ES271669A1 - Polymerization of butadiene - Google Patents
Polymerization of butadieneInfo
- Publication number
- ES271669A1 ES271669A1 ES0271669A ES271669A ES271669A1 ES 271669 A1 ES271669 A1 ES 271669A1 ES 0271669 A ES0271669 A ES 0271669A ES 271669 A ES271669 A ES 271669A ES 271669 A1 ES271669 A1 ES 271669A1
- Authority
- ES
- Spain
- Prior art keywords
- aluminium
- butadiene
- methyl
- triisobutyl
- catalyst system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B9/00—Component parts for respiratory or breathing apparatus
- A62B9/02—Valves
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/08—Isoprene
Landscapes
- Health & Medical Sciences (AREA)
- Pulmonology (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Polymers of butadiene in which at least 80% of the units are in a cis-1,4 configuration are made by polymerizing butadiene in the presence of a catalyst system formed by mixing (1) TiCl3I, (2) an organo-aluminium compound of the formula AlR3 or AlR2X, in which each R is a hydrocarbon radical and X is a halogen atom, and (3) an organic ether. Specified aluminium compounds are aluminium trimethyl, triethyl, triisobutyl, trihexadecyl, triphenyl, monomethyldiethyl, monoethyldimethyl, diethylmonochloride, and diisobutyl monobromide. The organic ether may be methyl, diethyl, din-propyl, diisopropyl, di-n-butyl, methyl ethyl, isopropyl ethyl, or isopropyl methyl ether, or ethylene oxide, furan, furfural, tetrahydrofuran, dioxane, or morpholine. The catalyst system may be preformed or formed in situ. The polymerization is generally effected in a hydrocarbon diluent, which may be dried by distillation over aluminium triisobutyl.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA811401 | 1960-11-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES271669A1 true ES271669A1 (en) | 1962-02-01 |
Family
ID=4141259
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES0271669A Expired ES271669A1 (en) | 1960-11-19 | 1961-10-31 | Polymerization of butadiene |
Country Status (6)
Country | Link |
---|---|
BE (1) | BE610400A (en) |
DE (1) | DE1174993B (en) |
ES (1) | ES271669A1 (en) |
FR (1) | FR1305251A (en) |
GB (1) | GB931950A (en) |
NL (1) | NL271399A (en) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE551851A (en) * | 1955-10-17 | |||
BE581294A (en) * | 1958-08-11 |
-
0
- BE BE610400D patent/BE610400A/xx unknown
- NL NL271399D patent/NL271399A/xx unknown
-
1961
- 1961-10-31 ES ES0271669A patent/ES271669A1/en not_active Expired
- 1961-10-31 GB GB3893261A patent/GB931950A/en not_active Expired
- 1961-11-02 DE DE1961P0028135 patent/DE1174993B/en active Pending
- 1961-11-14 FR FR878923A patent/FR1305251A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
NL271399A (en) | |
GB931950A (en) | 1963-07-24 |
BE610400A (en) | |
FR1305251A (en) | 1962-09-28 |
DE1174993B (en) | 1964-07-30 |
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