ES2721659T3 - Aparato para generar 1-metilciclopropeno - Google Patents
Aparato para generar 1-metilciclopropeno Download PDFInfo
- Publication number
- ES2721659T3 ES2721659T3 ES12763166T ES12763166T ES2721659T3 ES 2721659 T3 ES2721659 T3 ES 2721659T3 ES 12763166 T ES12763166 T ES 12763166T ES 12763166 T ES12763166 T ES 12763166T ES 2721659 T3 ES2721659 T3 ES 2721659T3
- Authority
- ES
- Spain
- Prior art keywords
- vessel
- methylcyclopropene
- container
- atom
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- SHDPRTQPPWIEJG-UHFFFAOYSA-N 1-methylcyclopropene Chemical compound CC1=CC1 SHDPRTQPPWIEJG-UHFFFAOYSA-N 0.000 title abstract 10
- 239000005969 1-Methyl-cyclopropene Substances 0.000 title abstract 9
- 150000001875 compounds Chemical class 0.000 abstract 5
- 239000002243 precursor Substances 0.000 abstract 5
- 239000012159 carrier gas Substances 0.000 abstract 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- -1 fluoride ions Chemical class 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 abstract 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 abstract 1
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 abstract 1
- 125000000041 C6-C10 aryl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 125000004437 phosphorous atom Chemical group 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/14—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
- A23B7/153—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
- A23B7/154—Organic compounds; Microorganisms; Enzymes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
- C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/02—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/04—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a three-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2204/00—Aspects relating to feed or outlet devices; Regulating devices for feed or outlet devices
- B01J2204/002—Aspects relating to feed or outlet devices; Regulating devices for feed or outlet devices the feeding side being of particular interest
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Aparato generador de A1-metilciclopropeno (1-MCP) que comprende: un primer recipiente que comprende un precursor de 1-metilciclopropeno; un segundo recipiente que comprende una solución de compuesto que contiene iones fluoruro que reacciona con el precursor de 1-metilciclopropeno para producir 1-metilciclopropeno; y un tercer recipiente que incluye un filtro para eliminar del producto de reacción los subproductos excepto el 1- metilciclopropeno; en donde el primer recipiente, el segundo recipiente y el tercer recipiente, o el segundo recipiente, el primer recipiente y el tercer recipiente están conectados de forma secuencial entre sí a través de un tubo, y un gas portador que es introducido en uno cualquiera del primer recipiente y el segundo recipiente para transferir cualquiera de los precursores de 1-metilciclopropeno y la solución del compuesto que contiene iones fluoruro al otro del primer recipiente y al segundo recipiente, de modo que el precursor del 1-metilciclopropeno y la solución del compuesto que contiene iones fluoruro reaccionan entre sí, en donde a medida que el gas portador se mueve del primer recipiente o del segundo recipiente al otro de ellos, el gas portador descarga al tercer recipiente un producto de reacción que incluye 1-metilciclopropeno producido en el otro del primer recipiente y el segundo recipiente, en donde el precursor de 1-metilciclopropeno es un derivado de :-halociclopropilsilano representado por la Fórmula 1 a continuación: **(Ver fórmula)** en la que A es un grupo metilo; B es un átomo de hidrógeno; X es un átomo de halógeno o un grupo saliente que contiene uno cualquiera seleccionado de un átomo de oxígeno, un átomo de azufre, un átomo de nitrógeno y un átomo de fósforo; y cada uno de R1, R2 y R3 es, independientemente, uno de un átomo de hidrógeno, un grupo alquilo C1-C10, un grupo arilo C6-C10, un grupo alcoxi C1-C10 y un átomo de halógeno, y en donde el compuesto que contiene iones fluoruro es un compuesto representado por la Fórmula 2 a continuación: **(Ver fórmula)** en la que cada uno de Ra, Rb, Rc y Rd es, independientemente, un grupo alquilo C1-C20 o un grupo arilo C6-C15.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20110029038 | 2011-03-30 | ||
| KR1020120015891A KR101877419B1 (ko) | 2011-03-30 | 2012-02-16 | 1-메틸시클로프로펜 발생 장치 |
| PCT/KR2012/001970 WO2012134088A2 (ko) | 2011-03-30 | 2012-03-20 | 1-메틸시클로프로펜 발생 장치 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2721659T3 true ES2721659T3 (es) | 2019-08-02 |
Family
ID=47282490
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12763166T Active ES2721659T3 (es) | 2011-03-30 | 2012-03-20 | Aparato para generar 1-metilciclopropeno |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US10010849B2 (es) |
| EP (1) | EP2692716B1 (es) |
| JP (1) | JP5827394B2 (es) |
| KR (1) | KR101877419B1 (es) |
| CN (1) | CN103459356A (es) |
| AR (1) | AR085732A1 (es) |
| AU (1) | AU2012237125B2 (es) |
| BR (1) | BR112013024934B1 (es) |
| CA (1) | CA2831794C (es) |
| CL (1) | CL2013002764A1 (es) |
| ES (1) | ES2721659T3 (es) |
| HU (1) | HUE044891T2 (es) |
| IL (1) | IL228488A (es) |
| MX (1) | MX355291B (es) |
| PL (1) | PL2692716T3 (es) |
| PT (1) | PT2692716T (es) |
| WO (1) | WO2012134088A2 (es) |
| ZA (1) | ZA201307464B (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014119842A1 (ko) * | 2013-01-30 | 2014-08-07 | (주)이룸바이오테크놀러지 | 숙성 관련 가스 발생 장치 |
| KR101550014B1 (ko) * | 2013-01-30 | 2015-09-07 | (주)이룸바이오테크놀러지 | 숙성 관련 가스 발생 장치 |
| US9538749B2 (en) | 2014-05-12 | 2017-01-10 | Valent Biosciences Corporation | Methods for increasing oil palm yield |
| ES2820879R1 (es) | 2016-02-19 | 2021-06-21 | Hazel Tech Inc | Composiciones para la liberación controlada de ingredientes activos y métodos de preparación de las mismas |
| WO2018106622A1 (en) | 2016-12-05 | 2018-06-14 | Pace International, Llc | Method and system for the treatment of agricultural products |
| EP3642176A1 (en) | 2017-06-21 | 2020-04-29 | Janssen Pharmaceutica NV | Device for generating ultra pure 1-methylcyclopropene |
| IL304085A (en) | 2018-04-27 | 2023-08-01 | Fresh Inset S A | Preparations and items containing complexes of 1-methylcyclopropane and alpha-cyclodextrin |
| US11730166B2 (en) | 2020-02-03 | 2023-08-22 | Fresh Inset S.A. | Stable 1-methylcyclopropene compositions and uses thereof |
| CN112098535B (zh) * | 2020-08-13 | 2022-11-15 | 上海市农业科学院 | 一种检测农作物中1-甲基环丙烯的方法及其用途 |
| KR102372431B1 (ko) * | 2020-11-05 | 2022-03-08 | 주식회사 에코플랜츠 | 1-메틸시클로프로펜 발생 장치 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6017849A (en) | 1998-08-20 | 2000-01-25 | Biotechnologies For Horticulture, Inc. | Synthesis methods, complexes and delivery methods for the safe and convenient storage, transport and application of compounds for inhibiting the ethylene response in plants |
| US6161725A (en) * | 1999-05-04 | 2000-12-19 | Flexible Products Company | Fluent product dispenser with temperature indicating means |
| TW200401609A (en) * | 2002-05-14 | 2004-02-01 | Rohm & Haas | Method and device for the generation of cyclopropene compounds |
| KR100692383B1 (ko) * | 2005-05-09 | 2007-03-09 | 선권석 | 교육용 산소발생 실험장치 |
| GB2432371B (en) * | 2005-11-17 | 2011-06-15 | Epichem Ltd | Improved bubbler for the transportation of substances by a carrier gas |
| KR100823872B1 (ko) * | 2005-11-18 | 2008-04-21 | 유상구 | 농산물의 숙성 과정을 조절하기 위한 시클로프로펜유도체의 발생장치 |
| US20090258143A1 (en) * | 2008-04-11 | 2009-10-15 | Peck John D | Reagent dispensing apparatus and delivery method |
| US20090255466A1 (en) * | 2008-04-11 | 2009-10-15 | Peck John D | Reagent dispensing apparatus and delivery method |
| KR101605677B1 (ko) * | 2008-09-25 | 2016-03-25 | (주)이룸바이오테크놀러지 | 1-메틸시클로프로펜을 제조하여 식물에 부가하는 방법 |
-
2012
- 2012-02-16 KR KR1020120015891A patent/KR101877419B1/ko active IP Right Grant
- 2012-03-20 US US14/007,951 patent/US10010849B2/en active Active
- 2012-03-20 AU AU2012237125A patent/AU2012237125B2/en active Active
- 2012-03-20 CN CN2012800170270A patent/CN103459356A/zh active Pending
- 2012-03-20 HU HUE12763166A patent/HUE044891T2/hu unknown
- 2012-03-20 ES ES12763166T patent/ES2721659T3/es active Active
- 2012-03-20 PL PL12763166T patent/PL2692716T3/pl unknown
- 2012-03-20 CA CA2831794A patent/CA2831794C/en active Active
- 2012-03-20 PT PT12763166T patent/PT2692716T/pt unknown
- 2012-03-20 MX MX2013011118A patent/MX355291B/es active IP Right Grant
- 2012-03-20 EP EP12763166.1A patent/EP2692716B1/en active Active
- 2012-03-20 JP JP2014502449A patent/JP5827394B2/ja active Active
- 2012-03-20 WO PCT/KR2012/001970 patent/WO2012134088A2/ko active Application Filing
- 2012-03-20 BR BR112013024934A patent/BR112013024934B1/pt active IP Right Grant
- 2012-03-28 AR ARP120101051A patent/AR085732A1/es unknown
-
2013
- 2013-09-17 IL IL228488A patent/IL228488A/en active IP Right Grant
- 2013-09-26 CL CL2013002764A patent/CL2013002764A1/es unknown
- 2013-10-07 ZA ZA2013/07464A patent/ZA201307464B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CL2013002764A1 (es) | 2014-05-02 |
| EP2692716A2 (en) | 2014-02-05 |
| IL228488A0 (en) | 2013-12-31 |
| CN103459356A (zh) | 2013-12-18 |
| KR101877419B1 (ko) | 2018-07-11 |
| EP2692716B1 (en) | 2019-03-20 |
| US20140017134A1 (en) | 2014-01-16 |
| PL2692716T3 (pl) | 2019-08-30 |
| AR085732A1 (es) | 2013-10-23 |
| ZA201307464B (en) | 2015-01-28 |
| HUE044891T2 (hu) | 2019-12-30 |
| AU2012237125B2 (en) | 2016-01-07 |
| JP2014522379A (ja) | 2014-09-04 |
| CA2831794C (en) | 2015-04-28 |
| CA2831794A1 (en) | 2012-10-04 |
| WO2012134088A3 (ko) | 2013-01-10 |
| MX2013011118A (es) | 2014-06-23 |
| BR112013024934A2 (pt) | 2017-10-31 |
| AU2012237125A1 (en) | 2013-10-17 |
| IL228488A (en) | 2016-09-29 |
| JP5827394B2 (ja) | 2015-12-02 |
| US10010849B2 (en) | 2018-07-03 |
| EP2692716A4 (en) | 2014-11-26 |
| NZ615620A (en) | 2015-09-25 |
| WO2012134088A2 (ko) | 2012-10-04 |
| BR112013024934B1 (pt) | 2020-01-14 |
| PT2692716T (pt) | 2019-05-22 |
| MX355291B (es) | 2018-04-13 |
| KR20120111994A (ko) | 2012-10-11 |
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