and soybeans.

The term "cultivated plants" is to be understood to include plants that have been modified by breeding, mutagenesis or genetic engineering, including, but not limited to, agricultural biotech products on the market or under development cf. http://cera-gmc.org/, see GM crops database here). Genetically modified plants are plants whose genetic material has been modified in such a way through the use of recombinant DNA techniques that, under natural circumstances, they cannot be readily obtained by crossing, mutations or natural recombination. Generally, one or more genes have been integrated into the genetic material of a genetically modified plant to improve certain properties of the plant. Such genetic modifications also include, but are not limited to, targeted post-translational modifications of protein (s), oligo or polypeptides for example, by glycosylation or polymer additions such as prenylated, acetylated or farnesylated building blocks or PEGs.

Plants that have been modified by reproduction, mutagenesis or genetic engineering, for example, have become tolerant to applications of specific classes of herbicides, such as auxin herbicides such as dicamba or 2,4-D; bleaching herbicides such as hydroxylphenylpyruvate dioxygenase (HPPD) inhibitors or phytoene desaturase (PDS) inhibitors; acetolactate synthase (ALS) inhibitors such as sulfonyl ureas or imidazolinones; enolpyruvilshikimate-3-phosphate synthase (EPSPS) inhibitors, such as glyphosate; glutamine synthetase (GS) inhibitors such as glufosinate; protoporphyrinogen-IX oxidase inhibitors; lipid biosynthesis inhibitors such as acetyl CoA carboxylase (ACCase) inhibitors; or oxinyl herbicides (ie, bromoxynil or ioxynyl) as a result of conventional breeding or genetic engineering methods. Additionally, plants have become resistant to multiple classes of herbicides through multiple genetic modifications, such as resistance to both glyphosate and glufosinate or both glyphosate and a herbicide of another class such as ALS inhibitors, HPPD inhibitors , auxin herbicides or ACCase inhibitors. These herbicide resistance technologies are for example described in Pest Managem. Sci. 61, 2005, 246; 61, 2005, 258; 61, 2005, 277; 61, 2005, 269; 61, 2005, 286; 64, 2008, 326; 64, 2008, 332; Weed Sci. 57, 2009, 108; Southern. J. Agricult. Res. 58, 2007, 708; Science 316, 2007, 1185; and references cited therein. Several cultivated plants have been made tolerant to herbicides by conventional breeding methods (mutagenesis), for example Clearfield® summer rape (Canola, BASF SE, Germany) is tolerant to imidazolinones, for example imazamox or ExpressSun® sunflowers (DuPont , USA) are tolerant of sulfonylureas, for example tribenuron. Genetic engineering methods have been used to make cultivated plants such as soybeans, cotton, corn, beets, and rapeseed tolerant to herbicides such as glyphosate and glufosinate, some of which are commercially available under the names RoundupReady® (glyphosate tolerant, Monsanto, USA), Cultivance® (imidazolinone tolerant, BASF SE, Germany) and LibertyLink® (glufosinate tolerant, Bayer CropScience, Germany).

Additionally, plants are also covered that are by using recombinant DNA techniques capable of synthesizing one or more insecticidal proteins, especially those known from the bacterial genus Bacillus, particularly from Bacillus thuringiensis, such as 8-endotoxins, for example, CryIA (b ), CryIA (c), CryIF, CryIF (a2), CryNA (b), CryIIIA, CryMIB (b1) or Cry9c; vegetative insecticidal proteins (VIP), eg VIP1, VIP2, VIP3 or VIP3A; insecticidal proteins of nematode colonizing bacteria, eg, Photorhabdus spp. or Xenorhabdus spp .; animal-produced toxins, such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins; toxins produced by fungi, such as Streptomycetes toxins, plant lectins, such as pea or barley lectins; agglutinins; proteinase inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin, or papain inhibitors; ribosome inactivating proteins (RIP), such as ricin, corn-RIP, abrin, luffin, saporin, or bryodin; steroid metabolism enzymes, such as 3-hydroxysteroid oxidase, ecdysteroid-IDP-glycosyltransferase, cholesterol oxidases, ecdysone or HMG-CoA-reductase inhibitors; ion channel blockers, such as sodium or calcium channel blockers; juvenile hormone esterase; diuretic hormone receptors (helicokinin receptors); stilben synthase, bibenzyl synthase, chitinases or glucanases. In the context of the present invention, these insecticidal proteins or toxins are to be expressly understood also as pre-toxins, hybrid proteins, truncated or otherwise modified proteins. Hybrid proteins are characterized by a new combination of protein domains (see, for example, WO 02/015701). Additional examples of such toxins or genetically modified plants capable of synthesizing such toxins are described, for example, in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/18810 and WO 03/52073. The production methods of such genetically modified plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above. These insecticidal proteins contained in genetically modified plants impart, to the plants that produce these proteins, tolerance to harmful pests of all taxonomic groups of tropods, especially to beetles (Coeloptera), two-winged insects (Diptera) and moths (Lepidoptera ) and nematodes (Nematoda). Genetically modified plants capable of synthesizing one or more insecticidal proteins, for example, are described in the publications mentioned above, and some of which are commercially available such as YieldGard® (corn cultivars that produce Cry1Ab toxin), YieldGard® Plus (corn cultivars that produce Cry1Ab and Cry3Bb1 toxins), Starlink® (corn cultivars that produce Cry9c toxin), Herculex® ^r W (corn cultivars that produce Cry34Ab1, Cry35Ab1 and the enzyme phosphinothricin-N-acetyltransferase [PAT]) ; NuCOTN® 33B (cotton cultivars producing Cry1Ac toxin), Bollgard® I (cotton cultivars producing Cry1Ac toxin), Bollgard® II (cotton cultivars producing Cry1Ac and Cry2Ab2 toxins); VIPCOT® (cotton cultivars that produce a VIP toxin); NewLeaf® (potato cultivars that produce Cry3A toxin); Bt-Xtra®, NatureGard®, KnockOut®, BiteGard®, Protecta®, Bt11 (for example, Agrisure® CB) and Bt176 from Syngenta Seeds SAS, France, (corn cultivars producing Cry1Ab toxin and PAT enzyme), MIR604 from Syngenta Seeds SAS, France (corn cultivars producing a modified version of Cry3A toxin, cf WO 03/018810), MON 863 from Monsanto Europe SA, Belgium (corn cultivars producing Cry3Bb1 toxin), Monsanto IPC 531 Europe SA, Belgium (cotton cultivars producing a modified version of Cry1Ac toxin) and 1507 from Pioneer Overseas Corporation, Belgium (corn cultivars producing Cry1 F toxin and PAT enzyme).

Additionally, plants are also covered that through the use of recombinant DNA techniques are capable of synthesizing one or more proteins to increase the resistance or tolerance of those plants to bacterial, viral or fungal pathogens. Examples of such proteins are so-called "pathogenesis-related proteins" (PR proteins, see eg EP-A 392 225), plant disease resistance genes (eg potato cultivars, expressing resistance genes that act against Phytophthora infestans derived from the wild potato Solanum bulbocastanum) or T4-lysozyme (for example, potato cultivars capable of synthesizing these proteins with greater resistance against bacteria such as Erwinia amylvora). The production methods of such genetically modified plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above.

Additionally, plants are also covered that are through the use of recombinant DNA techniques capable of synthesizing one or more proteins to increase productivity (for example, biomass production, grain yield, starch content, oil content, or protein content. ), tolerance to drought, salinity or other environmental factors limiting growth or tolerance to pests and fungal, bacterial or viral pathogens of these plants.

Additionally, plants that contain through the use of recombinant DNA techniques a modified amount of content substances or new content substances are also covered, specifically to improve human or animal nutrition, for example, oil crops that produce omega-3 fatty acids. long-chain health-promoting or unsaturated omega-9 fatty acids (eg, Nexera® rapeseed, DOW Agro Sciences, Canada).

Additionally, plants that contain by using recombinant DNA techniques a modified amount of content substances or new content substances are also covered, specifically to improve the production of raw material, for example, potatoes that produce higher amounts of amylopectin ( eg Amflora® potato, BASF SE, Germany).

The compositions are particularly suitable for controlling the following plant diseases:

Albugo spp. (white rust) on ornamental plants, vegetables (eg A. candida) and sunflowers (eg A. tragopogonis); Alternaria spp. (Alternaria leaf spot) on vegetables, rape (A. brassicola or brassicae), sugar beet (A. tenuis), fruits, rice, soybeans, potatoes (for example, A. solanior A. alternata), tomatoes (for example, A. solanior A. alternata) and wheat; Aphanomyces spp. in sugar beets and vegetables; Ascochyta spp. in cereals and vegetables, for example, A. tritici (anthracnose) in wheat and A. hordei in barley; Bipolaris and Drechslera spp. (teleomorph: Cochliobolus spp.), eg southern leaf blight ( D. maydis) or northern leaf blight ( B. zeicola) on maize, eg fuzzy spot ( B. sorokiniana) on cereals and for example, B. oryzae in rice and grass; Blumeria (formerly Erysiphe) graminis (powdery mildew) on cereals (for example, on wheat or barley); Botrytis cinerea (teleomorph: Botryotinia fuckeliana: gray mold) on fruits and berries (eg strawberries), vegetables (eg lettuce, carrots, celery and cabbages), rapeseed, flowers, vines, forest plants and wheat; Bremia lactucae (downy mildew) on lettuce; Ceratocystis ( syn. Ophiostoma) spp. (rot or wilt) in broadleaf trees and evergreens, eg C. ulmi (Dutch elm disease) in elm trees; Cercospora spp. (Cercospora leaf spots) on corn (for example, gray leaf spot: C. zeae-maydis), rice, sugar beet (for example, C. beticola), sugar cane, vegetables, coffee, soy (for example , C. sojina or C. kikuchii) and rice; Cladosporium spp. on tomatoes (eg C. fulvum: leaf mold) and cereals, eg C. herbarum (black ear) on wheat; Claviceps purpurea (ergot) in cereals; Cochliobolus (anamorph: Bipolaris Helminthosporium ) spp. (leaf spots) on corn (C. carbonum), cereals (e.g. C. sativus, anamorph: B. sorokiniana) and rice (eg, C. miyabeanus, anamorph: H. oryzae); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose) on cotton (for example, C. gossypii), corn (for example, C. graminicola: anthracnose stem rot), berries, potatoes (for example, C. coccodes: black dot), beans (for example , C. lindemuthianum) and soybeans (for example, C. truncatum or C. gloeosporioides); Corticium spp., For example, C. sasakii (pod blight) on rice; Corynespora cassiicola (leaf spots) on soybeans and ornamental plants; Cycloconium spp., For example, C. oleaginum on olive trees; Cylindrocarpon spp. (eg, canker of fruit trees or declination of young vines, teleomorph: Nectria or Neonectria spp.) on fruit trees, grapevines (eg, C. liriodendri, teleomorph: Neonectria liriodendri: black foot disease) and ornamental plants; Dematophora (teleomorph: Rosellinia) necatrix (root and stem rot) on soybeans; Diaporthe spp., For example, D. phaseolorum (fungal wilt) in soybeans; Drechslera ( syn. Helminthosporium, teleomorph: Pyrenophora) spp. in corn, cereals, such as barley (for example, D. teres, red spot) and wheat (for example, D. tritici-repentis: brown spot), rice and grass; Esca (dieback, stroke) in grapevines, caused by Formitiporia ( syn. Phellinus) punctata, F. mediterranea, Phaeomoniella chlamydospora (formerly Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum and / or Botryosphaeria obtusa; Elsinoe spp. in pome fruits (E. pyri), red fruits (E. veneta: anthracnose) and vines (E. ampelina: anthracnose); Entyloma oryzae (leaf charcoal) on rice; Epicoccum spp. (black mold) on wheat; Erysiphe spp. (powdery mildew) on sugar beet (E. betae), vegetables (eg E. pisi), such as cucurbits (eg E. cichoracearum), cabbages, rapeseed (eg E. cruciferarum); Eutypa lata (Eutypa canker or dieback, anamorphic: Cytosporina lata, syn. Libertella blepharis) on fruit trees, vines, and ornamental woods; Exserohilum ( syn. Helminthosporium ) spp. in corn (for example, E. turcicum ); Fusarium (teleomorph: Gibberella ) spp. (wilt, root or stem rot) in various plants, such as F. graminearum or F. culmorum (root rot, scabies or head blight) in cereals (for example, wheat or barley), F. oxysporum on tomatoes, F. solani (f glycines sp. now synonymous with F. virguliforme) and F. tucumaniae and F. brasiliense each causing sudden death syndrome in soybeans and F. verticillioides in corn; Gaeumannomyces graminis (pietin) on cereals (eg wheat or barley) and corn; Gibberella spp. in cereals (eg G. zeae) and rice (eg G. fujikuroi: Bakanae disease); Glomerella cingulata on vines, pome fruits and other plants and G. gossypii on cotton; Grainstaining complex in rice; Guignardia bidwellii (black rot) on vines; Gymnosporangium spp. on pinkish plants and junipers, eg G. sabinae (rust) on pears; Helminthosporium spp. ( syn. Drechslera, teleomorph: Cochliobolus) in corn, cereals and rice; Hemileia spp., For example, H. vastatrix (coffee leaf rust) on coffee trees; Isariopsis clavispora ( syn. Cladosporium vitis) on vines; Macrophomina phaseolina ( syn. Phaseoli) (root and stem rot) on soybeans and cotton; Microdochium ( syn. Fusarium) nivale (pink snow mold) on cereals (eg wheat or barley); Microsphaera diffusa (powdery mildew) on soybeans; Monilinia spp., For example, M. laxa, M. fructicola and M. fructigena (flower and twig blight, brown rot) on stone fruits and other pinkish plants; Mycosphaerella spp. in cereals, bananas, red fruits and ground nuts, such as for example, M. graminicola (anamorph: Septoria tritici, Septoria spot) in wheat or M. fijiensis (black leaf streak disease) in bananas; Peronospora spp. (downy mildew) on cabbage (eg P. brassicae), rapeseed (eg P. parasitica), onions (eg P. destructor), tobacco ( P. tabacina), and soybeans (eg P. manshurica ); Phakopsora pachyrhizi and P. meibomiae (soybean rust) on soybeans; Phialophora spp. for example, on grapevines (eg P. tracheiphila and P. tetraspora) and soybeans (eg P. gregata: stem rot); Phoma lingam (root and stem rot) in rapeseed and cabbage and P. betae (root rot, leaf spot and fungal wilt) in sugar beet; Phomopsis spp. on sunflowers, grapevines (eg P. viticola: cane and leaf spot) and soybeans (eg stem rot: P. phaseoli, teleomorph: Diaporthe phaseolorum); Physoderma maydis (brown spots) on corn; Phytophthora spp. (wilt, root rot. leaf, fruit and stem) in various plants, such as paprika and cucurbits (eg P. capsici), soybeans (eg P. megasperma, sin. P. sojae) , potatoes and tomatoes (eg P. infestans: late blight) and broadleaf trees (eg P. ramorum: sudden oak death); Plasmodiophora brassicae (hernia) in cabbage, rapeseed, radish and other plants; Plasmopara spp., For example, P. viticola (common vine downy mildew) on vines and P. halstedii on sunflowers; Podosphaera spp. (powdery mildew) on roseaceous plants, hops, pip and red fruits, eg P. leucotricha on apples; Polymyxa spp., For example, in cereals, such as barley and wheat ( P. graminis) and sugar beet ( P. betae) and therefore viral diseases transmitted; Pseudocercosporella herpotrichoides (eye spot, teleomorph: Tapesia yallundae) on cereals, eg wheat or barley; Pseudoperonospora (downy mildew) on various plants, eg P. cubensis on cucurbits or P. humili on hops; Pseudopezicula tracheiphila (red fire disease or, rotbrenner ', anamorph: Phialophora) on vines; Puccinia spp. (rust) on various plants, e.g. P. triticina (brown or leaf rust), P. striiformis (yellow or striated rust), P. hordei (dwarf rust), P. graminis (black or stem rust) or P. recondita (brown or leaf rust) on cereals, such as, for example, wheat, barley or rye, P. kuehnii (orange rust) on sugar cane and P. asparagi on asparagus; Pyrenophora (anamorph: Drechslera) tritici-repentis (brown spot) on wheat or P. teres (web spot) on barley; Pyricularia spp., For example, P. oryzae (teleomorph: Magnaporthe grisea, rice blast) on rice, and P. grisea on grass and cereals; Pythium spp. (fungal wilt) on grass, rice, corn, wheat, cotton, rapeseed, sunflowers, soybeans, sugar beets, vegetables and various other plants (eg P. ultimum or P. aphanidermatum); Ramularia spp., For example, R. collocygni (Ramularia leaf spots, physiological leaf spots) on barley, and R. beticola on sugar beet; Rhizoctonia spp. on cotton, rice, potatoes, lawns, corn, rapeseed, potatoes, sugar beets, vegetables and various other plants, for example R. solani (root and stem rot) in soybeans, R. solani (pod blight ) on rice, or R. cerealis (Rhizoctonia spring blight) on wheat or barley; Rhizopus stolonifer (black mold, soft rot) on strawberries, carrots, cabbage, vines, and tomatoes; Rhynchosporium secalis (scald) on barley, rye and triticale; Sarocladium oryzae and S. attenuatum (pod rot) on rice; Sclerotinia spp. (stem rot or white mold) in vegetables and field crops, such as rapeseed, sunflowers (eg S. sclerotiorum) and soybeans (eg S. rolfsii or S. sclerotiorum); Septoria spp. in various plants, for example, S. glycines (brown spot) on soybeans, S. tritici (Septoria spot) on wheat, and S. ( syn. Stagonospora) nodorum ( Stagonospora spot) on cereals; Uncinula ( syn. Erysiphe) necator (powdery mildew, anamorphic: Oidium tuckeri) on vines; Setospaeria spp. (leaf blight) on corn (eg S. turcicum, syn . Helminthosporium turcicum) and grass; Sphacelotheca spp. (charcoal) in corn (eg S. reiliana: head charcoal), sorghum and sugar cane; Sphaerotheca fuliginea (powdery mildew) on cucurbits; Spongospora subterranea (powdery scab) on potatoes and viral diseases transmitted by it; Stagonospora spp. in cereals, for example, S. nodorum ( Stagonospora spot, teleomorph: Leptosphaeria [ syn. Phaeosphaeria] nodorum) in wheat; Synchytrium endobioticum on potatoes (potato wart disease); Taphrina spp., For example, T. deformans (leaf curl disease) on peaches, and T. pruni (plum leprosy) on plums; Thielaviopsis spp. (black root rot) in tobacco, pome fruits, vegetables, soybeans and cotton, eg T. basicola ( syn. Chalara elegans); Tilletia spp. (common caries or wheat char) in cereals, such as, for example, T. tritici ( syn. T. caries, wheat caries) and T. controversa (dwarf caries) in wheat; Typhula incarnata (gray snow mold) on barley or wheat; Urocystis spp., For example, U. occulta (stem smut) on rye; Uromyces spp. (rust) in vegetables, such as beans (eg U. appendiculatus, syn. U. phaseoli) and sugar beets (eg U. betae); Ustilago spp. (bare charcoal) in cereals (eg U. nuda and U. avaenae), maize (eg U. maydis: maize charcoal) and sugar cane; Venturia spp. (scab) on apples (eg V. inaequalis) and pears; and Verticillium spp. (wilt) in various plants, such as fruit and ornamental plants, vines, berries, vegetables and field crops, for example V. dahliae in strawberries, rapeseed, potatoes and tomatoes.

The compositions are also suitable for controlling harmful fungi in the protection of stored products or harvest and in the protection of materials. The term "protection of materials" should be understood as the protection of technical and non-living materials, such as adhesives, glues, wood, paper and cardboard, textiles, leather, paint dispersions, plastics, cooling lubricants, fibers or fabrics, against the infestation and destruction by harmful microorganisms, such as fungi and bacteria. Regarding the protection of wood and other materials, special attention is paid to the following harmful fungi: Ascomycetes such as Ophiostoma spp., Ceratocystis spp., Aureobasidium pullulans, Sclerophoma spp., Chaetomium spp., Humicola spp., Petriella spp. ., Trichurus spp .; Basidiomycetes such as Coniophora spp., Coriolus spp., Gloeophyllum spp., Lentinus spp., Pleurotus spp., Poria spp., Serpula spp. and Tyromyces spp., Deuteromycetes such as Aspergillus spp., Cladosporium spp., Penicillium spp., Trichorma spp., Alternaria spp., Paecilomyces spp. and Zygomycetes such as Mucor spp., and also in the protection of stored products and crops the following yeast fungi are worthy of mention: Candida spp. and Saccharomyces cerevisae.

The compositions can be used to improve the health of a plant. The invention also relates to a method of improving plant health by treating a plant, its propagation material and / or the place where the plant is growing or will grow with an effective amount of the components of the compositions of the invention or the compositions of the invention, respectively. .

The term "plant health" should be understood to indicate a condition of the plant and / or its products that is determined by various indicators alone or in combination with each other, such as yield (eg increase in biomass and / or increase in content of valuable ingredients), plant vigor (for example, improved plant growth and / or greener leaves ("greening effect")), quality (for example, improved content or composition of certain ingredients) and tolerance to abiotic and / or biotic stress. The indicators identified above for the health status of a plant may be interdependent or may result from each other.

The compounds of formula I can be present in different crystalline modifications whose biological activity can differ. Compositions comprising such modifications of compounds I are also the object of the present invention.

The compositions are used to treat fungi or plants, plant propagation materials, such as seeds, soil, surfaces, materials or rooms to be protected from fungal attack with a fungicidally effective amount of the active substances. The application can be carried out both before and after the infection of plants, plant propagation materials, such as seeds, soil, surfaces, materials or rooms by fungi.

Plant propagation materials can be treated with the components of the compositions of the invention and the compositions of the invention, respectively, prophylactically at or before planting or transplantation.

The invention also relates to agrochemical compositions comprising an auxiliary and the components of the composition of the respective invention or the composition of the invention, respectively.

An agrochemical composition comprises a fungicidally effective amount of the components of the compositions of the invention or the composition of the invention, respectively. The term "effective amount" indicates an amount of the composition or components, which is sufficient to control noxious fungi in cultivated plants or in the protection of materials and which does not result in substantial damage to the treated plants. Said amount can vary over a wide range and depends on various factors, such as the species of fungi to be controlled, the plant or cultivated material treated, the climatic conditions and the specific compound I used.

The components of the compositions of the invention or the compositions of the invention, respectively, their N-oxides and salts can be converted into common types of agrochemical compositions, for example, solutions, emulsions, suspensions, powders, sprays, pastes, granules, presses, capsules and compositions thereof. Examples of composition types are suspensions (eg SC, OD, FS), emulsifiable concentrates (eg EC), emulsions (eg EW, EO, ES, ME), capsules (eg CS, ZC) , pastes, tablets, wettable powders or powders (eg WP, SP, WS, DP, DS), pressed (eg BR, TB, DT), granules (eg WG, SG, GR, F ^g , G ^g , MG), insecticidal articles (eg LN), as well as gel formulations for the treatment of plant propagation materials such as seeds (eg GF). These and other types of compositions are defined in the "Catalog of pesticide formulation types and international coding system", Technical Monograph No. 2, 6th Ed. May 2008, CropLife International.

Compositions are prepared in a known manner, as described by Mollet and Grubemann, Formulation Technology, Wiley VCH, Weinheim, 2001; o Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.

Suitable auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, humectants, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesion agents, thickeners, humectants, repellants, attractants, feed stimulants , compatibilizers, bactericides, antifreeze agents, antifoam agents, colorants, adhesives and binders.

Suitable liquid carriers and solvents are water and organic solvents, such as medium to high boiling mineral oil fractions, eg kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, eg toluene, paraffin, tetrahydronaphthalene, alkylated naphthalenes; alcohols, eg, ethanol, propanol, butanol, benzyl alcohol, cyclohexanol; glycols; DMSO; ketones, for example cyclohexanone; esters, eg lactates, carbonates, fatty acid esters, gammabutyrolactone; fatty acids; phosphonates; amines; amides, eg, N-methylpyrrolidone, fatty acid dimethylamides; and compositions thereof.

Suitable solid carriers or fillers are mineral earths, for example silicates, silica gels, talc, kaolin, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, oxide magnesium; polysaccharides, eg cellulose, starch; fertilizers, for example ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of plant origin, for example, cereal flour, tree bark flour, wood flour, walnut shell flour and compositions thereof.

Suitable surfactants are surfactant compounds, such as anionic, cationic, nonionic, and amphoteric surfactants, block polymers, polyelectrolytes, and compositions thereof. Such surfactants can be used as emulsifiers, dispersants, solubilizers, humectants, penetration enhancers, protective colloids, or adjuvants. Examples of surfactants are listed in McCutcheon's, Vol.1: Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Ed. Or North American Ed.).

Suitable anionic surfactants are alkali, alkaline earth, or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and compositions thereof. Examples of sulfonates are alkylaryl sulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignin sulfonates, fatty acid and oil sulfonates, ethoxylated alkylphenol sulfonates, alkoxylated arylphenol sulfonates, condensed naphthalene sulfonates, dodecyl naphthalene sulfonates, and tridecyl sulphonates. and alkylnaphthalenes, sulfosuccinates, or sulfosuccinamates. Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols or of fatty acid esters. Examples of phosphates are phosphate esters. Examples of carboxylates are alkylcarboxylates and carboxylated alcohol or alkylphenolethoxylates.

Suitable nonionic surfactants are alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and compositions thereof. Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids, or fatty acid esters that have been alkoxylated with 1 to 50 equivalents. Ethylene oxide and / or propylene oxide, preferably ethylene oxide, can be used for the alkoxylation. Examples of N-substituted fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters, or monoglycerides. Examples of sugar-based surfactants are sorbitan, ethoxylated sorbitan, sucrose glucose esters, or alkylpolyglucosides. Examples of polymeric surfactants are homo or copolymers of vinylpyrrolidone, vinyl alcohols, or vinyl acetate.

Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or long chain primary amine salts. Suitable amphoteric surfactants are alkyl betaines and imidazolines. Suitable block polymers are block polymers of the A-B or A-B-A type comprising blocks of polyethylene oxide and polypropylene oxide, or of the A-B-C type comprising alkanol, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or polyethyleneamines.

Suitable adjuvants are compounds that have negligible or even zero pesticidal activity on their own, and that improve the biological performance of compound I on the target. Examples are surfactants, mineral or vegetable oils, and other auxiliaries. Additional examples are listed in Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, 2006, chapter 5.

Suitable thickeners are polysaccharides (eg, xanthan gum, carboxymethyl cellulose), inorganic clays (organically modified or unmodified), polycarboxylates, and silicates.

Suitable bactericides are bronopol and isothiazolinone derivatives such as alkyl isothiazolinones and benzisothiazolinones.

Suitable antifreeze agents are ethylene glycol, propylene glycol, urea, and glycerin.

Suitable antifoaming agents are silicones, long chain alcohols, and fatty acid salts.

Suitable colorants (eg red, blue or green) are low water solubility pigments and water soluble dyes. Examples are inorganic dyes (eg, iron oxide, titanium oxide, iron hexacyanoferrate) and organic dyes (eg, alizarin, azo, and phthalocyanine dyes).

Suitable tackifiers or binders are polyvinylpyrrolidones, polyvinyl acetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers.

Examples of types of general composition and their preparation are (in which the active substances indicate the respective components (= active ingredients) of the composition of the invention):

i) Water soluble concentrates (SL, LS)

10-60% by weight of active substances and 5-15% by weight of wetting agent (eg alcohol alkoxylates) are dissolved in water and / or in a water soluble solvent (eg alcohols) up to 100% in weigh. The active substance dissolves when diluted with water.

ii) Dispersible concentrates (DC)

5-25% by weight of active substances and 1-10% by weight of dispersant (eg polyvinylpyrrolidone) are dissolved in an organic solvent (eg cyclohexanone) up to 100% by weight. Dilution with water produces a dispersion.

iii) Emulsifiable concentrates (EC)

15-70% by weight of active substances and 5-10% by weight of emulsifiers (for example, calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in a water-insoluble organic solvent (for example, aromatic hydrocarbon) until the 100% by weight. Dilution with water produces an emulsion.

iv) Emulsions (EW, EO, ES)

5-40% by weight of active substances and 1-10% by weight of emulsifiers (e.g. calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in 20-40% by weight of water-insoluble organic solvent (e.g. , aromatic hydrocarbon). This composition is introduced into water up to 100% by weight by means of an emulsifying machine and becomes a homogeneous emulsion. Dilution with water produces an emulsion. v) Suspensions (SC, OD, FS)

In a stirred ball mill, 20-60% by weight of active substances are ground with the addition of 2-10% by weight of dispersants and wetting agents (for example, sodium lignosulfonate and alcohol ethoxylate), 0.1-2 % by weight of thickener (eg xanthan gum) and water up to 100% by weight to give a fine suspension of the active substance. Dilution with water produces a stable suspension of the active substance. For the FS type composition, up to 40% by weight of binder (eg polyvinyl alcohol) is added.

vi) Water dispersible granules and water soluble granules (WG, SG)

50-80 % by weight of active substances are finely ground with the addition of dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate) up to 100% by weight and prepared as water-dispersible or water-soluble granules by means of technical apparatus (eg extrusion, spray tower, fluidized bed). Dilution with water produces a stable dispersion or solution of the active substance.

vii) Water dispersible powders and water soluble powders (WP, SP, WS)

50-80% by weight of active substances are ground in a rotor-stator mill with the addition of 1-5% by weight of dispersants (for example sodium lignosulfonate), 1-3% by weight of wetting agents (for example , alcohol ethoxylate) and solid carrier (eg silica gel) up to 100% by weight. Dilution with water produces a stable dispersion or solution of the active substance.

viii) Gel (GW, GF)

In a stirred ball mill, 5-25% by weight of active substances are ground with the addition of 3-10% by weight of dispersants (for example sodium lignosulfonate), 1-5% by weight of thickener (for example carboxymethylcellulose) and water up to 100% by weight to give a fine suspension of the active substance. Dilution with water produces a stable suspension of the active substance.

iv) Microemulsion (ME)

5-20% by weight of active substances are added to 5-30% by weight of mixture of organic solvents (for example, fatty acid dimethylamide and cyclohexanone), 10-25% by weight of mixture of surfactants (for example, alcohol ethoxylate and arylphenol ethoxylate), and water up to 100% by weight. This composition is stirred for 1 hr to spontaneously produce a thermodynamically stable microemulsion.

iv) Microcapsules (CS)

An oil phase comprising 5-50% by weight of active substances, 0-40% by weight of water-insoluble organic solvent (for example aromatic hydrocarbon), 2-15% by weight of acrylic monomers (for example, methacrylate of methyl, methacrylic acid and a di- or triacrylate) are dispersed in an aqueous solution of a protective colloid (eg, polyvinyl alcohol). Radical polymerization initiated by a radical initiator results in the formation of poly (meth) acrylate microcapsules. Alternatively, an oil phase comprising 5-50% by weight of a compound I according to the invention, 0-40% by weight of a water-insoluble organic solvent (for example aromatic hydrocarbon) and an isocyanate monomer (for example diphenylmethene -4,4'-diisocyanate) are dispersed in an aqueous solution of a protective colloid (eg, polyvinyl alcohol). The addition of a polyamine (eg, hexamethylenediamine) results in the formation of polyurea microcapsules. The monomers amount to 1-10% by weight. The% by weight refers to the total CS composition. ix) Dry powders (DP, DS)

1-10% by weight of active substances are finely ground and intimately mixed with a solid carrier (eg finely divided kaolin) up to 100% by weight.

x) Granules (GR, FG)

0.5-30% by weight of active substances are finely ground and associated with a solid carrier (eg silicate) up to 100% by weight. Granulation is achieved by extrusion, spray drying or fluidized bed.

xi) Ultra Low Volume Liquids (UL)

1-50% by weight of active substances are dissolved in an organic solvent (eg aromatic hydrocarbon) up to 100% by weight.

Compositions of types i) to xi) may optionally comprise other auxiliaries, such as 0.1-1% by weight of bactericides, 5-15% by weight of antifreeze agents, 0.1-1% by weight of antifoam agents and 0.1-1 % by weight of colorants.

The agrochemical compositions generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75% by weight of the active substance. The active substances are used in a purity of 90% to 100%, preferably 95% to 100% (according to the NMR spectrum).

Seed Treatment Solutions (LS), Suspoemulsions (SE), Fluid Concentrates (FS), Dry Treatment Powders (DS), Water Dispersible Powders for Slurry Treatment (WS), Water Soluble Powders (SS), Emulsions (ES), emulsifiable concentrates (EC) and gels (GF) are commonly used for the treatment of plant propagation materials, in particular seeds. The compositions in question give, after dilution from two to ten times, concentrations of the active substance from 0.01 to 60% by weight, preferably from 0.1 to 40%, in ready-to-use preparations. The application can be done before or during sowing. The methods of applying compound I and the compositions thereof, respectively, on the propagation material of plants, especially seeds, include methods of fertilizing, coating, pelletizing, dusting, soaking and applying in furrows of the propagation material. Preferably, compound I or compositions thereof, respectively, are applied to the plant propagation material by a method such that germination is not induced, for example, by seed dressing, pelletizing, coating and dusting.

When used in plant protection, the amounts of active substances applied are, depending on the type of effect desired, from 0.001 to 2 kg per ha, preferably from 0.005 to 2 kg per ha, more preferably from 0.05 to 0.9 kg per ha, and in particular 0.1 to 0.75 kg per ha, from 0.1 to 10 kg of active ingredients per 100 kg of seed

In the treatment of plant propagation materials such as seeds, for example by dusting, coating or dipping seeds, amounts of the active substance are generally required from 0.1 to 10 kg of the active substance per 100 kg of seed, in particular from 0.1 to 1000 g, preferably from 1 to 1000 g, more preferably from 1 to 100 g, and more preferably from 5 to 100 g, per 100 kilograms of plant propagation material (preferably seeds).

When used to protect stored materials or products, the amount of active substance applied depends on the type of application area and the desired effect. The amounts usually applied in the protection of materials are 0.001 g to 2 kg, preferably 0.005 g to 1 kg, of the active substance per cubic meter of treated material.

Various types of oils, humectants, adjuvants, fertilizers or micronutrients and other pesticides (e.g. herbicides, insecticides, fungicides, growth regulators, protectants) can be added to the active substances or the compositions comprising them as a premix or, if appropriate not until immediately before use (tank mix). These agents can be mixed with the compositions according to the invention in a weight ratio of 1: 100 to 100: 1, preferably 1:10 to 10: 1.

The user applies the composition according to the invention usually from a pre-dosing device, a backpack sprayer, a spray tank, a spray plane or an irrigation system. Usually, the agrochemical composition is prepared with water, buffer solution and / or additional auxiliaries up to the desired application concentration and in this way the ready-to-use spray liquor or the agrochemical composition according to the invention is obtained. Typically, 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of useful agricultural area.

According to one embodiment, the individual components of the composition according to the invention, such as parts of a kit or parts of the composition, can be mixed by the user himself in a spray tank or any other type of container used for applications (for example , seed treatment drums, seed pelletizing machinery, knapsack sprayer) and other auxiliaries, if applicable.

When live microorganisms, such as microbial pesticides of groups L1), L3) and L5), are part of such a kit, care must be taken that the choice and quantities of the components (for example, chemical pesticides) and of the additional auxiliaries should not influence the viability of the microbial pesticides in the composition mixed by the user. Especially for bactericides and solvents, the compatibility with the respective microbial pesticide must be taken into account.

Accordingly, one embodiment of the invention is a kit for preparing a usable pesticidal composition, the kit comprising a) a composition comprising component 1) as defined herein and at least one auxiliary; and b) a composition comprising component 2) as defined herein and at least one auxiliary; and optionally c) a composition comprising at least one auxiliary and optionally one additional active component 3) as defined herein.

In compositions, the proportions of the components are sometimes advantageously chosen to produce a synergistic effect.

The term "synergistic effect" is understood to refer in particular to that defined by the formula of (Colby, S. R., "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds, 15, pp. 20-22, 1967).

The term "synergistic effect" is also understood to refer to that defined by the application of the Tammes method, (Tammes, PML, "Isobols, a graphic representation of synergism in pesticides", Netherl. J. Plant Pathol. 70, 1964) .

The components can be used individually or already partially or completely mixed with each other to prepare the composition according to the invention. They can also be packaged and used as a combination, such as a parts kit.

The fungicidal action of the compositions according to the invention can be demonstrated by the tests described below.

The active compounds, separately or together, are prepared as a stock solution comprising 25 mg of active compound that is made up to 10 ml using a composition of acetone and / or DMSO and the emulsifier Uniperol® EL (wetting agent having a emulsifying and dispersing action based on ethoxylated alkylphenols) in a solvent / emulsifier volume ratio of 99: 1. The composition is then made up to 100 ml with water. This stock solution is diluted with the described solvent / emulsifier / water composition to give the active compound concentration indicated below. Visually determined percentages of infected leaf areas are converted to% efficiencies of the untreated control.

Efficacy (E) is calculated as follows using Abbot's formula:

a corresponds to the fungicidal infection of the treated plants in% and

P corresponds to the fungicidal infection of the untreated plants (control) in%

An efficacy of 0 means that the level of infection of the treated plants corresponds to that of the untreated control plants; an efficiency of 100 means that the treated plants were not infected.

Expected efficiencies of active compound combinations were determined using Colby's formula (Colby, SR "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds, 15, pp. 20-22, 1967) and compared with observed efficiencies .

Colby's formula: E = xy - x * y / 100

E expected efficacy, expressed in% of the untreated control, when using the composition of active compounds A and B at concentrations a and b

x efficacy, expressed in% of the untreated control, when active compound A is used at concentration a and efficacy, expressed in% of the untreated control, when active compound B is used at concentration b.

Micro tests

The active compounds were formulated separately as a stock solution with a concentration of 10,000 ppm in dimethylsulfoxide.

The orisastrobin product was used as a finished commercial formulation and was diluted with water to the indicated concentration of active compound.

Stock solutions were mixed proportionally, pipetted onto a microtiter plate (MTP), and diluted with water to the indicated concentrations. Then a spore suspension of the respective pathogen was added in the respective nutrient medium. The plates were placed in a chamber saturated with water vapor at a temperature of 18 ° C. Using an absorption photometer, MTPs were measured at 405 nm 7 days after inoculation.

The measured parameters were compared with the growth of the control variant without active compound (100%) and the blank value free of fungi and without active compound to determine the relative growth in% of the pathogens in the respective active compounds. These percentages were converted into efficiencies.

The expected efficiencies of the active compound compositions were determined using the formula of Colby [R.S. Colby, "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, 20-22 (1967)] and were compared with observed efficiencies.

Claims (11)

1. Compositions comprising, 1) as component I the: compound I-32- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) propan-2-ol; and 2) as component II a biopesticide selected from: Bacillus amyloliquefaciens ssp. plantarum MBI 600 (II-27), Bacillus pumilus INR-7 (II-29), Bacillus subtilis FB17 (II-176). 2. The compositions of claim 1, wherein component I and component II are present in a total weight ratio of from 100: 1 to 1: 100 wherein the total weight of component II is based on the amount of solid material (dry matter). Component II. The compositions of claim 1 or 2, wherein component I and component II are present in a total weight ratio of from 100: 1 to 1: 100, wherein the total weight of component II is calculated as based on the amount of CFU of component 11, where 1 x 109 c Fu equals one gram of total weight of component II. 4. The compositions of any one of claims 1 to 3, further comprising a component III selected from biopesticides. 5. The compositions of any one of claims 1 to 3, further comprising a component III selected from biopesticides of groups L1) to L6): L1) Microbial pesticides with fungicidal, bactericidal, viricidal and / or activating activity of plant defenses: Bacillus altitudinis, B. amyloliquefaciens, B. megaterium, B. mojavensis, B. mycoides, B. pumilus, B. simplex, B solisalsi, B. subtilis, B. subtilis var. amyloliquefaciens, Metschnikowia fructicola, Microdochium dimerum, Microsphaeropsis ochracea, Muscodor albus, Paenibacillus alvei, Paenibacillus polymyxa, Pantoea agglomerans ( II-35), Pantoea vagans, Penicillium bilaiae, Phlebiopsis chondrasis, Pudolebiopsis gigantea. Pythium oligandrum, Sphaerodes mycoparasitica, Streptomyces griseoviridis, S. lydicus, S. violaceusniger, Talaromyces flavus, Trichoderma asperellum, T. atroviride, T. fertile, T. gamsii, T. harmatum, T. harzianum, T. polysporum, T. stromaticum , T. virens, T. viride, Typhula phacorrhiza, Ulocladium oudemansii, Verticillium dahlia, zucchini yellow mosaic virus (avirulent strain); L2) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or activator of plant defenses: chitosan (hydrolyzed), potassium or sodium bicarbonate, salicylic acid, tea tree oil; L3) Microbial pesticides with insecticidal, acaricidal, molluscid and / or nematicidal activity: Agrobacterium radiobacter, Bacillus cereus, B. firmus, B. thuringiensis, B. thuringiensis ssp. aizawai, B. t. ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, B. t. ssp. tenebrionis, Beauveria bassiana, Burkholderia spp., Flavobacterium spp., Metarhizium anisopliae, Metarhizium anisopliae var. anisopliae, M. anisopliae var. acridum, Nomuraea rileyi, Paecilomyces fumosoroseus, Paecilomyces lilacinus, Paenibacillus popilliae, Pasteuria spp., P. nishizawae, P. penetrans, P. ramosa, P. reneformis, P. thornea, P. usagae, Pseudomonas fluorescens, Pseudomonas putroida virus Spodoptera littoralis (SpliNPV), Steinernema carpocapsae, S. feltiae, S. kraussei, Streptomyces galbus, S. microflavus; L4) Biochemical pesticides with insecticidal, acaricidal, molluscid, pheromone and / or nematicidal activity: cisjasmone, methyl jasmonate, Neem oil, Quillay extract, Tagetes oil; L5) Microbial pesticides with plant stress reducing activity, plant growth regulator, plant growth promoter and / or performance enhancer: Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium spp., B. elkanii, B. japonicum, B. liaoningense, B. lupini, Delftia acidovorans, Glomus intrarad ices, Mesorhizobium spp., Rhizobium leguminosarum bv. phaseoli, RI bv. trifolii, RI bv. viciae, R. tropici, Sinorhizobium meliloti; L6) Biochemical pesticides with plant stress reducing activity, plant growth regulator and / or plant performance enhancer: abscisic acid, indole-3-acetic acid, jasmonic acid and its salts or derivatives thereof. The compositions of any one of claims 1 to 3, further comprising a component III selected from biopesticides of groups La) to Lf) as defined in claim 2. La) Microbial pesticides with fungicidal, bactericidal, virucidal and / or activator of the defenses of plants selected from: Bacillus altudinis, Bacillus amyloliquefaciens, Bacillus amyloliquefaciens ssp. plantarum MBI 600 (II-27), B. amyloliquefaciens ssp. plantarum D747, B. megaterium, B. mojavensis (II-28), B. mycoides, B. pumilus INR-7 (II-29), B. pumilus GHA 180, B. simplex (II-30), B. solisalsi (II-31), Bacillus subtilis, Burkholderia sp., Microsphaeropsis ochracea, Muscodor albus, Paenibacillus alvei, Paenibacillus polymyxa (II-34), Pantoea agglomerans (II-35), Pantoea vagans, Penicillium bilaiae, Pseudphisomonas sp., Pseudphisomonas sp. , P. fluorescens, Sphaerodes mycoparasitica (II-36), Streptomyces lydicus (II-37), S. violaceusniger (II-38), Trichoderma fertile JM41R (II-39), Typhula phacorrhiza (II-40), Verticillium dahlia ( II-42), zucchini yellow mosaic virus (avirulent strain); Lb) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or activating activity of the defenses of plants selected from: potassium or sodium bicarbonate, salicylic acid, tea tree oil; Lc) Microbial pesticides with insecticidal, acaricidal, molluscid and / or nematicidal activity selected from: Agrobacterium radiobacter, Bacillus cereus, Bacillus firmus (II-44), B. thuringiensis ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, Beauveria bassiana (II-45), Metarhizium anisopliae (II-46), M. anisopliae var. anisopliae, M. anisopliae var. acridum, Paecilomyces fumosoroseus, P. lilacinus, Paenibacillus popilliae, Pasteuria spp., P. nishizawae, P. reneformis, P. usagae, Pseudomonas fluorescens, Pseudomonas putida, Steinernema feltiae, Steinernema kraussei, Streptomcesbuslavces; Ld) Biochemical pesticides with insecticidal, acaricidal, molluscid, pheromone and / or nematicidal activity selected from: methyl jasmonate, Neem oil, Quillay extract (11-47), Tagetes oil; Le) Microbial pesticides with plant stress reducing activity, plant growth regulator, plant growth promoter and / or performance enhancer selected from: Azospirillum amazonense, A. brasilense (11-48), A. lipoferum , A. irakense, A. halopraeferens, Bradyrhizobium sp. (11-49), B. japonicum (II-50), B. elkanii, B. lupini, B. liaoningense, Delftia acidovorans, Glomus intraradices, Mesorhizobium sp. (II-51), M. ciceri, M. huakii, M. loti, Rhizobium leguminosarum bv. phaseoli (II-53), R. I. trifolii, R. I. bv. viciae (II-54), R. tropici, Sinorhizobium meliloti (II-55); Lf) Biochemical pesticides with plant stress reducing activity, plant growth regulator and / or plant performance enhancer selected from: abscisic acid, indole-3-acetic acid, jasmonic acid (II-43) or salts or derivatives thereof. The compositions of any one of claims 1 to 3, further comprising a component III selected from herbicides, insecticides, growth regulators and fungicides. The compositions of any one of claims 1 to 4, further comprising an agrochemical auxiliary. 9. A non-therapeutic use of a composition as defined in any one of claims 1 to 4 to combat phytopathogenic fungi. 10. A non-therapeutic method of combating phytopathogenic fungi, comprising treating fungi or materials, plants, soil or seeds to be protected against fungal attack with an effective amount of a composition as defined in any of claims 1 to 4. 11. Plant propagation material, coated with components I, II or I, II and III of the compositions defined in any one of claims 1 to 4, in an amount from 0.1 to 10 kg of active substances per 100 kg seed.