ES269544A1 - Un procedimiento para la oxidaciën de acido cicloalcano carboxilico - Google Patents
Un procedimiento para la oxidaciën de acido cicloalcano carboxilicoInfo
- Publication number
- ES269544A1 ES269544A1 ES0269544A ES269544A ES269544A1 ES 269544 A1 ES269544 A1 ES 269544A1 ES 0269544 A ES0269544 A ES 0269544A ES 269544 A ES269544 A ES 269544A ES 269544 A1 ES269544 A1 ES 269544A1
- Authority
- ES
- Spain
- Prior art keywords
- carboxylic acid
- metal
- water
- magnesium
- cycloalkane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 cycloalkane carboxylic acid Chemical class 0.000 title abstract 7
- 230000003647 oxidation Effects 0.000 title abstract 5
- 238000007254 oxidation reaction Methods 0.000 title abstract 5
- 238000000034 method Methods 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 6
- 239000005749 Copper compound Substances 0.000 abstract 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- 150000001880 copper compounds Chemical class 0.000 abstract 4
- 150000001925 cycloalkenes Chemical class 0.000 abstract 4
- NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical compound OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 abstract 4
- JBDSSBMEKXHSJF-UHFFFAOYSA-N cyclopentanecarboxylic acid Chemical compound OC(=O)C1CCCC1 JBDSSBMEKXHSJF-UHFFFAOYSA-N 0.000 abstract 4
- 229910052749 magnesium Inorganic materials 0.000 abstract 4
- 239000011777 magnesium Substances 0.000 abstract 4
- 150000003839 salts Chemical class 0.000 abstract 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000007513 acids Chemical class 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 229910052788 barium Inorganic materials 0.000 abstract 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 239000012295 chemical reaction liquid Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 150000001879 copper Chemical class 0.000 abstract 2
- VZFUCHSFHOYXIS-UHFFFAOYSA-N cycloheptane carboxylic acid Natural products OC(=O)C1CCCCCC1 VZFUCHSFHOYXIS-UHFFFAOYSA-N 0.000 abstract 2
- 238000004821 distillation Methods 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract 2
- 239000012442 inert solvent Substances 0.000 abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 2
- 239000011572 manganese Substances 0.000 abstract 2
- 239000000155 melt Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002736 metal compounds Chemical class 0.000 abstract 2
- OTCVAHKKMMUFAY-UHFFFAOYSA-N oxosilver Chemical class [Ag]=O OTCVAHKKMMUFAY-UHFFFAOYSA-N 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910001923 silver oxide Inorganic materials 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
- C07C1/2078—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by a transformation in which at least one -C(=O)-O- moiety is eliminated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
- C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL254566 | 1960-08-04 | ||
| NL264222 | 1961-04-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES269544A1 true ES269544A1 (es) | 1962-01-01 |
Family
ID=26641728
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES0269544A Expired ES269544A1 (es) | 1960-08-04 | 1961-08-03 | Un procedimiento para la oxidaciën de acido cicloalcano carboxilico |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE606883A (es) |
| CH (1) | CH422767A (es) |
| ES (1) | ES269544A1 (es) |
| GB (1) | GB964980A (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL6401389A (es) * | 1964-02-17 | 1965-08-18 | ||
| US4393260A (en) | 1980-08-01 | 1983-07-12 | The Standard Oil Company | Preparation of cyclohexenyl compounds |
-
1961
- 1961-07-28 GB GB27549/61A patent/GB964980A/en not_active Expired
- 1961-08-03 ES ES0269544A patent/ES269544A1/es not_active Expired
- 1961-08-03 BE BE606883A patent/BE606883A/fr unknown
- 1961-08-03 CH CH913261A patent/CH422767A/de unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB964980A (en) | 1964-07-29 |
| CH422767A (de) | 1966-10-31 |
| BE606883A (fr) | 1962-02-05 |
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| SU363693A1 (ru) | СПОСОБ ПОЛУЧЕНИЯ ОКСИБЕНЗОФЕНОНОКСИМОВ1Изобретение относитс к способам получени органических соединений, которые могут быть использованы в качестве комнлексо- образователей дл извлечени различных ценных металлов из водных растворов их солей.' Известен способ получени оксибензофено- иоксимов путем взаимодействи хлорангидри- дов бензойных кислот с пара-замещенными фенолами, с последующей перегруппировкой полученных эфиров до оксибензофенонов, которые превращаютс в соответствующие ок- симы действием сол нокислого гидроксилами- на в присутствии акцепторов хлористого водорода.Недостат!кам'И указанного способа вл ютсл его многостадийность, низкий выход кетонов на стадии перегруппировки, необходимость применени сол нокислого гидроксиламина, хлористого алюмини , хлористого бензоила, пиридина, щелочи.Цель изобретени — упрощение технологического процесса. По предлагаемому способу получени замещенных оксибензофенонокси- мов общей формулы:где R—ОН; R2,R''—Н, алкил или алкоксил бензилфенол фотохимически оксимируют хлористым нитрозило.м или смесью хлора, окиси азота и хлористого водорода, в среде инерт- 5 ного растворител с последующим выделением целевого продукта известным способом.Пример.1020Получение 5- | |
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